Project/Area Number |
24780168
|
Research Category |
Grant-in-Aid for Young Scientists (B)
|
Allocation Type | Multi-year Fund |
Research Field |
Wood science
|
Research Institution | Nagoya University |
Principal Investigator |
AOKI Dan 名古屋大学, 生命農学研究科, 助教 (80595702)
|
Co-Investigator(Renkei-kenkyūsha) |
AOKI Dan 名古屋大学, 大学院生命農学研究科, 助教 (80595702)
|
Project Period (FY) |
2012-04-01 – 2014-03-31
|
Project Status |
Completed (Fiscal Year 2013)
|
Budget Amount *help |
¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
|
Keywords | セルロース / リビング重合 / ATRP / ポリマーブラシ / 高次構造 |
Research Abstract |
Novel polymer material based on a cellulose derivative was prepared. The purpose of the study is to control the primary structure by a chemical modification, the secondary structure by a molecular orientation, and the tertiary and higher structures by an accumulation of them. Cellulose derivatives having reaction sites in the side group were synthesized. Living radical polymerization was applied to a film of the cellulose derivative to introduce well-defined vinyl polymer side chains. Chemical structures, molecular weights, and their higher structures were investigated by NMR, GPC, and polarized FT-IR measurements.
|