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Development of nitrogen–boron bond cleavage reaction and its application to practical synthesis of multifunctional compounds

Research Project

Project/Area Number 24850011
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Organic chemistry
Research InstitutionOsaka University

Principal Investigator

KENSUKE Kiyokawa  大阪大学, 工学(系)研究科(研究院), 助教 (80632364)

Project Period (FY) 2012-08-31 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords有機化学 / 合成化学 / アミノホウ素化 / アミノボラン / ホウ素
Research Abstract

Suitable aminoboranes has been designed, and indeed, we succeeded in synthesizing and isolation of several aminoboranes. We next investigated the cleavage of nitrogen-boron bond of the aminoborane followed by aminoboration of carbon-carbon multiple bond moieties such as alkenes and alkynes by using transition metal catalysts. Although extensive screening of metal catalysts such as Pd, Pt, and Cu catalysts in combination with ligands was conducted, the effective catalyst system has not been established yet. However, the present study provided new insights into organic synthesis using aminoboranes.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • Research Products

    (7 results)

All 2014 2013

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (6 results)

  • [Journal Article] Metal-Free Aziridination of Styrene Derivatives with Iminoiodinane Catalyzed by a Combination of Iodine and Ammonium Iodide2013

    • Author(s)
      Satoshi Minakata
    • Journal Title

      Org. Lett.

      Volume: 15 Issue: 18 Pages: 4858-4861

    • DOI

      10.1021/ol402276f

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Presentation] ヨウ素/アンモニウムヨージド触媒系によるイミノヨージナンを窒素源としたスチレン誘導体のアジリジン化反応2014

    • Author(s)
      清川謙介、小坂知輝、南方聖司
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋(口頭発表)
    • Related Report
      2013 Final Research Report
  • [Presentation] ヨウ素/アンモニウムヨージド触媒系によるイミノヨージナンを窒素源としたスチレン誘導体のアジリジン化反応2014

    • Author(s)
      清川謙介
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Annual Research Report
  • [Presentation] ヨウ素/アンモニウム塩触媒を用いたイミノヨージナンを窒素源とするスチレン誘導体のメタルフリーアジリジン化反応2013

    • Author(s)
      清川謙介、小坂知輝、南方聖司
    • Organizer
      第3回CSJ化学フェスタ2013
    • Place of Presentation
      東京(ポスター発表)
    • Related Report
      2013 Final Research Report
  • [Presentation] ヨウ素/アンモニウム塩触媒を活用したイミノヨージナンを窒素源とするアジリジン合成2013

    • Author(s)
      清川謙介、小坂知輝、南方聖司
    • Organizer
      第16回ヨウ素学会シンポジウム
    • Place of Presentation
      千葉(ポスター発表)
    • Related Report
      2013 Final Research Report
  • [Presentation] ヨウ素/アンモニウム塩触媒を用いたイミノヨージナンを窒素源とするスチレン誘導体のメタルフリーアジリジン化反応2013

    • Author(s)
      清川謙介
    • Organizer
      第3回CSJ化学フェスタ2013
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] ヨウ素/アンモニウム塩触媒を活用したイミノヨージナンを窒素源とするアジリジン合成2013

    • Author(s)
      清川謙介
    • Organizer
      第16回ヨウ素学会シンポジウム
    • Place of Presentation
      千葉
    • Related Report
      2013 Annual Research Report

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Published: 2012-11-27   Modified: 2019-07-29  

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