| Project/Area Number |
24850017
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
|
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| Research Institution | Tokyo Metropolitan University (2013)
Aoyama Gakuin University (2012) |
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Principal Investigator |
MIURA Hiroki 首都大学東京, 都市環境科学研究科, 助教 (20633267)
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| Project Period (FY) |
2012-08-31 – 2014-03-31
|
| Project Status |
Completed (Fiscal Year 2013)
|
| Budget Amount *help |
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
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| Keywords | 有機金属化学 / イリジウム / C-H活性化 / 単純アルケン / 活性メチレン / カチオン性錯体 / 付加反応 / 1,3-ジケトン |
|---|
| Research Abstract |
Addition of carbon-hydrogen bonds to carbon-carbon multiple bond is environmental-benign molecular transformations to afford substituted alkenes with 100% atom-economy. In the present study, cationic iridium catalysts were found to show high activity and selectivity toward the addition of 1,3-dicarbonyl compounds to simple terminal alkenes. Among Ir catalysts examined, [Ir(cod)2]SbF6 showed the highest activity to afford the corresponding products in high yields. Reaction of various terminal alkenes and 1,3-diketones produced the corresponding products in good to high yields.
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