Development of Morphology-Controllable Graphite Films and Their Morphology-Based Optoelectrical Functions

• Project/Area Number: 25246002
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Nanostructural chemistry
• Research Institution: Kyoto University
• Principal Investigator: Akagi Kazuo 京都大学, 工学研究科, 教授 (20150964)
• Co-Investigator(Kenkyū-buntansha): 松下 哲士 京都大学, 工学(系)研究科(研究院), 助教 (90589186)
• Project Period (FY): 2013-04-01 – 2017-03-31
• Project Status: Completed (Fiscal Year 2016)
• Budget Amount: ¥46,150,000 (Direct Cost: ¥35,500,000、Indirect Cost: ¥10,650,000); Fiscal Year 2016: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000); Fiscal Year 2015: ¥8,840,000 (Direct Cost: ¥6,800,000、Indirect Cost: ¥2,040,000); Fiscal Year 2014: ¥11,570,000 (Direct Cost: ¥8,900,000、Indirect Cost: ¥2,670,000); Fiscal Year 2013: ¥18,590,000 (Direct Cost: ¥14,300,000、Indirect Cost: ¥4,290,000)
• Keywords: 三重結合部位 / 共役複素環ポリマー / 炭素化収率 / キラル液晶 / 不斉電気化学重合 / ヘリカル炭素化物 / 形態保持炭素化 / 配向グラファイト / キラルネマチック液晶 / 高分子合成 / 高分子構造・物性 / 電子・電気材料 / ナノ材料 / 有機導体 / 不斉反応場 / ヘリカルポリアセチレン / ヘリカル共役ポリマー / 階層的スパイラル形態 / ヘリカルカーボン / ヘリカルグラファイト

Outline of Final Research Achievements

We prepared macroscopically aligned and helicity-controlled graphite films and clarified their morphology-based optoelectrical functions.　Several types of conjugated polymers that have hierarchically spiral morphologies and/or aligned parallel and perpendicular to the substrate were synthesized through chemical and electrochemical polymerizations, and subsequently they were subjected as precursors for thermal heating procedures based on the morphology-retaining carbonization and graphitization. The spectroscopic properties and electrical characteristics such as supercapacitor of the prepared carbon and graphite films were investigated from the viewpoint of next-generation functional materials.

Research Products

• [Journal Article] Chiroptical Resolution and Thermal Switching of Chirality in Conjugated Polymer Luminescence via Selective Reflection using a Double-Layered Cell of Chiral Nematic Liquid Crystal (2017)
  • Author(s): J. Yan, F. Ota, B. A. San Jose, K. Akagi
  • Journal Title: Adv. Funct. Mater. Volume: 27 Issue: 2 Pages: 1604529-1604539
  • DOI: 10.1002/adfm.201604529
  • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Aligned Carbon and Graphite Fibers Prepared from Poly(3,4-ethylenedioxythiophene) Single Crystals Synthesized by Solid-State Polymerization and Their Supercapacitor Performance (2017)
  • Author(s): B. Yan, S. Matsushita, K. Akagi
  • Journal Title: J. Mater. Chem. C Volume: 5 Issue: 15 Pages: 3823-3829
  • DOI: 10.1039/c7tc00709d
  • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Morphology-Controlled Carbonaceous and Graphitic Materials Prepared from Conjugated Polymers as Precursors through Solid-State Carbonization (2016)
  • Author(s): S. Matsushita, B. Yan, M. Kyotani, K. Akagi
  • Journal Title: Synth. Met. Volume: 216 Pages: 103-112
  • DOI: 10.1016/j.synthmet.2015.09.010
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Helically Assembled Pyrene Arrays on an RNA Duplex that Exhibit Circularly Polarized Luminescence with Excimer Formation (2016)
  • Author(s): M. Nakamura, J. Suzuki, F. Ota, T. Takada, K. Akagi, K. Yamana
  • Journal Title: Chem. Eur. J. Volume: 22 Issue: 27 Pages: 9121-9124
  • DOI: 10.1002/chem.201602043
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Liquid Crystallinity-Enforced Chirality Transfer from Chiral Monosubstituted Polyacetylene Copolymer to Poly(para-phenyleneethynylene) (2016)
  • Author(s): B. A. San Jose, S. Matsushita, K. Akagi
  • Journal Title: Macromolecules Volume: 49 Issue: 20 Pages: 7703-7708
  • DOI: 10.1021/acs.macromol.6b01952
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Morphology-Controlled Carbon and Graphitic Films Prepared from Helical PEDOT Films as Precursors via Solid-State Carbonization (2016)
  • Author(s): B. Yan, S. Matsushita, K. Akagi
  • Journal Title: Chem. Mater. Volume: 28 Issue: 23 Pages: 8781-8791
  • DOI: 10.1021/acs.chemmater.6b04355
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Apparent Power Law Scaling of Variable Range Hopping Conduction in Carbonized Polymer Nanofibers (2016)
  • Author(s): K. H. Kim, S. Lara-Avila, H. Kang, H. He, J. Eklof, S. J. Hong, M. Park, K. Moth-Poulsen, S. Matsushita, K. Akagi, S. Kubatkin, Y. W. Park
  • Journal Title: Sci. Rep. Volume: 6 Issue: 1 Pages: 37783-37791
  • DOI: 10.1038/srep37783
  • NAID: 120005997908
  • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] 光で光を制御する ― 光応答性白色および虹色カラー発光体の創成 (2016)
  • Author(s): 渡辺和誉, 赤木和夫
  • Journal Title: 化学 Volume: 71巻 Pages: 32-37
  • NAID: 40020963823
  • Acknowledgement Compliant
• [Journal Article] Macroscopically Aligned Graphite Films Prepared from Iodine-Doped Stretchable Polyacetylene Films Using Morphology-Retaining Carbonization (2015)
  • Author(s): S. Matsushita, K. Akagi
  • Journal Title: J. Am. Chem. Soc. Volume: 137 Issue: 28 Pages: 9077-9087
  • DOI: 10.1021/jacs.5b04012
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Macroscopically Aligned Carbon and Graphite Whiskers Prepared from Poly(m-phenylene) Derivatives with Helicene-like Helical Structures (2015)
  • Author(s): B. Yan, S. Matsushita, K. Suda, K. Akagi
  • Journal Title: Chem.Mater. Volume: in press Issue: 8 Pages: 2973-2980
  • DOI: 10.1021/acs.chemmater.5b00303
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Interchain Helically π-Stacked Assembly of Cationic Chiral Poly(para-phenylene) Derivatives Enforced by Anionic π-Conjugated Molecules through Both Electrostatic and π－π Interactions (2015)
  • Author(s): K. Watanabe, Z. Sun, K. Akagi
  • Journal Title: Chem.Mater. Volume: in press Issue: 8 Pages: 2895-2902
  • DOI: 10.1021/acs.chemmater.5b00121
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Dynamic Control of Full-Colored Emission and Quenching of Photoresponsive Conjugated Polymers by Photostimuli (2015)
  • Author(s): K. Watanabe, H. Hayasaka, T. Miyashita, K. Ueda , K. Akagi
  • Journal Title: Adv. Funct. Mater. Volume: in press Issue: 19 Pages: 2794-2806
  • DOI: 10.1002/adfm.201500136
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Helical Network Polymers Exhibiting Circularly Polarized Luminescence with Thermal Stability. Synthesis via Photo-Cross-Link Polymerizations of Methacrylate Derivatives in a Chiral Nematic Liquid Crystal (2015)
  • Author(s): J. Park, T. Yu, T. Inagaki, K. Akagi
  • Journal Title: Macromolecules Volume: 48 Issue: 7 Pages: 1930-1940
  • DOI: 10.1021/acs.macromol.5b00063
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Liquid Crystallinity-Embodied Imidazolium-Based Ionic Liquids and Their Chiral Mesophases Induced by Axially Chiral Tetra-Substituted Binaphthyl Derivatives (2015)
  • Author(s): S. Ahn, S.Yamakawa, K. Akagi
  • Journal Title: J. Mater. Chem. C Volume: 3 Issue: 16 Pages: 3960-3970
  • DOI: 10.1039/c4tc02968b
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] 超階層構造制御されたらせん共役ポリマー (2015)
  • Author(s): 赤木和夫
  • Journal Title: 高分子 Volume: 64 Pages: 703-705
• [Journal Article] Low Bandgap Poly(thienylenemethine) Derivatives Bearing Terarylene Moieties in the Side Chains (2014)
  • Author(s): S. Ahn, K. Yabumoto, Y.S. Jeong, K. Akagi
  • Journal Title: Polym. Chem. Volume: 5 Issue: 24 Pages: 6977-6989
  • DOI: 10.1039/c4py00849a
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Helically Assembled π-Conjugated Polymers with Circularly Polarized Luminescence (2014)
  • Author(s): K. Watanabe, K. Akagi
  • Journal Title: Sci. Tech. Adv. Mater. Volume: 15 Pages: 44203-44224
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Dynamic Switching of Circularly Polarized Luminescence of Di-Substituted Polyacetylene by Selective Transmission through a Thermotropic Chiral Nematic Liquid Crystal (2014)
  • Author(s): B. A. San Jose, J. Yan, K. Akagi
  • Journal Title: Angew. Chem. Int. Ed. Volume: 53 Issue: 40 Pages: 10641-10644
  • DOI: 10.1002/anie.201404250
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Helicity Control of π-Stacked Assemblies of Oligo(para-phenylene) Derivatives using Photoresponsive Chiral Moieties at Terminal Sites (2014)
  • Author(s): B. A. San Jose, T. Ashibe, N.Tada, S. Yorozuya, K. Akagi
  • Journal Title: Adv. Funct. Mater. Volume: 24 Issue: 39 Pages: 6166-6171
  • DOI: 10.1002/adfm.201401453
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Helical Nylons and Polyphthalamides Synthesized by Chiral Interfacial Polymerizations between Chiral Nematic Liquid Crystal and Water Layers (2014)
  • Author(s): J. Park, M. Goh, K. Akagi
  • Journal Title: Macromolecules Volume: 47 Issue: 9 Pages: 2784-2795
  • DOI: 10.1021/ma500515s
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Photochemically Colour-Tuneable White Fluorescence Illuminants consisting of Conjugated Polymer Nanospheres (2014)
  • Author(s): J. Bu, K. Watanabe, H. Hayasaka, K. Akagi
  • Journal Title: Nature. Commun. Volume: in press Issue: 1 Pages: 3799-3806
  • DOI: 10.1038/ncomms4799
  • Peer Reviewed
• [Journal Article] Helical Carbon and Graphite Films Prepared from Helical Poly(3,4-ethylenedioxythiophene) Films Synthesized by Electrochemical Polymerization in Chiral Nematic Liquid Crystals (2014)
  • Author(s): S. Matsushita, B. Yan, S. Yamamoto, Y. S. Jeong, K. Akagi
  • Journal Title: Angew. Chem., Int. Ed. Volume: 53 Issue: 6 Pages: 1659-1663
  • DOI: 10.1002/anie.201308462
  • Peer Reviewed
• [Journal Article] 常温で世界一電気を良く通す高分子 (2014)
  • Author(s): 赤木和夫
  • Journal Title: 化学と教育 Volume: 62 Pages: 556-557
• [Journal Article] Superhelix Structure in Helical Conjugated Polymers Synthesized in an Asymmetric Reaction Field (2013)
  • Author(s): T. Mori, K. Akagi
  • Journal Title: Macromolecules Volume: 46 Issue: 17 Pages: 6699-6711
  • DOI: 10.1021/ma401092v
  • Peer Reviewed
• [Journal Article] Dispersion and Magnetic Field-Induced Alignment of Functionalized Carbon Nanotubes in Liquid Crystals (2013)
  • Author(s): H. J. Yoo, S. Y. Lee, N. H. You, D. S. Lee, H. Yeo, Y. M. Choi, M. Goh, J. Park, K. Akagi, J. W. Cho
  • Journal Title: Synth. Met. Volume: 181 Pages: 10-17
  • DOI: 10.1016/j.synthmet.2013.07.023
  • Peer Reviewed
• [Journal Article] Iodine Doping Effects on the Lattice Thermal Conductivity of Oxidized Polyacetylene Nanofibers (2013)
  • Author(s): K. Bi, A. Weathers, S. Matsushita, M. T. Pettes, M. Goh, K. Akagi, L. Shi
  • Journal Title: J. Appl. Phys. Volume: 114 Issue: 19 Pages: 194302-194307
  • DOI: 10.1063/1.4831945
  • Peer Reviewed
• [Journal Article] Electrochromism-Driven Linearly and Circularly PolarisedDichroism of Poly(3,4-ethylenedioxythiophene) Derivatives with Chirality and Liquid Crystallinity (2013)
  • Author(s): S. Matsushita, Y.-S. Jeong, K. Akagi
  • Journal Title: Chem. Commun Volume: 49, No. 19 Issue: 19 Pages: 1883-1890
  • DOI: 10.1039/c2cc37116b
  • Peer Reviewed
• [Journal Article] Hierarchically Self-Assembled Helical Conjugated Polymers (2013)
  • Author(s): K. Watanabe, K. Suda, K. Akagi
  • Journal Title: J. Mater. Chem. C. Volume: 1, No.16 Issue: 16 Pages: 2797-2805
  • DOI: 10.1039/c3tc00045a
  • Peer Reviewed
• [Journal Article] Liquid Crystalline Polyacetylene Derivatives with Advanced Electrical and Optical Properties (2013)
  • Author(s): B. A. San Jose
  • Journal Title: Polym. Chem. Volume: in press Issue: 20 Pages: 5144-5161
  • DOI: 10.1039/c3py00063j
  • Peer Reviewed
• [Presentation] Helical Structures and Chiroptical Properties of Multifunctional Conjugated Polymers (2017)
  • Author(s): K. Akagi
  • Organizer: 29th International Symposium on Chirality (Chirality 2017)
  • Place of Presentation: Waseda University International Conference Center（Shinjuku-ku, Tokyo, Japan)
  • Year and Date: 2017-07-09
  • Int'l Joint Research / Invited
• [Presentation] Conjugated Polymers-Based Multifunctional Materials with Photoresponsive Helical Structures and Chiroptical Properties (2017)
  • Author(s): K. Akagi
  • Organizer: Energy Materials Nanotechnology (EMN) Meeting on Smart and Multifunctional Materials
  • Place of Presentation: Mercure Roma West (Rome, Italy)
  • Year and Date: 2017-06-24
  • Int'l Joint Research / Invited
• [Presentation] キラル液晶場での光カチオン重合によるヘリカルネットワークポリマーの合成とその円偏光発光特性 (2017)
  • Author(s): 楠 賢、稲垣拓也、赤木和夫
  • Organizer: 第66回高分子学会年次大会
  • Place of Presentation: 幕張メッセ (千葉県千葉市)
  • Year and Date: 2017-05-29
• [Presentation] キラル置換型ポリメタフェニレンエチニレン誘導体の凝集状態でのキラル反転 (2017)
  • Author(s): 日高将智、閻柏如、松下哲士、赤木和夫
  • Organizer: 第66回高分子学会年次大会
  • Place of Presentation: 幕張メッセ (千葉県千葉市)
  • Year and Date: 2017-05-29
• [Presentation] 多重分子間相互作用を利用したキラルおよびアキラル芳香族共役系ポリマー間でのキラリティ転写 (2017)
  • Author(s): 原田恭佑、野津賢祐、赤木和夫
  • Organizer: 第66回高分子学会年次大会
  • Place of Presentation: 幕張メッセ (千葉県千葉市)
  • Year and Date: 2017-05-29
• [Presentation] キラルネマチック相を示す液晶性イオン液体の合成と不斉電解重合への応用 (2017)
  • Author(s): 和田浩平、山川勝平、赤木和夫
  • Organizer: 第66回高分子学会年次大会
  • Place of Presentation: 幕張メッセ (千葉県千葉市)
  • Year and Date: 2017-05-29
• [Presentation] 液晶と共役ポリマーとの融合化学の開拓と展開(Development and Progress of Interdisciplinary Chemistry Based on Integration of Liquid Crystals and Conjugated Polymers） (2017)
  • Author(s): 赤木和夫
  • Organizer: 日本化学会
  • Place of Presentation: 慶応大学日吉キャンパス(神奈川県横浜市）
  • Year and Date: 2017-03-16
  • Invited
• [Presentation] キラル液晶の選択反射を用いた共役ポリマー発光のキラル分割と熱的スイッチング (2016)
  • Author(s): 赤木和夫
  • Organizer: 日本化学繊維研究所第74回講演会
  • Place of Presentation: 京都大学桂ホール（京都府京都市）
  • Year and Date: 2016-11-10
  • Invited
• [Presentation] 芳香族系キラル側鎖を有する二置換ポリアセチレンの合成と円偏光発光特性 (2016)
  • Author(s): 大田冬木、赤木和夫
  • Organizer: 第65回高分子討論会
  • Place of Presentation: 神奈川大学 横浜キャンパス (神奈川県横浜市)
  • Year and Date: 2016-09-14
• [Presentation] π-π相互作用と水素結合を利用した芳香族共役系ポリマー凝集体の構築とその光学特性 (2016)
  • Author(s): 原田恭佑、野津賢祐、赤木和夫
  • Organizer: 第65回高分子討論会
  • Place of Presentation: 神奈川大学 横浜キャンパス (神奈川県横浜市)
  • Year and Date: 2016-09-14
• [Presentation] キラル側鎖を有するポリジフェニルアセチレン誘導体の合成と光学特性 (2016)
  • Author(s): 松山大起、大田冬木、赤木和夫
  • Organizer: 第65回高分子討論会
  • Place of Presentation: 神奈川大学 横浜キャンパス (神奈川県横浜市)
  • Year and Date: 2016-09-14
• [Presentation] 温度により多重キラル反転する不斉液晶の開発 (2016)
  • Author(s): 大門幸生、坪井一俊、赤木和夫
  • Organizer: 日本液晶討論会
  • Place of Presentation: 大阪工業大学 大宮キャンパス（大阪府大阪市）
  • Year and Date: 2016-09-05
• [Presentation] 軸不斉ビナフチル部位と光応答性ジアリールエテン部位を架橋したキラル化合物の合成と不斉液晶場の構築 (2016)
  • Author(s): 森川陽太、植田健太、赤木和夫
  • Organizer: 日本液晶討論会
  • Place of Presentation: 大阪工業大学 大宮キャンパス（大阪府大阪市）
  • Year and Date: 2016-09-05
• [Presentation] キラルネマチック相を示す液晶性イオン液体の合成と不斉電解重合への応用 (2016)
  • Author(s): 和田浩平、山川勝平、赤木和夫
  • Organizer: 日本液晶討論会
  • Place of Presentation: 大阪工業大学 大宮キャンパス（大阪府大阪市）
  • Year and Date: 2016-09-05
• [Presentation] Hierarchically Assembled Conjugated Polymers with Photoresponsive Helical Structures and Chiroptical Properties (2016)
  • Author(s): K. Akagi
  • Organizer: International Conference on Science and Technology of Synthetic Metals (ICSM2016)
  • Place of Presentation: Guangzhou Baiyun International Convention Center (Guangzhou, China)
  • Year and Date: 2016-06-26
  • Int'l Joint Research / Invited
• [Presentation] Hierarchically Assembled Conjugated Polymers with Photoresponsive Helical Structures and Chiroptical Properties (2016)
  • Author(s): K. Akagi
  • Organizer: International Conference on Science and Technology of Synthetic Metals (ICSM2014)
  • Place of Presentation: Guangzhou (China)
  • Year and Date: 2016-06-26
  • Int'l Joint Research / Invited
• [Presentation] キラルおよびラセミ芳香族共役系ポリマー間でのヘリカル積層π－π相互作用に基づくキラリティ転写 (2016)
  • Author(s): 野津賢祐、渡辺和誉、赤木和夫
  • Organizer: 第65回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場 (兵庫県神戸市)
  • Year and Date: 2016-05-25
• [Presentation] Synthesis of Helical Network Polymers through Photo-Crosslink Polymerization in Chiral Liquid Crystal Field and Their Application to Chiral Templates (2016)
  • Author(s): T. Inagaki, J. Park, K. Akagi
  • Organizer: 第65回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場 (兵庫県神戸市)
  • Year and Date: 2016-05-25
• [Presentation] キラル液晶が織りなす捻れの世界 (2016)
  • Author(s): 赤木和夫
  • Organizer: 日本学術振興会・情報科学用有機材料第142委員会
  • Place of Presentation: 東京理科大学神楽坂キャンパス、（東京都新宿区）
  • Year and Date: 2016-03-10
  • Invited
• [Presentation] Advances in Conjugated Polymers (2015)
  • Author(s): K. Akagi
  • Organizer: The 2015 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2015)
  • Place of Presentation: Honolulu, Hawaii (USA)
  • Year and Date: 2015-12-15
  • Int'l Joint Research / Invited
• [Presentation] Recent Progress in Conjugated Polymers (2015)
  • Author(s): K. Akagi
  • Organizer: Pacific Polymer Conference 14
  • Place of Presentation: Kauai, Hawaii (USA)
  • Year and Date: 2015-12-09
  • Int'l Joint Research / Invited
• [Presentation] 有機高分子系の熱分解を制御した形態保持化学的固相炭素化 (2015)
  • Author(s): 京谷陸征、松下哲士、赤木和夫
  • Organizer: 炭素材料学会年会
  • Place of Presentation: 関西大学千里山キャンパス （大阪府吹田市）
  • Year and Date: 2015-12-02
• [Presentation] 共役ポリマーの円偏光発光における極限的非対称性因子の実現 (2015)
  • Author(s): 赤木和夫
  • Organizer: 日本化学繊維研究所第73回講演会
  • Place of Presentation: 京都大学桂ホール（京都府京都市）
  • Year and Date: 2015-11-10
  • Invited
• [Presentation] Hierarchically Assembled Conjugated Polymers with Helical Structures and Chiroptical Properties (2015)
  • Author(s): K. Akagi
  • Organizer: Bristol-Heidelberg-Kyoto (BHK) Symposium
  • Place of Presentation: Bristol (UK)
  • Year and Date: 2015-11-05
  • Int'l Joint Research / Invited
• [Presentation] セルロース系繊維材料の熱分解の無い化学的固相炭素化竹紙からの丈夫な高導電性炭化紙の生成 (2015)
  • Author(s): 京谷陸征、田中裕之、松下哲士、赤木和夫
  • Organizer: 繊維学会秋季年会
  • Place of Presentation: 京都工芸繊維大学 （京都府京都市）
  • Year and Date: 2015-10-22
• [Presentation] Recent Progress in Conjugated Polymers (2015)
  • Author(s): K. Akagi
  • Organizer: IUPAC 11th International Conference on Advanced Polymers via Macromolecular Engineering (APME 2015)
  • Place of Presentation: Pacifico Yokohama (Yokohama, Japan)
  • Year and Date: 2015-10-18
  • Int'l Joint Research / Invited
• [Presentation] 光応答性不斉化合物を用いた液晶場のキラリティー制御 (2015)
  • Author(s): 植田健太、赤木和夫
  • Organizer: 日本液晶討論会
  • Place of Presentation: 東京工業大学 すずかけ台キャンパス（神奈川県横浜市）
  • Year and Date: 2015-09-07
• [Presentation] Progress in Helical Conjugated Polymers (2015)
  • Author(s): K. Akagi
  • Organizer: The Kyoto-Bordeaux Symposium
  • Place of Presentation: Center of Innovation Building of Kyoto University (Kyoto, Japan)
  • Year and Date: 2015-05-22
  • Int'l Joint Research / Invited
• [Presentation] Advances in Conjugated Polymers (2015)
  • Author(s): K. Akagi
  • Organizer: The International Symposium on Carbon Electronics (ISCE) 2015
  • Place of Presentation: Pusan (Korea)
  • Year and Date: 2015-05-11
  • Int'l Joint Research / Invited
• [Presentation] 次世代機能ポリマー (2015)
  • Author(s): 赤木和夫
  • Organizer: 科学研究費 新学術領域研究「元素ブロック高分子材料の創出」第５回公開シンポジウム
  • Place of Presentation: 東京理科大学神楽坂キャンパス （東京都新宿区）
  • Year and Date: 2015-01-29
  • Invited
• [Presentation] ラセン共役ポリマーの合成と超階層構造制御 (2015)
  • Author(s): 赤木和夫
  • Organizer: 高分子学会東海シンポジウム
  • Place of Presentation: 名古屋国際会議場（愛知県名古屋市）
  • Year and Date: 2015-01-15
  • Invited
• [Presentation] Chirality-switchable Circularly Polarized Luminescence through Selective Reflection based on Combination of Disubstituted Polyacetylene Film and Double-layered Chiral Nematic Liquid Crystal Cell (2014)
  • Author(s): J. Yan, B. San Jose, K. Akagi
  • Organizer: KIPS若手高分子シンポジウム
  • Place of Presentation: 京都大学桂ホール (京都府京都市)
  • Year and Date: 2014-12-12
• [Presentation] 極性キラル化合物を用いたイオン性芳香族共役ポリマーへのキラル誘起 (2014)
  • Author(s): 大島拓実. 渡辺和誉, 赤木和夫
  • Organizer: KIPS若手高分子シンポジウム
  • Place of Presentation: 京都大学桂ホール (京都府京都市)
  • Year and Date: 2014-12-12
• [Presentation] Advances in Conjugated Polymers - Helical conjugated polymers, helical graphites, circularly polarized luminescent spherulites, and photochemically switchable fluorescent illuminants (2014)
  • Author(s): K. Akagi
  • Organizer: Lecture of Applied Chemistry
  • Place of Presentation: National Chiao Tung University (NCTU), Hsinchu, (Taiwan)
  • Year and Date: 2014-11-27
  • Invited
• [Presentation] Helical Conjugated Polymers Synthesized in Chiral Liquid Crystal Field and Carbonization-based Helical Graphites (2014)
  • Author(s): K. Akagi
  • Organizer: Joint Workshop on Functional Materials 2014
  • Place of Presentation: National Central University (NCU), Taoyuan, (Taiwan)
  • Year and Date: 2014-11-26 – 2014-11-27
  • Invited
• [Presentation] Synthesis of Liquid Crystalline Ionic Liquids and Chirality Induction (2014)
  • Author(s): S. Yamakawa, S. Ahn, K. Akagi
  • Organizer: Joint Workshop on Functional Materials 2014
  • Place of Presentation: National Central University (NCU), Taipei, (Taiwan)
  • Year and Date: 2014-11-26 – 2014-11-27
• [Presentation] Chirality Control of Liquid Crystal Field using Photoresponsive Chiral Compounds (2014)
  • Author(s): K. Ueda, K. Akagi
  • Organizer: Joint Workshop on Functional Materials 2014
  • Place of Presentation: National Central University (NCU), Taipei, (Taiwan)
  • Year and Date: 2014-11-26 – 2014-11-27
• [Presentation] Vertically Aligned Polyacetylene Films Synthesized in Spontaneously Vertical-Aligned Liquid Crystal Polymerization Field (2014)
  • Author(s): H. Horikawa, S. Matsushita, K. Akagi
  • Organizer: Joint Workshop on Functional Materials 2014
  • Place of Presentation: National Central University (NCU), Taoyuan, (Taiwan)
  • Year and Date: 2014-11-26 – 2014-11-27
• [Presentation] Synthesis of Helical Network Polymers with Circularly Polarized Luminescence through Photo-copolymerization in Chiral Nematic Liquid Crystal Field (2014)
  • Author(s): T. Yu, J. Park, K. Akagi
  • Organizer: Joint Workshop on Functional Materials 2014
  • Place of Presentation: National Central University (NCU), Taoyuan, (Taiwan)
  • Year and Date: 2014-11-26 – 2014-11-27
• [Presentation] Chirality-switchable Circularly Polarized Luminescence through Selective Reflection based on Combination of Disubstituted Polyacetylene Film and Double-layered Chiral Nematic Liquid Crystal Cell (2014)
  • Author(s): J. Yan, F. Ota, B. A. San Jose, K. Akagi
  • Organizer: Joint Workshop on Functional Materials 2014
  • Place of Presentation: National Central University (NCU), Taoyuan, (Taiwan)
  • Year and Date: 2014-11-26 – 2014-11-27
• [Presentation] Synthesis of Helical Aromatic Conjugated Copolymers in Asymmetric Liquid Crystal Reaction Field with Thermally Switchable Helical Sense (2014)
  • Author(s): K. Tsuboi, T. Yamashita, K. Akagi
  • Organizer: Joint Workshop on Functional Materials 2014
  • Place of Presentation: National Central University (NCU), Taoyuan, (Taiwan)
  • Year and Date: 2014-11-26 – 2014-11-27
• [Presentation] Helical Assemblies between Poly(para-phenylene) Copolymers and Chiral Compounds (2014)
  • Author(s): S. Kondo, K. Watanabe, H. Iida, K. Akagi
  • Organizer: Joint Workshop on Functional Materials 2014
  • Place of Presentation: National Central University (NCU), Taoyuan, (Taiwan)
  • Year and Date: 2014-11-26 – 2014-11-27
• [Presentation] Synthesis and Properties of Novel Low Bandgap Polymers - Poly(thienylenemethine)s Derivatives bearing Ternary Arylene Moieties in Side Chains (2014)
  • Author(s): Y. Imamura, S. Ahn, R. Shimizuguchi, K. Akagi
  • Organizer: Joint Workshop on Functional Materials 2014
  • Place of Presentation: National Central University (NCU), Taoyuan, (Taiwan)
  • Year and Date: 2014-11-26 – 2014-11-27
• [Presentation] Chiral Induction on Ionic Aromatic Conjugated Polymers using Polar Chiral Compounds (2014)
  • Author(s): T. Oshima, K. Watanabe, K. Akagi
  • Organizer: Joint Workshop on Functional Materials 2014
  • Place of Presentation: National Central University (NCU), Taoyuan, (Taiwan)
  • Year and Date: 2014-11-26 – 2014-11-27
• [Presentation] Helical Carbon and Graphite Films using Electrochemically Doped H-PEDOT Films as Precursors (2014)
  • Author(s): C. Tao, B. Yan, S. Matsushita, K. Akagi
  • Organizer: Joint Workshop on Functional Materials 2014
  • Place of Presentation: National Central University (NCU), Taoyuan, (Taiwan)
  • Year and Date: 2014-11-26 – 2014-11-27
• [Presentation] Structures and Properties of Carbonized Papers Prepared through Solid-State Carbonizations of Chemically Pretreated Papers (2014)
  • Author(s): T. Kawamata1, K. Fujino, M. Kyotani, S. Matsushita, K. Akagi
  • Organizer: Joint Workshop on Functional Materials 2014
  • Place of Presentation: National Central University (NCU), Taoyuan, (Taiwan)
  • Year and Date: 2014-11-26 – 2014-11-27
• [Presentation] Photochemically Color-Tuneable White Fluorescence Illuminants consisting of Conjugated Polymer Nanospheres (2014)
  • Author(s): K. Watanabe, J. Bu, H. Hayasaka, K. Akagi
  • Organizer: Joint Workshop on Functional Materials 2014
  • Place of Presentation: National Central University (NCU), Taoyuan, (Taiwan)
  • Year and Date: 2014-11-26 – 2014-11-27
• [Presentation] 光応答性共役ポリマーナノ粒子からなる白色発光体の創成 (2014)
  • Author(s): 赤木和夫
  • Organizer: 日本化学繊維研究所内2回講演会
  • Place of Presentation: 京都大学桂ホール（京都府京都市）
  • Year and Date: 2014-11-11
  • Invited
• [Presentation] 液晶性共役ポリマーとキラル化合物からなるらせん状ポリマー集積体 (2014)
  • Author(s): 近藤俊輔, 渡辺和誉, 赤木和夫
  • Organizer: 第63回高分子学会討論会
  • Place of Presentation: 長崎大学 (長崎県長崎市)
  • Year and Date: 2014-09-24 – 2014-09-26
• [Presentation] Synthesis of Liquid Crystalline Ionic Liquids and their Chirality Induction (2014)
  • Author(s): S. Yamakawa, S. Ahn, K. Akagi
  • Organizer: 第63回高分子学会討論会
  • Place of Presentation: 長崎大学 (長崎県長崎市)
  • Year and Date: 2014-09-24 – 2014-09-26
• [Presentation] 極性キラル化合物を用いたイオン性芳香族共役ポリマーへのキラル誘起 (2014)
  • Author(s): 大島拓実. 渡辺和誉, 赤木和夫
  • Organizer: 第63回高分子学会討論会
  • Place of Presentation: 長崎大学 (長崎県長崎市)
  • Year and Date: 2014-09-24 – 2014-09-26
• [Presentation] 自発垂直配向ネマチック液晶を重合場とするポリアセチレンフィルムの合成 (2014)
  • Author(s): 堀川大夢. 松下哲士. 赤木和夫
  • Organizer: 第63回高分子学会討論会
  • Place of Presentation: 長崎大学 (長崎県長崎市)
  • Year and Date: 2014-09-24 – 2014-09-26
• [Presentation] 温度制御型不斉液晶反応場におけるらせん状芳香族共役系コポリマーの合成 (2014)
  • Author(s): 坪井一俊, 山下智弘, 安相範, 赤木和夫
  • Organizer: 第63回高分子学会討論会
  • Place of Presentation: 長崎大学 (長崎県長崎市)
  • Year and Date: 2014-09-24 – 2014-09-26
• [Presentation] 不斉反応場での光重合を用いたヘリカルネットワークポリマーの合成と性質 (2014)
  • Author(s): 于 天驕, パク ジンウー, 赤木 和夫
  • Organizer: 第63回高分子学会討論会
  • Place of Presentation: 長崎大学 (長崎県長崎市)
  • Year and Date: 2014-09-24 – 2014-09-26
• [Presentation] 光応答性不斉化合物を用いた液晶場のキラリティー制御 (2014)
  • Author(s): 植田健太, 赤木和夫
  • Organizer: 日本液晶学会討論会
  • Place of Presentation: くにびきメッセ（島根県松江市）
  • Year and Date: 2014-09-08 – 2014-09-10
• [Presentation] Helical Conjugated Polymers Synthesized in Chiral Liquid Crystal Field and Carbonization-based Helical Graphites (2014)
  • Author(s): K. Akagi
  • Organizer: International Conference on the Science and Technology of Synthetic Metals, ICSM2014
  • Place of Presentation: LOGOMO Congress Center, Turku, (Finland)
  • Year and Date: 2014-06-30 – 2014-07-05
  • Invited
• [Presentation] 木材パルプからの紙の化学的固相炭素化と生成した機能性炭化紙の構造物性 (2014)
  • Author(s): 京谷陸征, 藤野謙一, 後藤至誠, 松下哲士, 赤木和夫
  • Organizer: 繊維学会年次大会
  • Place of Presentation: タワーホール船堀（東京都江戸川区）
  • Year and Date: 2014-06-11 – 2014-06-13
• [Presentation] 綿布の化学的固相炭素化と生成した炭化織物の導電性と力学物性 (2014)
  • Author(s): 京谷陸征, 松下哲士, 赤木和夫
  • Organizer: 繊維学会年次大会
  • Place of Presentation: タワーホール船堀（東京都江戸川区）
  • Year and Date: 2014-06-11 – 2014-06-13
• [Presentation] Helical Assemblies between Liquid Crystalline Poly(para-phenylene) Derivatives and Chiral Compounds (2014)
  • Author(s): S. Kondo, K. Watanabe, K. Akagi
  • Organizer: 63th SPSJ Annual Meeting
  • Place of Presentation: 名古屋国際会議場（愛知県名古屋市）
  • Year and Date: 2014-05-28 – 2014-05-30
• [Presentation] Carbonization of Helical Poly(3,4-ethylenedioxythiophene) Films that are Electrochemically Doped with Alkylsulfonic Acids (2014)
  • Author(s): C. Tao, B. Yan, S. Matsushita, K. Akagi
  • Organizer: 63th SPSJ Annual Meeting
  • Place of Presentation: 名古屋国際会議場（愛知県名古屋市）
  • Year and Date: 2014-05-28 – 2014-05-30
• [Presentation] Circularly Polarized Luminescence based on Selective Transmission using Di-substituted Polyacetylene Derivative and Chiral Nematic Liquid Crystal (2014)
  • Author(s): J. Yan, B. San Jose, K. Akagi
  • Organizer: 63th SPSJ Annual Meeting
  • Place of Presentation: 名古屋国際会議場（愛知県名古屋市）
  • Year and Date: 2014-05-28 – 2014-05-30
• [Presentation] Helical Carbon and Graphite Films Prepared from Helical Poly(3,4-ethylenedioxythiophene) Films Synthesized by Electrochemical Polymerization in Chiral Nematic Liquid Crystals (2014)
  • Author(s): S. Matsushita, B. Yan, S. Yamamoto, Y.S. Jeong, K. Akagi
  • Organizer: 63th SPSJ Annual Meeting
  • Place of Presentation: 名古屋国際会議場（愛知県名古屋市）
  • Year and Date: 2014-05-28 – 2014-05-30
• [Presentation] キノイド構造を主鎖に持つローバンドギャップポリマーの合成と性質 (2014)
  • Author(s): 今村泰之, 安相範, 清水口亮介, 赤木和夫
  • Organizer: 第63回高分子年次大会
  • Place of Presentation: 名古屋国際会議場（愛知県名古屋市）
  • Year and Date: 2014-05-28 – 2014-05-30
• [Presentation] Helicity Control of Conjugated Polymers in Chiral Liquid Crystal Reaction Field (2014)
  • Author(s): K. Akagi
  • Organizer: The 2nd KYOTO-BRISTOL Symposium
  • Place of Presentation: Kyoto University, Kyoto
  • Invited
• [Presentation] Synthesis of Helical Conjugated Polymers in Chiral Liquid Crystal Reaction Field (2014)
  • Author(s): K. Akagi
  • Organizer: Functional Polymeric Materials Conference
  • Place of Presentation: Fiesta Americana Condesa Hotel, Cancun, Mexico
  • Invited
• [Presentation] イオン性共役ポリマーの階層的集積化による球晶の創成と円偏光発光 (2014)
  • Author(s): 赤木和夫
  • Organizer: 日本化学会第94春季年会、分子協調光子化学シンポジウム
  • Place of Presentation: 名古屋大学 (愛知県名古屋市)
  • Invited
• [Presentation] Hierarchically Controlled Helical Graphite Films (2013)
  • Author(s): K. Akagi
  • Organizer: International Symposium on Carbon Electronics (ISCE) 2013
  • Place of Presentation: Hoam Convention Center, Seoul National University, Korea
  • Invited
• [Presentation] Welcome Remark and Introduction of Joint Workshop and Research Laboratory (2013)
  • Author(s): K. Akagi
  • Organizer: Joint Workshop on Functional Synthetic Metals 2013
  • Place of Presentation: Royal Hotel, Jeju, Korea
  • Invited
• [Presentation] Lyotropic Chiral Nematic Liquid Crystalline Aliphatic Conjugated Polymers Based on Disubstituted Polyacetylene Derivatives That Exhibit High Dissymmetry Factors in Circularly Polarized Luminescence (2013)
  • Author(s): B. A. San Jose, S. Matsushita, K. Akagi
  • Organizer: 62nd SPSJ Annual Meeting
  • Place of Presentation: Kyoto International Conference Center, Kyoto
• [Presentation] Synthesis and Properties of Novel Low Bandgap Polymers - Poly(thienylenemethine)s bearing Ternary Arylene Moieties as Side Chains (2013)
  • Author(s): R. Shimizuguchi, S. Ahn, K. Yabumoto, Y. Jeong, K. Akagi
  • Organizer: 62nd SPSJ Annual Meeting
  • Place of Presentation: Kyoto International Conference Center, Kyoto
• [Presentation] 円偏光発光性スフェルライトの形成－ヘリカルπ-スタッキング構造を持つイオン性共役ポリマーの自己組織化 (2013)
  • Author(s): 渡辺和誉, 飯田洋, 赤木和夫
  • Organizer: 第62回高分子年次大会
  • Place of Presentation: 京都国際会館（京都府京都市）
• [Presentation] 化学的固相炭素化セルロースクロスの物性と燃料電池電極機能 (2013)
  • Author(s): 京谷陸征, 松下哲士, 赤木和夫
  • Organizer: 第62回高分子年次大会
  • Place of Presentation: 京都国際会館（京都府京都市）
• [Presentation] セルロース系クロスの化学的固相炭素化と炭素化クロスの構造物性 (2013)
  • Author(s): 京谷陸征, 松下哲士, 赤木和夫
  • Organizer: 繊維学会年次大会
  • Place of Presentation: タワーホール船堀（東京都江戸川区）
• [Presentation] Lyotropic Chiral Nematic Liquid Crystalline Di-substituted Polyacetylene Derivatives that exhibit Circularly Polarized Luminescence (2013)
  • Author(s): B. A. San Jose, S. Matsushita, K. Akagi
  • Organizer: 日本液晶学会討論会
  • Place of Presentation: 大阪大学 豊中キャンパス（大阪府豊中市）
• [Presentation] 温度によりらせん制御可能な不斉液晶反応場での芳香族共役系高分子のキラリティー制御 (2013)
  • Author(s): 安相範, 高文柱, 山本雅晴, 赤木和夫
  • Organizer: 日本液晶学会討論会
  • Place of Presentation: 大阪大学 豊中キャンパス（大阪府豊中市）
• [Presentation] 軸不斉ビナフチル誘導体を用いたネマチックおよびスメクチック液晶へのキラル誘起 - 二置換および四置換型キラルビナフチル誘導体の合成と性質 (2013)
  • Author(s): 朴珍吁, 高文柱, 安相範, 赤木和夫
  • Organizer: 日本液晶学会討論会
  • Place of Presentation: 大阪大学 豊中キャンパス（大阪府豊中市）
• [Presentation] Synthesis of Low-bandgap Polymers consisting of Thienylene Methine Moieties in Main Chains and Control of Their Bandgaps (2013)
  • Author(s): Y. Imamura, S. Ahn, R. Shimizuguchi, K. Akagi
  • Organizer: 第62回高分子討論会
  • Place of Presentation: 金沢大学 角間キャンパス(石川県金沢市)
• [Presentation] 新規温度制御型不斉液晶反応場でのヘリカルポリアセチレンの合成とらせん制御 (2013)
  • Author(s): 山下智弘, 堀江慶太, 高文柱, 赤木和夫
  • Organizer: 第62回高分子討論会
  • Place of Presentation: 金沢大学 角間キャンパス(石川県金沢市)
• [Presentation] ヘリカルπ-スタッキング構造を持つイオン性共役ポリマーの自己組織化とキラルスフェルライトの形成 (2013)
  • Author(s): 渡辺和誉, 孫澤蒙, 飯田洋, 赤木和夫
  • Organizer: 第62回高分子討論会
  • Place of Presentation: 金沢大学 角間キャンパス(石川県金沢市)
• [Presentation] Macroscopically Aligned Carbon Whiskers Prepared from Self-Assembled Aromatic π-Conjugated Polymers as Carbonization Precursors (2013)
  • Author(s): B. Yan, S. Matsushita, K. Suda, K. Akagi
  • Organizer: 第62回高分子討論会
  • Place of Presentation: 金沢大学 角間キャンパス(石川県金沢市)
• [Presentation] Dynamic Switching of Circularly Polarized Light through Selective Reflection in a Thermotropic Chiral Nematic Liquid Crystal Phase (2013)
  • Author(s): B. A. San Jose, J. Yan, S. Matsushita, K. Akagi
  • Organizer: 31st Physics Congress of the Samahang Pisika ng Pilipinas
  • Place of Presentation: University of San Carlos, Cebu City, Philippines
• [Presentation] セルロースの化学的固相炭素化法による新規な導電性シートの開発 (2013)
  • Author(s): 京谷陸征, 松下哲士, 赤木和夫
  • Organizer: 第22回ポリマー材料フォーラム
  • Place of Presentation: タワーホール船堀（東京都江戸川区）
• [Presentation] 「次世代機能ポリマー」多機能性高分子
  • Author(s): 赤木和夫
  • Organizer: 第29回新材料・新技術利用研究会
  • Place of Presentation: 生産開発科学研究所（京都府京都市）
  • Invited
• [Presentation] イオン性共役ポリマー会合体の階層的自己組織化による青色円偏光発光性球晶の創成
  • Author(s): 赤木和夫
  • Organizer: 第71回化学繊維研究所講演会
  • Place of Presentation: 桂ホール 京都大学 （京都府京都市）
  • Invited
• [Book] Functional Organic and Hybrid Nanostructured Materials: Fabrication, Properties, and Applications, “Functional Nanostructured Conjugated Polymers” (2017)
  • Author(s): S. Matsushita, B. A. San Jose, K. Akagi
  • Publisher: Wiley-VCH
• [Book] 日本の高分子科学技術史 第2巻 (2016)
  • Author(s): 赤木和夫
  • Total Pages: 252
  • Publisher: 高分子学会
• [Book] The Liquid Crystal Display Story: 50 Years of Liquid Crystal R&D that lead The Way to the Futur (2014)
  • Author(s): K. Akagi （分担執筆）
  • Total Pages: 410
  • Publisher: Springer
• [Book] Nanoscience with Liquid Crystal: From Self-Organized Nanostructures to Applications (2014)
  • Author(s): B. A. San Jose, K. Akagi（分担執筆）
  • Total Pages: 420
  • Publisher: Springer
• [Book] Conjugated Polymers: A Practical Guide to Synthesis (2014)
  • Author(s): K. Akagi (分担執筆）
  • Total Pages: 480
  • Publisher: RSC Polymer Chemistry Series
• [Book] 液晶ディスプレイ物語 -50年の液晶開発と未来に託す夢- (2013)
  • Author(s): 赤木和夫 （分担執筆）
  • Total Pages: 517
  • Publisher: エース出版
• [Book] キラル化学 -その起源から最新のキラル材料研究まで- (2013)
  • Author(s): 赤木和夫, 渡辺和誉 （分担執筆）
  • Total Pages: 205
  • Publisher: 化学同人
• [Book] 技術シーズを活用した研究開発テーマの発掘 (2013)
  • Author(s): 渡辺和誉, 松下哲士, 赤木和夫 （分担執筆）
  • Total Pages: 321
  • Publisher: 技術情報協会
• [Remarks] 研究紹介
  • URL: http://www.fps.polym.kyoto-u.ac.jp/research.html
• [Remarks] 研究紹介
  • URL: http://www.fps.polym.kyoto-u.ac.jp/research.html
• [Patent(Industrial Property Rights)] シート状炭素材料 (2014)
  • Inventor(s): 赤木和夫
  • Industrial Property Rights Holder: 日本製紙株式会社
  • Industrial Property Rights Type: 特許
  • Filing Date: 2014-03-31