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Development of new transformations based on transition metal-catalyzed alkylation and its applications

Research Project

Project/Area Number 25248025
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionOsaka University

Principal Investigator

Kambe Nobuaki  大阪大学, 工学研究科, 教授 (60144432)

Project Period (FY) 2013-05-31 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥47,060,000 (Direct Cost: ¥36,200,000、Indirect Cost: ¥10,860,000)
Fiscal Year 2016: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
Fiscal Year 2015: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
Fiscal Year 2014: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
Fiscal Year 2013: ¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Keywordsクロスカップリング反応 / 多成分反応 / アルキル化反応 / 遷移金属触媒 / コバルト
Outline of Final Research Achievements

This project was focused on the developments and applications of catalytic alkylation reactions. The significant achievements are as follows. Alkyl-alkyl cross-coupling reactions using Fe, Co, Ni, and Cu along with unsaturated hydrocarbon additives were developed and examined in detail. The Cu catalyst shows quite high catalytic activity, achieving more than 1 million TON. The Co catalyst enables cross-coupling of tertiary alkyl Grignard regents to construct quaternary carbon centers. Site-selective alkylation of 1,3-dienes at the internal carbon was achieved by Cu catalyst. Ni catalyst enables multicomponent coupling reactions of 1,3-butadiene. We succeeded in isolation of anionic Ni complexes, that have been proposed as the key catalytic intermediates in the cross-coupling reactions.
Natural products containing a long alkyl chain were synthesized using Ni-catalysts. Another achievement includes development of chemical transformations of less reactive bonds such as C-F, C-O and C-H.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (107 results)

All 2017 2016 2015 2014 2013 Other

All Int'l Joint Research (1 results) Journal Article (17 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 17 results,  Acknowledgement Compliant: 9 results,  Open Access: 1 results) Presentation (85 results) (of which Int'l Joint Research: 20 results,  Invited: 14 results) Book (4 results)

  • [Int'l Joint Research] 湖南大学(中国)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Nickel-Catalyzed Dimerization and Alkylarylation of 1,3-Dienes with Alkyl Fluorides and Aryl Grignard Reagents2016

    • Author(s)
      Takanori Iwasaki, Xin Min, Asuka Fukuoka, Hitoshi Kuniyasu, and Nobuaki
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 18 Pages: 5550-5554

    • DOI

      10.1002/anie.201601126

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regioselective phosphorylation of myo-inositol with BINOL-derived phosphoramidites and its application for protozoan lysophosphatidylinositol.2016

    • Author(s)
      Aiba, T., Sato, M., Umegaki, D., Iwasaki, T., Kambe, N., Fukase, K., Fujimoto, Y.
    • Journal Title

      Org. Biomol. Chem.

      Volume: 14 Issue: 28 Pages: 6672-6675

    • DOI

      10.1039/c6ob01062h

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fe-Catalyzed Cross-Coupling Reaction of Vinylic Ethers with Aryl Grignard Reagents2016

    • Author(s)
      Takanori Iwasaki, Ryo Akimoto, Hitoshi Kuniyasu, and Nobuaki Kambe
    • Journal Title

      Chem. Asian J.

      Volume: 11 Issue: 20 Pages: 2834-2837

    • DOI

      10.1002/asia.201600972

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Multicomponent Coupling Reaction of Perfluoroarenes with 1,3-Butadiene and Aryl Grignard Reagents Promoted by an Anionic Ni(II) Complex2016

    • Author(s)
      Takanori Iwasaki, Asuka Fukuoka, Xin Min, Wataru Yokoyama, Hitoshi Kuniyasu, and Nobuaki Kambe
    • Journal Title

      Org. Lett.

      Volume: 18 Issue: 19 Pages: 4868-4871

    • DOI

      10.1021/acs.orglett.6b02343

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Regioselective Cis Insertion of DMAD into Au-P Bonds: Effect of Auxialiary Ligands on the Reaction Mechanism2015

    • Author(s)
      Hitoshi Kuniyasu, Takuya Nakajima, Takashi Tamaki, Takanori Iwasaki, Nobuaki Kambe
    • Journal Title

      Organometallics

      Volume: 34 Issue: 7 Pages: 1373-1376

    • DOI

      10.1021/acs.organomet.5b00078

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Copper-mediated thiolation of carbazole derivatives and related N-heterocycle compounds2015

    • Author(s)
      Longzhi Zhu, Xin Cao, Renhua Qiu, Takanori Iwasaki, Vutukuri Prakash Reddy, Xinhua Xu, Shuang-Feng Yin, and Nobuaki Kambe
    • Journal Title

      RSC Adv.

      Volume: 5 Issue: 49 Pages: 39358-39365

    • DOI

      10.1039/c5ra04965b

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Nickel-catalyzed synthesis of diarylsulfides and sulfones via C-H bond functionalization of arylamides2015

    • Author(s)
      Vutukuri Prakash Reddy, Renhua Qiu, Takanori Iwasaki, and Nobuaki Kambe
    • Journal Title

      Org. Biomol. Chem.

      Volume: 13 Issue: 24 Pages: 6803-6813

    • DOI

      10.1039/c5ob00149h

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Cu-Catalyzed Regioselective Hydroalkylation of 1,3-Dienes with Alkyl Fluorides and Grignard Reagents2015

    • Author(s)
      Takanori Iwasaki, Ryohei Shimizu, Reiko Imanishi, Hitoshi Kuniyasu, and Nobuaki Kambe
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 54 Issue: 32 Pages: 9347-9350

    • DOI

      10.1002/anie.201503288

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Palladium-Catalyzed Insertion Reactions of Isocyanides into Thiocarbamates and Selenocarbamates2015

    • Author(s)
      Daisuke Shiro, Shin-ichi Fujiwara, Susumu Tsuda, Takanori Iwasaki, Hitoshi Kuniyasu, Nobuaki Kambe
    • Journal Title

      Chem. Lett.

      Volume: 40 Issue: 4 Pages: 465-467

    • DOI

      10.1246/cl.141141

    • NAID

      130005062143

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] AlCl3-Catalyzed Insertion of Isocyanides into Nitrogen-Sulfur Bonds of Sulfenamides2015

    • Author(s)
      Daisuke Shiro, Shin-ichi Fujiwara, Susumu Tsuda, Takanori Iwasaki, Hitoshi Kuniyasu, Nobuaki Kambe
    • Journal Title

      Tetrahedron Lett.

      Volume: 56 Issue: 12 Pages: 1531-1534

    • DOI

      10.1016/j.tetlet.2015.01.096

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Cobalt-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Alkyl Grignard Reagents: A New Route to Constructing Quaternary Carbon Centers2014

    • Author(s)
      Takanori Iwasaki, Hiroaki Takagawa, Kanako Okamoto, Surya Prakash Singh, Hitoshi Kuniyasu, and Nobuaki Kambe
    • Journal Title

      Synthesis (PSP Article)

      Volume: 46 (12) Issue: 12 Pages: 1583-1592

    • DOI

      10.1055/s-0033-1341152

    • Related Report
      2014 Annual Research Report 2013 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Diarylrhodates as Promising Active Catalysts for the Arylation of Vinyl Ethers with Grignard Reagents2014

    • Author(s)
      Takanori Iwasaki, Yoshinori Miyata, Ryo Akimoto, Yuuki Fujii, Hitoshi Kuniyasu, and Nobuaki Kambe
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136 (26) Issue: 26 Pages: 9260-9263

    • DOI

      10.1021/ja5043534

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Copper-Catalyzed Alkyl-Alkyl Cross-Coupling Reactions Using Hydrocarbon Additives: Efficiency of Catalyst and Roles of Additives2014

    • Author(s)
      Takanori Iwasaki, Reiko Imanishi, Ryohei Shimizu, Hitoshi Kuniyasu, Jun Terao, and Nobuaki Kambe
    • Journal Title

      J. Org. Chem. (Featured Article)

      Volume: 79 (18) Issue: 18 Pages: 8522-8532

    • DOI

      10.1021/jo501006u

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Halogen Exchange by Reaction of CpRu(Cl)(PPh3)2 with MeC(O)X (X = Br, I) and its Mechanistic Study2014

    • Author(s)
      Hitoshi Kuniyasu, Atsushi Sanagawa, Takuya Nakajima, Takanori Iwasaki, Nobuaki Kambe, Karan Bobuatong, and Masahiro Ehara
    • Journal Title

      J. Organomet. Chem.

      Volume: 769 Pages: 34-37

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Palladium-Catalyzed Decarbonylative Rearrangement of N-Allenyl Seleno- and Tellurocarbamates2014

    • Author(s)
      Daisuke Shiro, Hiroyuki Nagai, Shin-ichi Fujiwara, Susumu Tsuda, Takanori Iwasaki, Hitoshi Kuniyasu, Nobuaki Kambe
    • Journal Title

      Heteroatom Chem.

      Volume: 25 Issue: 6 Pages: 518-524

    • DOI

      10.1002/hc.21217

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Co-Catalyzed Cross-Coupling of Alkyl Halides with Tertiary Alkyl Grignard Reagents Using a 1,3-Butadiene Additive2013

    • Author(s)
      T.Iwasaki, H.Takagawa, S.P.Singh, H.Kuniyasu, N.Kambe
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 135(26) Issue: 26 Pages: 9604-9607

    • DOI

      10.1021/ja404285b

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] (4) Facile Halogen Exchange Method between Au(Cl)(L) and MeC(O)X (L = PPh3 and IPr; X = Br and I) via -Bond Methathesis Supported by DFT Calculation2013

    • Author(s)
      Sanagawa, A.; Kuniyasu, H.; Nakane, D.; Iwasaki, T.; Kambe, N.; Bobuatong, K.; Ehara, M.
    • Journal Title

      Chem. Lett.

      Volume: 42 Issue: 8 Pages: 831-832

    • DOI

      10.1246/cl.130335

    • NAID

      10031189264

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 「シクロデキストリンを環状テンプレートとして利用したピラー[n]アレーン(n = 6, 7, 8)のサイズ選択的合成」2017

    • Author(s)
      倉田周弥、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      神奈川(慶應義塾大学 日吉キャンパス)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 「ニッケル触媒を用いたパーフルオロアレーン、アリールグリニャール試薬、1,3-ブタジエンの多成分反応とその機構研究」2017

    • Author(s)
      横山航、福岡明日香、閔欣、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      神奈川(慶應義塾大学 日吉キャンパス)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 「アルキル-アルキルクロスカップリング反応を利用したミコール酸類の合成研究」2017

    • Author(s)
      寺東祥平、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      神奈川(慶應義塾大学 日吉キャンパス)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 「コバルト触媒によるフッ化アルキルとアルキルグリニャール試薬とのクロスカップリング反応」2017

    • Author(s)
      山下晃司、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      神奈川(慶應義塾大学 日吉キャンパス)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] “Fe-catalyzed cross-coupling reaction of vinylic ethers with aryl Grignard reagents’’2017

    • Author(s)
      Takanori Iwasaki, Ryo Akimoto, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      Biotechnology and Chemistry for Green Growth
    • Place of Presentation
      Hyogo
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 「ニッケル触媒によるパーフルオロアレーン、アリールグリニャール試薬、1,3-ブタジエンとの多成分反応」2016

    • Author(s)
      横山航、福岡明日香、閔欣、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      第25回石油学会関西支部第61回日本エネルギー学会関西支部合同研究発表会
    • Place of Presentation
      京都(京都大学桂キャンパス)
    • Year and Date
      2016-12-09
    • Related Report
      2016 Annual Research Report
  • [Presentation] 「ハロゲン化アルキルによるアレン類のアルキル化反応」2016

    • Author(s)
      佐々木惟莉亜、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      第25回石油学会関西支部第61回日本エネルギー学会関西支部合同研究発表会
    • Place of Presentation
      京都(京都大学桂キャンパス)
    • Year and Date
      2016-12-09
    • Related Report
      2016 Annual Research Report
  • [Presentation] “Nickel-Catalyzed Multicomponent Coupling Reaction of 1,3-Dienes”2016

    • Author(s)
      Takanori Iwasaki, Xin Min, Asuka Fukuoka, Wataru Yokoyama, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      The 10th International Symposium on Integrated Synthesis (ISONIS-10)
    • Place of Presentation
      Hyogo
    • Year and Date
      2016-11-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 「アルキル-アルキルカップリング反応を基盤とするシクロプロパン含有脂肪酸の合成」2016

    • Author(s)
      寺東祥平、国安均、岩﨑孝紀、神戸宣明
    • Organizer
      第6回CSJ化学フェスタ2016
    • Place of Presentation
      東京(タワーホール船堀)
    • Year and Date
      2016-11-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 「酸フルオリドをフッ素源とするエポキシドの触媒的アロイルフッ素化反応」2016

    • Author(s)
      塩崎大悟、国安均、中﨑雅人、岩﨑孝紀、神戸宣明
    • Organizer
      第6回CSJ化学フェスタ2016
    • Place of Presentation
      東京(タワーホール船堀)
    • Year and Date
      2016-11-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] “Transition Metal Catalyzed Alkylation Reactions Using Fluoroalkanes”2016

    • Author(s)
      Nobuaki Kambe
    • Organizer
      International Symposium on Catalysis and Fine Chemicals 2016 (C&FC 2016)
    • Place of Presentation
      Taipei, China
    • Year and Date
      2016-11-11
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] “Fe-catalyzed cross-coupling reaction of vinylic ethers with aryl Grignard reagents”2016

    • Author(s)
      Takanori Iwasaki, Ryo Akimoto, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      International Symposium on C-O Activation (ISCO 2016)
    • Place of Presentation
      Hyogo
    • Year and Date
      2016-10-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] “Nickel-catalyzed multicomponent reaction of perfluoroarenes, aryl Grignard reagents, and two molecules of 1,3-butadiene”2016

    • Author(s)
      Wataru Yokoyama, Asuka Fukuoka, Xin Min, Takanori Iwasaki, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      International Symposium on C-O Activation (ISCO 2016)
    • Place of Presentation
      Hyogo
    • Year and Date
      2016-10-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] “Co-catalyzed cross-coupling reaction of alkyl fluorides with alkyl Grignard reagents”2016

    • Author(s)
      Koji Yamashita, Iwasaki, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      International Symposium on C-O Activation (ISCO 2016)
    • Place of Presentation
      Hyogo
    • Year and Date
      2016-10-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] “C-C Bond Formation Using Anionic Transition Metal Catalysts”2016

    • Author(s)
      Nobuaki Kambe
    • Organizer
      The 16th National Youth Conference on Catalysis (NYCC-16)
    • Place of Presentation
      Changsha, China
    • Year and Date
      2016-10-24
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 「遷移金属触媒を用いるC-F結合のC-C結合への変換反応」2016

    • Author(s)
      神戸宣明
    • Organizer
      フッ素化学研究講演会
    • Place of Presentation
      愛知(名古屋大学)
    • Year and Date
      2016-10-06
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 「ニッケル触媒によるフッ化アルキルおよびアリールグリニャール試薬によるジエンの二量化を伴ったアルキルアリール化反応」2016

    • Author(s)
      岩﨑孝紀、閔欣、福岡明日香、国安 均、神戸宣明
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      東京(早稲田大学西早稲田キャンパス)
    • Year and Date
      2016-09-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 「ニッケル触媒による1,3-ブタジエンの二量化を伴ったパーフルオロアレーン、アリールグリニャール試薬、1,3-ブタジエンとの多成分反応」2016

    • Author(s)
      横山航、福岡明日香、閔欣、岩﨑孝紀、国安 均、神戸宣明
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      東京(早稲田大学西早稲田キャンパス)
    • Year and Date
      2016-09-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 「酸フルオリドをフッ素源とするエポキシドの触媒的アロイルフッ素化反応」2016

    • Author(s)
      塩崎大悟、国安均、中﨑雅人、岩﨑孝紀、神戸宣明
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      東京(早稲田大学西早稲田キャンパス)
    • Year and Date
      2016-09-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] “Nickel-Catalyzed Dimerization and Alkylarylation of 1,3-Dienes with Alkyl Fluorides and Aryl Grignard Reagents’’2016

    • Author(s)
      Takanori Iwasaki, Asuka Fukuoka, Xin Min, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      Joint Symposium Aachen-Osaka
    • Place of Presentation
      Aachen, Germany
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] “Nickel-Catalyzed Dimerization and Alkylarylation of 1,3-Dienes with Alkyl Fluorides and Aryl Grignard Reagents’’2016

    • Author(s)
      Takanori Iwasaki, Xin Min, Asuka Fukuoka, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      20th International Symposium on Homogeneous Catalysis
    • Place of Presentation
      Kyoto
    • Year and Date
      2016-07-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] “Synthesis of Fatty Acids Containing Cyclopropane Ring through Ni-catalyzed Cross-coupling Reaction’’2016

    • Author(s)
      Shohei Terahigashi, Takanori Iwasaki, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      20th International Symposium on Homogeneous Catalysis
    • Place of Presentation
      Kyoto
    • Year and Date
      2016-07-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] “Nickel-Catalyzed Multicomponent Reaction of Perfluoroarenes, Aryl Grignard Reagents, and 1,3-Butadiene through Dimerization of 1,3-Butadiene’’2016

    • Author(s)
      Wataru Yokoyama, Asuka Fukuoka, Xin Min, Takanori Iwasaki, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      20th International Symposium on Homogeneous Catalysis
    • Place of Presentation
      Kyoto
    • Year and Date
      2016-07-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] “Co-Catalyzed Cross-Coupling Reaction of Alkyl Fluorides with Tertiary Alkyl Grignard Reagents’’2016

    • Author(s)
      Koji Yamashita, Takanori Iwasaki, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      20th International Symposium on Homogeneous Catalysis
    • Place of Presentation
      Kyoto
    • Year and Date
      2016-07-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 「ニッケル触媒による二量化を伴った1,3-ジエンのアルキルアリール化反応」2016

    • Author(s)
      岩﨑孝紀、閔欣、福岡明日香、国安 均、神戸宣明
    • Organizer
      第109回有機合成シンポジウム
    • Place of Presentation
      東京(東京工業大学大岡山キャンパス)
    • Year and Date
      2016-06-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] 「酸フルオリドをフッ素源とするエポキシドの触媒的フッ素化反応」2016

    • Author(s)
      塩崎大悟、国安均、中﨑雅人、岩﨑孝紀、神戸宣明
    • Organizer
      第5回JACI/GSCシンポジウム
    • Place of Presentation
      兵庫(ANAクラウンプラザホテル)
    • Year and Date
      2016-06-03
    • Related Report
      2016 Annual Research Report
  • [Presentation] 「遷移金属触媒を用いる飽和炭素鎖およびヘテロ原子団の導入反応」2016

    • Author(s)
      神戸宣明
    • Organizer
      石油学会第65回年会
    • Place of Presentation
      東京(タワーホテル船橋)
    • Year and Date
      2016-05-23
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] “Catalytic C-H Bond Functionalization Using Dichalcogenides and Chalcogenophenes’’2016

    • Author(s)
      Takanori Iwasaki, Vutukuri Prakash Reddy, Renhua Qiu, Nobuaki Kambe
    • Organizer
      The 13th International Conference on the Chemistry of Selenium and Tellurium
    • Place of Presentation
      Gifu
    • Year and Date
      2016-05-23
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 「遷移金属アニオン錯体がおもしろい」2016

    • Author(s)
      神戸宣明
    • Organizer
      セミナー
    • Place of Presentation
      千葉(三井化学)
    • Year and Date
      2016-05-18
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 「ニッケル触媒を用いた1,3-ブタジエンの二量化を伴うパーフルオロアレーンとアリールグリニャール試薬との多成分反応」2016

    • Author(s)
      閔欣、福岡明日香、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      京都(同志社大学京田辺キャンパス)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 「ニッケル触媒によるアルキル-アルキルクロスカップリング反応を利用したシクロプロパン含有脂肪酸の合成」2016

    • Author(s)
      寺東祥平、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      京都(同志社大学京田辺キャンパス)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 「銅触媒を用いた共役ジエン類のヒドロ及びアルキルパーフルオロアリール化反応」2016

    • Author(s)
      岡本華奈子、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      京都(同志社大学京田辺キャンパス)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] “Anionic Group 9 Transition Metal Complexes: Structure and Reactivities”2016

    • Author(s)
      Takanori Iwasaki, Hiroaki Takagawa, Kanako Okamoto, Suruya Prakash Singh, Yoshinori Miyata, Ryo Akimoto, Yuuki Fujii, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      Biotechnology and Chemistry for Green Growth
    • Place of Presentation
      Osaka (Japan)
    • Year and Date
      2016-03-09
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] “Rhodium-catalyzed arylation of vinyl ethers with Grignard reagents and its mechanistic studies using a flow micro reactor”2015

    • Author(s)
      Takanori Iwasaki, Ryo Akimoto, Yoshinori Miyata, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015 (PACIFICHEM 2015)
    • Place of Presentation
      Honolulu (America)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] “Ni-catalyzed dimerizative alkylarylation of 1,3-butadiene by alkyl halides and aryl Grignard reagents”2015

    • Author(s)
      Takanori Iwasaki, Asuka Fukuoka, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015 (PACIFICHEM 2015)
    • Place of Presentation
      Honolulu (America)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] “Nickel-Catalyzed Reaction of Perfluoroarenes with 1,3-Butadiene through Dimerization of 1,3-Butadiene”2015

    • Author(s)
      Xin Min, Takanori Iwasaki, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015 (PACIFICHEM 2015)
    • Place of Presentation
      Honolulu (America)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] “Cu-catalyzed Hydro- and Alkylperfluoroarylation of 1,3-Butadiene”2015

    • Author(s)
      Kanako Okamoto, Takanori Iwasaki, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015 (PACIFICHEM 2015)
    • Place of Presentation
      Honolulu (America)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 「ニッケル触媒による二量化を伴った1,3-ブタジエンのヒドロパーフルオロアリール化反応」2015

    • Author(s)
      閔欣、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      石油学会関西支部 第24回研究発表会
    • Place of Presentation
      大阪(大阪大学中之島センター)
    • Year and Date
      2015-12-04
    • Related Report
      2015 Annual Research Report
  • [Presentation] 「銅触媒を用いた共役ジエン類へのパーフルオロアリール基導入反応」2015

    • Author(s)
      岡本華奈子、岩﨑孝紀、 国安均、神戸宣明
    • Organizer
      第42回有機典型元素化学討論会
    • Place of Presentation
      愛知(名古屋大学野依記念学術交流館)
    • Year and Date
      2015-12-03
    • Related Report
      2015 Annual Research Report
  • [Presentation] “Nickel-Catalyzed Multi-Component Coupling Reaction of Perfluoroarenes, Alkyl Grignard Reagents, and 1,3-Butadiene”2015

    • Author(s)
      Xin Min, Takanori Iwasaki, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      The Eighth International Forum on Chemistry of Functional Organic Chemicals (IFOC-8)
    • Place of Presentation
      Tokyo (Japan)
    • Year and Date
      2015-11-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] “Copper-Catalyzed Regioselective Hydroalkylation of 1,3-Dienes with Alkyl Fluorides and Grignard Reagents”2015

    • Author(s)
      Takanori Iwasaki, Ryohei Shimizu, Reiko Imanishi, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13)
    • Place of Presentation
      Kyoto (Japan)
    • Year and Date
      2015-11-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 「銅触媒による1,3-ジエンの位置選択的ヒドロアルキル化反応」2015

    • Author(s)
      岩﨑孝紀、清水良平、今西怜子、国安 均、神戸宣明
    • Organizer
      第108回有機合成シンポジウム
    • Place of Presentation
      東京(早稲田大学国際会議場)
    • Year and Date
      2015-11-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] 「ニッケル触媒による二量化を伴った1,3-ブタジエンのヒドロパーフルオロアリール化反応」2015

    • Author(s)
      閔欣、岩﨑孝紀、国安 均、神戸宣明
    • Organizer
      第5回CSJ化学フェスタ2015 ―日本化学会秋季事業―
    • Place of Presentation
      東京(タワーホール船堀)
    • Year and Date
      2015-10-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 「鉄触媒を用いたアルケニルエーテルとグリニャール試薬とのクロスカップリング反応」2015

    • Author(s)
      秋本諒、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      第62回有機金属化学討論会
    • Place of Presentation
      大阪(関西大学千里山キャンパス)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] 「ニッケル触媒による1,3-ブタジエンの二量化を伴うパーフルオロアレーンとアルキルグリニャール試薬との反応 」2015

    • Author(s)
      閔欣、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      第62回有機金属化学討論会
    • Place of Presentation
      大阪(関西大学千里山キャンパス)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] “Carbon-Carbon Bond Forming Reactions Catalyzed by Transition Metal Ate Complexes”2015

    • Author(s)
      Nobuaki Kambe
    • Organizer
      The 7th Spanish Portuguese Japanese Organic Chemistry Symposium (7th SPJ-OCS)
    • Place of Presentation
      Seville (Spain)
    • Year and Date
      2015-06-03
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 「遷移金属触媒による1,3-ブタジエンのパーフルオロアリール化」2015

    • Author(s)
      岩﨑孝紀、閔欣、岡本華奈子、福岡明日香、国安 均、神戸宣明
    • Organizer
      石油学会第58回年会第20回JPIJSポスターセッション
    • Place of Presentation
      東京(タワーホール船堀)
    • Year and Date
      2015-05-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] 「遷移金属触媒による1,3-ブタジエンのアルキル化反応」2015

    • Author(s)
      岩﨑孝紀、清水良平、今西怜子、福岡明日香、国安 均、神戸宣明
    • Organizer
      石油学会第58回年会第64回研究発表会
    • Place of Presentation
      東京(タワーホール船堀)
    • Year and Date
      2015-05-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] 「ニッケル触媒によるフッ化アルキル、ブタジエン、アリールグリニャール試薬との多成分反応」2015

    • Author(s)
      岩﨑孝紀、福岡明日香、閔欣、国安 均、神戸宣明
    • Organizer
      第13回次世代を担う有機化学シンポジウム
    • Place of Presentation
      滋賀(立命館大学びわこ・くさつキャンパス)
    • Year and Date
      2015-05-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] 触媒反応開発研究と分析機器との繋がり2015

    • Author(s)
      岩﨑孝紀、宮田佳典、秋本 諒、藤井佑樹、国安 均、神戸宣明
    • Organizer
      島津製作所・大研科学産業講演会
    • Place of Presentation
      島津製作所関西支社マルチホール(大阪)
    • Year and Date
      2015-01-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Syntheses and Reactions of Organochalcogen Copmpounds Catalyzed by Transition Metals2014

    • Author(s)
      Nobuaki Kambe
    • Organizer
      IXXth International Symposium on Selected Problems of Chemistry of Acyclic and Cyclic Heteroorganic Compounds
    • Place of Presentation
      the CMMS PAS in Lodz (Poland)
    • Year and Date
      2014-11-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] Cleavage and Formation of Carbon-Fluorine Bonds2014

    • Author(s)
      Nobuaki Kambe
    • Organizer
      International Symposium on Advances in the Chemistry of Heteroorganic Compounds
    • Place of Presentation
      AJD University in Czeastochowa (Poland)
    • Year and Date
      2014-11-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Carbon-Carbon Bond Forming Reactions Catalyzed by Transition Metals Having Unsaturated Carbon Ligands2014

    • Author(s)
      Nobuaki Kambe
    • Organizer
      Vietnam Malaysia International Chemical Congress (VMICC)
    • Place of Presentation
      Hanoi(Vietnam)
    • Year and Date
      2014-11-07 – 2014-11-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] Transition Metal Catalyzed C-C Bond Forming Reactions Using Grignard Reagents2014

    • Author(s)
      神戸宣明
    • Organizer
      北興化学工業依頼講演
    • Place of Presentation
      北興化学工業(東京)
    • Year and Date
      2014-10-22
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Co-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Alkyl Grignard Reagents2014

    • Author(s)
      Takanori Iwasaki
    • Organizer
      ETH-OU Joint-Symposium
    • Place of Presentation
      Osaka
    • Year and Date
      2014-10-09
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ジアリールロデートを触媒活性種とする炭素―酸素結合の切断を伴うクロスカップリング反応2014

    • Author(s)
      岩﨑孝紀、宮田佳典、秋本 諒、藤井佑樹、国安 均、神戸宣明
    • Organizer
      第61回有機金属化学討論会
    • Place of Presentation
      九州大学(福岡)
    • Year and Date
      2014-09-23 – 2014-09-25
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 遷移金属触媒を用いるホスフィン配位子を使わない炭素骨格構築法2014

    • Author(s)
      神戸宣明
    • Organizer
      日本プロセス化学会
    • Place of Presentation
      船堀(東京)
    • Year and Date
      2014-07-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] Diarylrhodates as Promising Active Catalyst for the Arylation of Vinyl Ethers with Grignard Reagents2014

    • Author(s)
      Takanori Iwasaki
    • Organizer
      ICOMC 2014 Post-Symposium in Osaka “New Aspects of Reactive Organometallic Complexes of Transition Metals”
    • Place of Presentation
      Osaka
    • Year and Date
      2014-07-19
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Carbon-Carbon Bond Forming Reactions Catalyzed by Rhodium Complexes2014

    • Author(s)
      Nobuaki Kambe
    • Organizer
      The XXVI International Conference on Organometallic Chemistry (ICOMC 2014)
    • Place of Presentation
      Royton Sapporo(Hokkaido)
    • Year and Date
      2014-07-15
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] アニオン性ロジウム錯体による炭素―酸素結合の切断を伴うクロスカップリング反応2014

    • Author(s)
      岩﨑孝紀、宮田佳典、秋本 諒、国安 均、神戸宣明
    • Organizer
      第105回有機合成シンポジウム
    • Place of Presentation
      東京工業大学大岡山キャンパス(岡山)
    • Year and Date
      2014-06-10 – 2014-06-11
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 炭素-フッ素結合の切断を伴う有機合成反応2014

    • Author(s)
      神戸宣明
    • Organizer
      学術振興会116委員会
    • Place of Presentation
      学士会館(東京)
    • Year and Date
      2014-06-02
    • Related Report
      2014 Annual Research Report
  • [Presentation] Co-Catalyzed Cross-Coupling of Alkyl Halides with Tertiary Alkyl Grignard Reagents Using a 1,3-Butadiene Additive2014

    • Author(s)
      Takanori Iwasaki, Hiroaki Takagawa, Surya P. Singh, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス(愛知県)
    • Year and Date
      2014-03-27 – 2014-03-30
    • Related Report
      2013 Annual Research Report
  • [Presentation] 銅触媒を用いたα,β―アセチレニックエステルのヒドロフッ素化反応2014

    • Author(s)
      中﨑雅人、国安均、真川敦嗣、岩﨑孝紀、 Bobuatong, Karan、江原正博、神戸宣明
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス(愛知県)
    • Year and Date
      2014-03-27 – 2014-03-30
    • Related Report
      2013 Annual Research Report
  • [Presentation] パラジウム触媒を用いたイソシアニドのカルバモカルコゲナートへの挿入反応2014

    • Author(s)
      城 大輔、藤原眞一、津田 進、岩﨑孝紀、国安 均、神戸宣明
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス(愛知県)
    • Year and Date
      2014-03-27 – 2014-03-30
    • Related Report
      2013 Annual Research Report
  • [Presentation] Au-PPh3結合間へのDMADのシス挿入反応2014

    • Author(s)
      中島拓耶・国安 均・玉置喬士・岩﨑孝紀・神戸宣明
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス(愛知県)
    • Year and Date
      2014-03-27 – 2014-03-30
    • Related Report
      2013 Annual Research Report
  • [Presentation] ロジウム触媒を用いたビニルエーテル類とアリールグリニャール試薬とのクロスカップリング反応2014

    • Author(s)
      秋本 諒・宮田佳典・岩﨑孝紀・国安 均・神戸宣明
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス(愛知県)
    • Year and Date
      2014-03-27 – 2014-03-30
    • Related Report
      2013 Annual Research Report
  • [Presentation] Pd/Xantphos触媒存在下、CsF/ArI/18-crown-6を用いたアレン類のアリールフッ素化反応2013

    • Author(s)
      若狭崇志・国安 均・真川敦嗣・岩﨑孝紀・ 神戸宣明
    • Organizer
      石油学会関西支部 第22回研究発表会
    • Place of Presentation
      近畿大学東大阪キャンパス(大阪府)
    • Year and Date
      2013-12-06
    • Related Report
      2013 Annual Research Report
  • [Presentation] シクロデキストリンの不斉場を利用したロジウム触媒によるアリールボロン酸のエノン類へのエナンチオ選択的1,4-付加反応2013

    • Author(s)
      高橋亮太、津田 進、岩﨑孝紀、朝日 薫、藤原 眞一、国安 均、神戸宣明
    • Organizer
      第40回有機典型元素化学討論会
    • Place of Presentation
      近畿大学11月ホール(大阪府)
    • Year and Date
      2013-12-05 – 2013-12-07
    • Related Report
      2013 Annual Research Report
  • [Presentation] パラジウム触媒を用いたカルコゲノカーバメートのイソシアニドへの付加反応2013

    • Author(s)
      城 大輔、藤原眞一、津田 進、岩﨑孝紀、国安 均、神戸宣明
    • Organizer
      第40回有機典型元素化学討論会
    • Place of Presentation
      近畿大学11月ホール(大阪府)
    • Year and Date
      2013-12-05 – 2013-12-07
    • Related Report
      2013 Annual Research Report
  • [Presentation] コバルト触媒を用いた三級アルキルグリニャール試薬とアルキルハライドとのクロスカップリング反応2013

    • Author(s)
      岩﨑孝紀、高川裕章、Singh, Surya P.、国安均、神戸宣明
    • Organizer
      第39回反応と合成の進歩シンポジウム
    • Place of Presentation
      九州大学医学部百年講堂(福岡県)
    • Year and Date
      2013-11-05 – 2013-11-06
    • Related Report
      2013 Annual Research Report
  • [Presentation] 銅触媒を用いる効率的sp3炭素間結合形成反応-触媒効率と不飽和炭化水素配位子の役割―2013

    • Author(s)
      今西怜子、清水良平、岩﨑孝紀、寺尾 潤、国安 均、神戸宣明
    • Organizer
      第3回CSJ化学フェスタ2013 ―日本化学会秋季事業―
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2013-10-21 – 2013-10-23
    • Related Report
      2013 Annual Research Report
  • [Presentation] パラジウム触媒を用いたN-アレニルセレノカーバメートの環化付加反応と脱一酸化炭素を伴う転位反応2013

    • Author(s)
      城 大輔、永井裕之、藤原眞一、津田 進、岩﨑孝紀、国安 均、神戸宣明
    • Organizer
      第3回CSJ化学フェスタ2013 ―日本化学会秋季事業―
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2013-10-21 – 2013-10-23
    • Related Report
      2013 Annual Research Report
  • [Presentation] Cross-Coupling of Tertiary Alkyl Grignard Reagents with Alkyl Halides Catalyzed by Cobalt Using 1,3-Butadiene as an Additive2013

    • Author(s)
      Takanori Iwasaki, Hiroaki Takagawa, Surya P. Singh, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      10th International Symposium on Carbanion Chemistry (ISCC-10)
    • Place of Presentation
      Kyoto
    • Year and Date
      2013-09-23 – 2013-09-26
    • Related Report
      2013 Annual Research Report
  • [Presentation] 銅触媒を用いるアルキル-アルキルクロスカップリング反応-触媒効率と不飽和炭化水素配位子の役割2013

    • Author(s)
      今西怜子、清水良平、岩﨑孝紀、国安 均、神戸宣明
    • Organizer
      第60回有機金属化学討論会
    • Place of Presentation
      学習院大学(東京都)
    • Year and Date
      2013-09-12 – 2013-09-14
    • Related Report
      2013 Annual Research Report
  • [Presentation] Pd/Xantphos触媒存在下、CsF/ArI/18-crown-6を用いたアレン類のアリールフッ素化反応2013

    • Author(s)
      若狭崇志・国安 均・真川敦嗣・岩﨑孝紀・ 神戸宣明
    • Organizer
      第60回有機金属化学討論会
    • Place of Presentation
      学習院大学(東京都)
    • Year and Date
      2013-09-12 – 2013-09-14
    • Related Report
      2013 Annual Research Report
  • [Presentation] シグマ結合メタセシスを経る金ハライドのハロゲン交換反応:簡便な合成反応としての利用と機構に関するDFT計算2013

    • Author(s)
      真川敦嗣、国安 均、岩崎孝紀、ボブアトング カラン、江原 正博、神戸 宣明
    • Organizer
      第60回有機金属化学討論会
    • Place of Presentation
      学習院大学(東京都)
    • Year and Date
      2013-09-12 – 2013-09-14
    • Related Report
      2013 Annual Research Report
  • [Presentation] CD連結NHC配位子-ロジウム触媒によるエノン類へのアリールボロン酸の1,4-付加反応-生成物キラリティーの反転2013

    • Author(s)
      高橋亮太、津田 進、岩﨑孝紀、朝日 薫、藤原 眞一、国安 均、神戸宣明
    • Organizer
      第30回シクロデキストリンシンポジウム
    • Place of Presentation
      くまもと県民交流館パレア(熊本県)
    • Year and Date
      2013-09-12 – 2013-09-13
    • Related Report
      2013 Annual Research Report
  • [Presentation] Co-catalyzed cross-coupling of alkyl halides with alkyl Grignard reagents2013

    • Author(s)
      Takanori Iwasaki, Hiroaki Takagawa, Jun Terao, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      The Sixteenth International Symposium on Relations between Homogeneous and Heterogeneous Catalysis (ISHHC-16)
    • Place of Presentation
      Hokkaido
    • Year and Date
      2013-08-04 – 2013-08-09
    • Related Report
      2013 Annual Research Report
  • [Presentation] Facile Halogen Exchange Reaction between Au(Cl)(L) and MeC(O)X(L = PPh3 and IPr; X = Br and I) viaσ61555;-Bond Metathesis Supported by DFT Calculation2013

    • Author(s)
      Atsushi Sanagawa, Hitoshi Kuniyasu, Bobuatong Karan, Lu Yunpeng, Masahiro Ehara, Nobuaki Kambe
    • Organizer
      The Sixteenth International Symposium on Relations between Homogeneous and Heterogeneous Catalysis (ISHHC-16)
    • Place of Presentation
      Hokkaido
    • Year and Date
      2013-08-04 – 2013-08-09
    • Related Report
      2013 Annual Research Report
  • [Presentation] Co-Catalyzed Cross-Coupling of Alkyl Halides with Tertiary Alkyl Grignard Reagents Using a 1,3-Butadiene Additive2013

    • Author(s)
      Takanori Iwasaki, Hiroaki Takagawa, Surya P. Singh, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      20th International Symposium on Olefin Metathesis and Related Chemistry (ISOM-20)
    • Place of Presentation
      Nara
    • Year and Date
      2013-07-14 – 2013-07-19
    • Related Report
      2013 Annual Research Report
  • [Presentation] Highly Effective Copper-Catalyzed sp3(C)-sp3(C) Bond Forming Reaction2013

    • Author(s)
      Reiko Imanishi, Ryohei Shimizu, Takanori Iwasaki, Jun Terao, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      20th International Symposium on Olefin Metathesis and Related Chemistry (ISOM-20)
    • Place of Presentation
      Nara
    • Year and Date
      2013-07-14 – 2013-07-19
    • Related Report
      2013 Annual Research Report
  • [Presentation] 銅触媒を用いたアルキンのヒドロフッ素化反応2013

    • Author(s)
      中﨑雅人、真川敦嗣、岩﨑孝紀、国安 均、神戸宣明
    • Organizer
      第46回有機金属若手の会 夏の学校
    • Place of Presentation
      宮城蔵王ロイヤルホテル(仙台)
    • Year and Date
      2013-07-08 – 2013-07-10
    • Related Report
      2013 Annual Research Report
  • [Presentation] アニオン性遷移金属種を鍵活性種とする炭素―炭素結合形成反応2013

    • Author(s)
      岩﨑孝紀
    • Organizer
      第2回新学術領域研究「反応集積化学」若手合宿
    • Place of Presentation
      八の坊(静岡県)
    • Year and Date
      2013-06-21 – 2013-06-22
    • Related Report
      2013 Annual Research Report
  • [Presentation] 高活性銅触媒によるアルキル―アルキルクロスカップリング反応2013

    • Author(s)
      岩﨑孝紀、今西怜子、清水良平、寺尾潤、国安均、神戸宣明
    • Organizer
      第2回JACI/GSCシンポジウム
    • Place of Presentation
      メルパルク大阪(大阪府)
    • Year and Date
      2013-06-06 – 2013-06-07
    • Related Report
      2013 Annual Research Report
  • [Presentation] 遷移金属触媒による2級および3級炭素上でのクロスカップリング反応2013

    • Author(s)
      岩﨑孝紀、高川裕章、沈如偉、寺尾潤、国安均、神戸宣明
    • Organizer
      第103回有機合成シンポジウム
    • Place of Presentation
      慶應義塾大学薬学部マルチメディア講堂(東京都)
    • Year and Date
      2013-06-05 – 2013-06-06
    • Related Report
      2013 Annual Research Report
  • [Book] Ni-Catalyzed C-C Couplings Using Alkyl Electrophiles2016

    • Author(s)
      Takanori Iwasaki, Nobuaki Kambe
    • Total Pages
      36
    • Publisher
      Springer
    • Related Report
      2016 Annual Research Report
  • [Book] 光を用いてNiの酸化状態を制御する-Ni触媒を用いたクロスカップリング反応の新展開2016

    • Author(s)
      岩﨑孝紀,神戸宣明
    • Total Pages
      2
    • Publisher
      化学同人
    • Related Report
      2016 Annual Research Report
  • [Book] Coupling Reactions Between sp3 Carbon Centers. In Gary A. Molander and Paul Knochel (eds)2014

    • Author(s)
      Takanori Iwasaki, and Nobuaki Kambe
    • Total Pages
      45
    • Publisher
      Comprehensive Organic Synthesis
    • Related Report
      2014 Annual Research Report
  • [Book] Coupling Reaction Between sp3-Carbon Centers2014

    • Author(s)
      Takanori Iwasaki, Nobuaki Kambe
    • Total Pages
      54
    • Publisher
      Elsevier
    • Related Report
      2013 Annual Research Report

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Published: 2013-06-20   Modified: 2022-02-07  

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