Organic Synthesis Using Various Valences of Iodine Reagents
| Project/Area Number |
25288047
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
Minakata Satoshi 大阪大学, 工学(系)研究科(研究院), 教授 (90273599)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Fiscal Year 2015: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥10,660,000 (Direct Cost: ¥8,200,000、Indirect Cost: ¥2,460,000)
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| Keywords | ヨウ素 / 超原子価ヨウ素 / 触媒反応 / アミノ化 / アミノ化反応 / 脱炭酸 / 酸化反応 / ハロゲン結合 / 不斉合成 |
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| Outline of Final Research Achievements |
This research project was carried out for the development of novel iodine reagents, especially iodine(I), (III), and (V) compounds, and their use in organic synthesis. The synthesis of iodine(I) reagents, which has an unique Lewis acidity, and its application to organic reactions were achieved. In addition, novel iodine(III) reagents containing nitrogen functional groups as a ligand were successfully synthesized, and they could be applied to amination reactions. The new type of amination reaction using iodine(V) reagents was also developed.
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Report
(4 results)
Research Products
(31 results)
