| Project/Area Number |
25288054
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Kobe University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
竹内 俊文 神戸大学, 工学研究科, 教授 (70179612)
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| Co-Investigator(Renkei-kenkyūsha) |
MINAMI Hideto 神戸大学, 大学工学研究科, 准教授 (20283872)
SUZUKI Toyoko 神戸大学, 大学工学研究科, 助教 (40314504)
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| Research Collaborator |
CHAIYASAT Amorn
CHAIYASAT Preeyaporn Rajamangala University of Technology Thanyaburi, Faculty of Science and Technology
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| Project Period (FY) |
2013-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥18,070,000 (Direct Cost: ¥13,900,000、Indirect Cost: ¥4,170,000)
Fiscal Year 2016: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2015: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2014: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2013: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
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| Keywords | 制御・リビングラジカル重合 / 乳化重合 / マイクロサスペンション重合 / 蓄熱材 / カプセル / 微粒子 / 異形 / バイオセンサー / 中空高分子微粒子 / 重合開始剤 / 開始剤切片の埋没 / ノニオン性界面活性剤 / 過硫酸カリウム / 機能性微粒子 / マイクロカプセル / 制御リビングラジカル重合 / 蓄熱剤 / 高分子合成 / 機能性高分子微粒子 / 蓄熱カプセル粒子 / タンパク質認識微粒子 / 異形高分子微粒子 / センサー / 制御/リビングラジカル重合 / ミニエマルション重合 / ナノ粒子 |
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| Outline of Final Research Achievements |
We have tried to apply controlled/living radical polymerization (CLRP), which has been so far mainly developed in homogeneous systems, to aqueous dispersed systems and gotten better harvests than expected. Especially, development of emulsifier-free emulsion polymerization, synthesis of high molecular weight (>10e6), monodisperse polystyrene particles, Syntheses of Janus type nonspherical polymer particles by applying CLRP at the limited locus of polymerization at a particle surface, high performance heat storage microcapsule particles, micrometer-size hydrophilic polymer particles without submicrometer-size byproduct particles, and polymer particles having biosensor functionality have been successfully conducted. These results will contribute to overcoming the long-standing problem and creation of novel functional polymer particles.
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