Synthesis and Application of New Functional Polymers Utilizing the Structural Feature of Vicinal Tri-and Tertacarbonyl Compound

• Project/Area Number: 25288060
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Partial Multi-year Fund
• Section: 一般
• Research Field: Polymer chemistry
• Research Institution: Kinki University
• Principal Investigator: ENDO Takeshi 近畿大学, 分子工学研究所, 教授 (40016738)
• Co-Investigator(Kenkyū-buntansha): FURUSHO Yoshio 滋賀医科大学, 医学部, 教授 (00281270) ; YAMADA Shuhei 近畿大学, 分子工学研究所, 助教 (00615932)
• Project Period (FY): 2013-04-01 – 2016-03-31
• Project Status: Completed (Fiscal Year 2015)
• Budget Amount: ¥13,780,000 (Direct Cost: ¥10,600,000、Indirect Cost: ¥3,180,000); Fiscal Year 2015: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000); Fiscal Year 2014: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000); Fiscal Year 2013: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
• Keywords: 機能性高分子 / トリカルボニル / ネットワークポリマー / 可逆な共有結合 / 隣接トリカルボニル / 水酸基含有ポリマー / 架橋 / 解架橋 / 隣接ポリカルボニル / レドックス特性

Outline of Final Research Achievements

By utilizing the fact that the vicinal tri-and tetracarbonyl compound undergo reversible addition over elimination reaction with water and alcohols, networked polymers of series of hydroxy group-containing polymer are constructed by the use of tri-and tetra carbonyl compound as cross-linking agent. Furthermore, the de-crosslinking of obtained networked polymer proceeds with the addition of water, and the original polymer are recovered in high yield.

Research Products

• [Journal Article] Reversible addition and elimination of alcohols by vicinal tetracarbonyl compound (2016)
  • Author(s): Shinya Maeda, Atsushi Sudo, Takeshi Endo
  • Journal Title: Tetrahedron Letters Volume: 57 Issue: 10 Pages: 1061-1065
  • DOI: 10.1016/j.tetlet.2015.12.112
  • Peer Reviewed
• [Journal Article] Reversible Capture and Release of Aromatic Amines by Vicinal Tricarbonyl Compound (2016)
  • Author(s): Tatsuya Yuki, Morio Yonekawa, Yoshio Furusho, Yoshihisa Sei, Ikuyoshi Tomita, Takeshi Endo
  • Journal Title: Tetrahedron Volume: 印刷中 Issue: 22 Pages: 2868-2873
  • DOI: 10.1016/j.tet.2016.03.093
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Construction of reversible crosslinking-decrosslinking system consisting of a polymer bearing vicinal tricarbonyl structure and poly(ethylene glycol) (2016)
  • Author(s): Yuki, T.; Yonekawa, M.; Matsumoto, K.; Tomita, I.; Endo, T.
  • Journal Title: Polym. Bull. Volume: 73 Issue: 2 Pages: 345-345
  • DOI: 10.1007/s00289-015-1490-5
  • Peer Reviewed
• [Journal Article] Reversible crosslinking and decrosslinking of polymers containing alcohol moiety using an acyclic bifunctional vicinal triketone (2014)
  • Author(s): Takeshi Endo et al.
  • Journal Title: J. Polym. Sci., Part A: Polym. Chem. Volume: 52 Issue: 7 Pages: 921-928
  • DOI: 10.1002/pola.27087
  • Peer Reviewed
• [Journal Article] Synthesis and x-ray structural analysis of an acyclic bifunctional vicinal triketone, its hydrate, and its ethanol-adduct (2013)
  • Author(s): Takeshi Endo et al.
  • Journal Title: Tetrahedron Volume: 69 Issue: 20 Pages: 4076-4080
  • DOI: 10.1016/j.tet.2013.03.065
  • Peer Reviewed
• [Presentation] 隣接トリカルボニル構造をもつポリマーと水酸基含有ポリマー系による架橋―解架橋挙動 (2015)
  • Author(s): 柚木辰也・米川盛生・松本幸三・冨田育義・遠藤剛
  • Organizer: 第65回ネットワークポリマー講演討論会
  • Place of Presentation: 新潟大学五十嵐キャンパス (新潟市)
  • Year and Date: 2015-10-07
• [Presentation] 隣接トリカルボニル構造をもつポリマーと水酸基含有ポリマー系による架橋―解架橋挙動 (2014)
  • Author(s): 柚木辰也・米川盛生・松本幸三・冨田育義・遠藤剛
  • Organizer: 第64回ネットワークポリマー講演討論会
  • Place of Presentation: 関西大学千里山キャンパス（大阪府吹田市）
  • Year and Date: 2014-10-22 – 2014-10-24
• [Presentation] 隣接トリカルボニル構造をもつポリマーと水酸基含有ポリマー系による架橋―解架橋挙動 (2014)
  • Author(s): 柚木辰也・米川盛生・松本幸三・冨田育義・遠藤剛
  • Organizer: 第63回高分子討論会
  • Place of Presentation: 長崎大学文教キャンパス（長崎県長崎市）
  • Year and Date: 2014-09-24 – 2014-09-26
• [Presentation] 隣接トリカルボニル構造をもつポリマーと水酸基含有ポリマー系による架橋―解架橋挙動 (2014)
  • Author(s): 柚木辰也・米川盛生・松本幸三・遠藤剛
  • Organizer: 第63回高分子学会年次大会
  • Place of Presentation: 名古屋国際会議場（愛知県名古屋市）
  • Year and Date: 2014-05-28 – 2014-05-30
• [Presentation] 隣接テトラカルボニル基への可逆的なアルコールの付加-脱離反応による構造変換およびネットワークポリマーへの応用 (2013)
  • Author(s): 前田真也・米川盛生・古荘義雄・遠藤剛
  • Organizer: 第62回高分子学会年次大会
  • Place of Presentation: 京都国際会館（京都府）
• [Presentation] 二官能性隣接トリカルボニル化合物の合成とそれを用いた多官能アルコール性ポリマーの可逆的な架橋-解架橋 (2013)
  • Author(s): 米川盛生・古荘義雄・遠藤剛
  • Organizer: 第62回高分子学会年次大会
  • Place of Presentation: 京都国際会館（京都府）
• [Remarks] 近畿大学分子工学研究所
  • URL: http://www.moleng.fuk.kindai.ac.jp/index.html