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Development of honeycomb-structued catalyst system for rapidly and effectively transforming C1-besed moleculars

Research Project

Project/Area Number 25289279
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Reaction engineering/Process system
Research InstitutionShizuoka University

Principal Investigator

Fukuhara Choji  静岡大学, 工学部, 教授 (30199260)

Co-Investigator(Kenkyū-buntansha) KOHNO Yoshimi  静岡大学, 工学部, 准教授 (50334959)
RYO WATANABE  静岡大学, 工学部, 助教 (80548884)
立元 雄治  静岡大学, 工学部, 准教授 (00324335)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2015: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2013: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Keywords構造体触媒 / メタルハニカム / 水蒸気改質 / メタネーション / ドライ改質 / CO2変換 / 水素製造 / 合成ガス製造 / 触媒反応システム / 新エネルギー / ハニカム触媒 / 二酸化炭素の利活用 / カーボン捕集 / 燃料電池 / 炭素資源 / 二酸化炭素 / 二酸化炭素削減
Outline of Final Research Achievements

In order to rapidly and effectively transform C1-type small molecule such as CO2, a structured reaction system for methanation was constructed. Furthermore, the structured reaction systems were constructed for dry-reforming CH4 and for decomposing CH4 to hydrogen and carbon. The structured catalysts for various reactions were based on the nickel-type catalyst, which were prepared using wash-coat method and using the combination technique of sol-gel method and electroless plating. From the viewpoints of catalyst activity and catalyst life, the prepared catalysts indicated a high performance for each reaction. It was concluded that the constructed catalyst systems had a powerful performance to produce an energy source from C1-type molecular.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (36 results)

All 2016 2015 2014 2013

All Journal Article (12 results) (of which Peer Reviewed: 12 results,  Acknowledgement Compliant: 2 results) Presentation (20 results) (of which Int'l Joint Research: 7 results,  Invited: 1 results) Patent(Industrial Property Rights) (4 results)

  • [Journal Article] Fixation and stability enhancement of beta-carotene by organo-modified mesoporous silica2016

    • Author(s)
      Yoshiumi Kohno, Yasushi Kato, Masashi Shibata, Choji Fukuhara, Yasuhisa Maeda, Yasumasa Tomita, and Kenkichiro Kobayashi
    • Journal Title

      Microporous Mesoporous Mater.

      Volume: 220 Pages: 1-6

    • DOI

      10.1016/j.micromeso.2015.08.019

    • NAID

      120006457910

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of ethylbenzene dehydrogenation of perovskite-type BaZrO3 catalyst by a small amount of Fe substitution in the B-site2015

    • Author(s)
      Ryo Watanabe, Yoshinori Saito, Choji Fukuhara
    • Journal Title

      Journal of Molecular Catalysis A: Chemical

      Volume: 404-405 Pages: 57-64

    • DOI

      10.1016/j.molcata.2015.04.010

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Dehydrogenation of Methylcyclohexane over Pt/TiO2 Catalyst2015

    • Author(s)
      Satoshi Nagatake, Takuma Higa, Shuhei Ogo, Yukihiro Sugiura, Ryo Watanabe, Choji Fukuhara, Yasushi Sekine
    • Journal Title

      Catalysis Letters

      Volume: 146 Issue: 1 Pages: 54-60

    • DOI

      10.1007/s10562-015-1623-3

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A metal-honeycomb-type structured catalyst for steam reforming of methane: Effect of preparation condition change on reforming performance2015

    • Author(s)
      Choji Fukuhara, Kazumasa Yamamoto, Yudai Makiyama, Wataru Kawasaki, Ryo Watanabe
    • Journal Title

      Journal of Catalysis A: General

      Volume: 492 Pages: 190-200

    • DOI

      10.1016/j.apcata.2014.11.040

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] High tolerance to coke deposition in methane steam reforming for yttria stabilized zirconia catalyst supported Ni by electroless plating2015

    • Author(s)
      Ryo Watanabe, Wataru Kawasaki, Ma Xiaojun, Choji Fukuhara
    • Journal Title

      Chemistry Letters

      Volume: 44 Pages: 82-84

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of water density on heterogeneous catalytic water gas shift reaction in the presence of Ru/C, Pd/LaCoO3 and Fe3O4 in supercritical water2015

    • Author(s)
      Takafumi Sato, Ryo Watanabe, Choji Fukuhara, Naotsugu Itoh
    • Journal Title

      The Journal of Supercritical Fluids

      Volume: 97 Pages: 211-216

    • DOI

      10.1016/j.supflu.2014.12.003

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dehydrogenation of ethylbenzene over zironium-based perovskite-type catalysts of AZrO3 (A: Ca, Sr, Ba)2014

    • Author(s)
      Ryo Watanabe, Yoshinori Sato, Choji Fukuhara
    • Journal Title

      Applied Catalysis A: General

      Volume: 482 Pages: 344-351

    • DOI

      10.1016/j.apcata.2014.06.012

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improved photostability of hydrophobic natural dye incorporated in organo-modified hydrotalcite2014

    • Author(s)
      Yoshiumi Kohno, Saeko Asai, Masashi Shibata, Choji Fukuhara, Yasuhisa Maeda, Yasumasa Tomita, and Kenkichiro Kobayashi
    • Journal Title

      J. Phys. Chem. Solids

      Volume: 75 Issue: 8 Pages: 945-50

    • DOI

      10.1016/j.jpcs.2014.04.010

    • NAID

      120005531425

    • Related Report
      2014 Annual Research Report 2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pd-supporting LaCoO3 catalyst with structured configuration for water gas shift reaction2014

    • Author(s)
      Ryo Watanabe, Yusuke Fujita, Tomohiro Tagawa, Kazumasa Yamamoto, Takeshi Furusawa, Choji Fukuhara
    • Journal Title

      Applied Catalysis A: General

      Volume: 477 Pages: 75-82

    • DOI

      10.1016/j.apcata.2014.03.005

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption behavior of natural anthocyanin dye on mesoporous silica2014

    • Author(s)
      Yoshiumi Kohno, Eriko Haga, Keiko Yoda, Masashi Shibata, Choji Fukuhara, Yasumasa Tomita, Yasuhisa Maeda, Kenkichiro Kobayashi
    • Journal Title

      Journal of Physics and Chemistry of Solids

      Volume: 75 Issue: 1 Pages: 48-51

    • DOI

      10.1016/j.jpcs.2013.08.007

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A novel nickel-based catalyst for methane dry reforming: A metal honeycomb-type catalyst prepared by sol-gel method and electroless plating2013

    • Author(s)
      Choji Fukuhara, Ryogo Hyodo, Kazumasa Yamamoto, Ryo Watanabe
    • Journal Title

      Applied Catalysis A: General

      Volume: 468 Pages: 18-25

    • DOI

      10.1016/j.apcata.2013.08.024

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stable and selective perovskite catalyst for dehydrogenation of propane working with redox mechanism2013

    • Author(s)
      R. Watanabe, Y. Hondo, K. Mukawa, C. Fukuhara, E. Kikuchi, Y. Sekine
    • Journal Title

      Applied Journal of Molecular Catalysis A : Chemical

      Volume: vol.377 Pages: 74-84

    • DOI

      10.1016/j.molcata.2013.04.033

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Effect of preparation condition change of Ni/Al2O3 structured catalyst on CO2 dry-reforming performance2015

    • Author(s)
      Takeo Osuka,Yoshiumi Kono,Ryo Watanabe,Choji Fukuhara
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      Hyatto Regency Waikiki Beach Resort and Spa (Hawaii, USA)
    • Year and Date
      2015-12-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A novel platinum-based catalyst for methylcyclohexane dehydrogenation in hydrogen storage and utilization technology2015

    • Author(s)
      Yoshikazu Hisamatsu,Kazumasa Yamamoto,Kota Tanaka,Ryo Watanabe,Choji Fukuhara
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      Hyatto Regency Waikiki Beach Resort and Spa (Hawaii, USA)
    • Year and Date
      2015-12-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Characterization of a novel Ni/YSZ catalyst with strong tolerance to carbon deposition for direct internal reforming (DIR)-SOFC2015

    • Author(s)
      Wataru Kawasaki,Yoshiumi Kono,Ryo Watanabe,Choji Fukuhara
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      Hyatto Regency Waikiki Beach Resort and Spa (Hawaii, USA)
    • Year and Date
      2015-12-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrothermal symthesis of structure-type iron oxide catalyst for water gas shift reaction2015

    • Author(s)
      Ryo Watanabe,Syuhei Watanabe,Choji Fukuhara
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      Hyatto Regency Waikiki Beach Resort and Spa (Hawaii, USA)
    • Year and Date
      2015-12-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A honeycomb-type Ni/CeO2 catalyst for CO2 methanation to transform greenhouse gas into useful resources2015

    • Author(s)
      Choji Fukuhara,Kotaro Hayakawa,Katsunori Murabayashi,Yosiumi Khono,Ryo Watanabe
    • Organizer
      The Asia Pacific Confederation of Chemical Engineering (APCChE)
    • Place of Presentation
      Melbourne Convention and Exhibition Centre (Melbourne, Australia)
    • Year and Date
      2015-09-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Iron oxide-type structured catalyst for water gas shift reaction2015

    • Author(s)
      Ryo Watanabe,Syuhei Watanabe,Choji Fukuhara
    • Organizer
      The Asia Pacific Confederation of Chemical Engineering (APCChE)
    • Place of Presentation
      Melbourne Convention and Exhibition Centre (Melbourne, Australia)
    • Year and Date
      2015-09-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A metal-honeycomb-type catalyst for methane dry reforming: effect of preparation condition change on reforming performance2015

    • Author(s)
      Choji Fukuhara,Takeo Ohsuka,Kazumasa Yamamoto,Wataru Kawasaki,Ryo Watanabe
    • Organizer
      13th International Conference on Carbon Dixoide Utilization
    • Place of Presentation
      National University of Singapore (Singapore)
    • Year and Date
      2015-07-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A nickel-based-honeycomb-type catalyst for dry reforming of methane2014

    • Author(s)
      Choji Fukuhara, Kazumasa Yamamoto, Takeo Ohsuka, Ryo Watanabe
    • Organizer
      23th International Symposium on Chemical Reaction Engineering (ISCRE23)
    • Place of Presentation
      Bangkok Convention Centre (Bangkok, Thailand)
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Yttria stabilized zirconia catalyst supported Ni by electroless plating, for SOFC anode with direct internal reforming2014

    • Author(s)
      Ryo Watanabe, Wataru Kawasaki, Choji Fukuhara
    • Organizer
      Grand Renewable Energy 2014
    • Place of Presentation
      Tokyo Big Site (Tokyo, Japan)
    • Year and Date
      2014-07-27 – 2014-07-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] Positive effect of oxidation treatment on methane dry reforming performance of Ni-based structured catalyst2014

    • Author(s)
      Takeo Ohsuka, Keigo Masuda, Ryo Watanabe, Choji Fukuhara
    • Organizer
      7th Tokyo Conference on Advanced Catalytic Science and Technology
    • Place of Presentation
      Kyoto Tersa (Kyoto, Japan)
    • Year and Date
      2014-06-01 – 2014-06-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Methane reforming property of Ni/YSZ catalyst prepared by electroless plating for SOFC anode with internal reforming2014

    • Author(s)
      Wataru Kawasaki, Xiaojun Ma, Ryo Watanabe, Choji Fukuhara
    • Organizer
      7th Tokyo Conference on Advanced Catalytic Science and Technology
    • Place of Presentation
      Kyoto Tersa (Kyoto, Japan)
    • Year and Date
      2014-06-01 – 2014-06-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Effect of nickel precursor type in electroless plating on methane reforming performance of Ni.Al2O3 structured catalyst2014

    • Author(s)
      Kazumasa Yamamoto, Yudai Makiyama, Ryo Watanabe, Choji Fukuhara
    • Organizer
      7th Tokyo Conference on Advanced Catalytic Science and Technology
    • Place of Presentation
      Kyoto Tersa (Kyoto, Japan)
    • Year and Date
      2014-06-01 – 2014-06-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Development and performance of novel Ni-based catalyst for CO2 methanation2014

    • Author(s)
      Kotaro Hayakawa, Ryo Watanabe, Choji Fukuhara
    • Organizer
      7th Tokyo Conference on Advanced Catalytic Science and Technology
    • Place of Presentation
      Kyoto Tersa (Kyoto, Japan)
    • Year and Date
      2014-06-01 – 2014-06-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Directly methane decomposition over Ni-based structured catalyst and effecto of silica-coating2014

    • Author(s)
      Hidenori Kato, Ryo Watanabe, Choji Fukuhara
    • Organizer
      7th Tokyo Conference on Advanced Catalytic Science and Technology
    • Place of Presentation
      Kyoto Tersa (Kyoto, Japan)
    • Year and Date
      2014-06-01 – 2014-06-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] A Metal-Honeycomb-Structured Catalyst for Methane Dry Reforming2014

    • Author(s)
      Choji Fukuhara
    • Organizer
      International Conference on Hydrogen Production ICH2P-2014
    • Place of Presentation
      Kyushu University (Fukuoka, Japan)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Preparation and performance of novel Ni/YSZ catalyst for SOFC anode with internal methane reforming2014

    • Author(s)
      Wataru Kawasaki,Xiaojun Ma,Ryo Watanabe, Choji Fukuhara
    • Organizer
      International Conference on Hydrogen Production ICH2P-2014
    • Place of Presentation
      Kyushu University (Fukuoka, Japan)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Methane Reforming over Ni/Al2O3 Structured Catalyst: Effect of Nickel Deposition Condition on Performance2014

    • Author(s)
      Kazumasa Yamamoto,Yudai Makiyama,Ryo Watanabe, Choji Fukuhara
    • Organizer
      International Conference on Hydrogen Production ICH2P-2014
    • Place of Presentation
      Kyushu University (Fukuoka, Japan)
    • Related Report
      2013 Annual Research Report
  • [Presentation] High performance of Fe-substituted BaZrO3 catalyst for dehydrogenation of ethylbenzene with steam2013

    • Author(s)
      Ryo Watanabe, Yoshinori Saito, Choji Fukuhara
    • Organizer
      11th European Congress on Catalysis
    • Place of Presentation
      Lyon Convention Center (Lyon, France)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Pd-supported LaCoO3 catalyst with configuration for water-gas shift reaction2013

    • Author(s)
      Ryo Watanabe, Yusuke Fujita, Tomohiro Tagawa, Choji Fukuhara
    • Organizer
      11th European Congress on Catalysis
    • Place of Presentation
      Lyon Convention Center (Lyon, France)
    • Related Report
      2013 Annual Research Report
  • [Presentation] A novel catalyst for CH4 dry reforming : a Ni-based honeycomb catalyst prepared by a combination technique of electroless plating and sol-gel methods2013

    • Author(s)
      Choji Fukuhara, Keigo Masuda, Kazumasa Yamamoto, Yudai Makiyama, Ryo Watanabe
    • Organizer
      11th European Congress on Catalysis
    • Place of Presentation
      Lyon Convention Center (Lyon, France)
    • Related Report
      2013 Annual Research Report
  • [Patent(Industrial Property Rights)] 有機ハイドライド用脱水素触媒及びその製造方法2015

    • Inventor(s)
      福原長寿,渡部 綾
    • Industrial Property Rights Holder
      福原長寿,渡部 綾
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-042436
    • Filing Date
      2015-03-04
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 触媒構造体及びその製造方法,並びに水素発生装置2015

    • Inventor(s)
      福原長寿,渡部 綾
    • Industrial Property Rights Holder
      福原長寿,渡部 綾
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-042438
    • Filing Date
      2015-03-04
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 触媒体及びその製造方法,並びに水素発生装置2014

    • Inventor(s)
      福原長寿,渡部 綾
    • Industrial Property Rights Holder
      福原長寿,渡部 綾
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-183397
    • Filing Date
      2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] メチルシクロヘキサン用脱水素触媒及びその製造方法2014

    • Inventor(s)
      福原長寿,渡部 綾
    • Industrial Property Rights Holder
      福原長寿,渡部 綾
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-183398
    • Filing Date
      2014-09-09
    • Related Report
      2014 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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