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Fabrication of functional fiber using carbon nanotubes encapsulating ferromagnetic metal nanowires

Research Project

Project/Area Number 25390030
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nanomaterials engineering
Research InstitutionMie University

Principal Investigator

Sato Hideki  三重大学, 工学(系)研究科(研究院), 准教授 (40324545)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords強磁性金属内包カーボンナノチューブ / 鉄ナノワイヤ / カーボンナノチューブ繊維 / 化学気相成長法 / 鉄内包カーボンナノチューブシート / 鉄内包カーボンナノチューブ / フェロセン / ニッケロセン / 磁気特性 / 磁化方向制御
Outline of Final Research Achievements

Carbon nanotubes that encapsulate ferromagnetic iron nanowire (Fe@CNTs) exhibit remarkably high coercivity due to its high aspect ratio shape. Because of this characteristic, various applications of Fe@CNT have been expected. This study focused on the following two points that are required for the applications: (i) to find out growth conditions of Fe@CNTs that give further enhancement of those coercivity, (ii) to develop methods to fabricate sheets that comprise Fe@CNT fibers.
It was found that the coercivity of Fe@CNTs was enhanced to more than 2.0 kOe by using Ni film with oxidation treatment as a catalyst for the growth of Fe@CNTs. In addition, the free-standing Fe@CNT sheet, which was the Fe@CNT film that was not supported by the substrate, was successfully fabricated by embedding the Fe@CNT film on the substrate in resin and detaching the film from it. This Fe@CNT sheet exhibited the same magnetic property as that before the detaching.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (25 results)

All 2016 2015 2014 2013

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 3 results,  Open Access: 2 results) Presentation (19 results) (of which Int'l Joint Research: 7 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Catalyst film preparation for efficient growth of carbon nanotubes filled with iron nanowires2016

    • Author(s)
      Eisuke Tamaki, Hideki Sato, Nobuo Kubonaka, Yuji Fujiwara
    • Journal Title

      Journal of Vacuum Science & Technology A

      Volume: 34 Issue: 2

    • DOI

      10.1116/1.4938055

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Growth Characteristics of Graphene Film by Chemical Vapor Deposition Method Using Nozzle Gas Injection2015

    • Author(s)
      Yusuke Matsuura, Hideki Sato, Hideto Miyake, Kazumasa Hiramatsu
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 13 Issue: 0 Pages: 265-268

    • DOI

      10.1380/ejssnt.2015.265

    • NAID

      130005074894

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Influence of Underlayer on Growth of Carbon Nanotubes Filled with Iron Nanowires2015

    • Author(s)
      Nobuo Kubonaka, Hideki Sato, Yuji Fujiwara
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 13 Issue: 0 Pages: 295-300

    • DOI

      10.1380/ejssnt.2015.295

    • NAID

      130005076096

    • ISSN
      1348-0391
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Effect of hydrogen plasma irradiation of catalyst films on growth of carbon nanotubes filled with iron nanowires2014

    • Author(s)
      Hideki Sato, Nobuo Kubonaka, Atsushi Nagata and Yuji Fujiwara
    • Journal Title

      Journal of Vacuum Science & Technology A

      Volume: 32 Issue: 2

    • DOI

      10.1116/1.4827822

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Growth of FePt encapsulated carbon nanotubes by thermal chemical vapor deposition2014

    • Author(s)
      Yuji Fujiwara, Tetsuya Kaneko, Kenta Hori, Sho Takase, Hideki Sato, Kohji Maeda, Tadashi Kobayashi, Takeshi Kato, Satoshi Iwata and Mutsuko Jimbo
    • Journal Title

      Journal of Vacuum Science & Technology A

      Volume: 32 Issue: 2

    • DOI

      10.1116/1.4862087

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Influence of catalyst preparation method on the magnetic characteristics of carbon nanotubes filled with iron nanowires2016

    • Author(s)
      Eisuke Tamaki, Hideki Sato and Yuji Fujiwara
    • Organizer
      8th International Symposium in Advanced Plasma Science and its Applications for Nitrides and Nanomaterials / 9th International Conference on Plasma-Nano Technology & Science
    • Place of Presentation
      名古屋大学(愛知県・名古屋市)
    • Year and Date
      2016-03-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Magnetic properties of few-layer graphene oxide sheets reduced in hydrogen atmosphere2016

    • Author(s)
      Yuji Fujiwara, Taichi Inamori, Takahiro Tanaka, Ryumaru Mori, Kohji Maeda, Mutsuko Jimbo and Tadashi Kobayashi
    • Organizer
      8th International Symposium in Advanced Plasma Science and its Applications for Nitrides and Nanomaterials / 9th International Conference on Plasma-Nano Technology & Science
    • Place of Presentation
      名古屋大学(愛知県・名古屋市)
    • Year and Date
      2016-03-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Reduction of breakdown voltage by using carbon nanotube film electrode2015

    • Author(s)
      Yusuke Komatsu, Hideki Sato
    • Organizer
      10th International Symposium on Atomic Level Characterizations for New Materials and Devices ’15 (ALC'15)
    • Place of Presentation
      くにびきメッセ(島根県・松江市)
    • Year and Date
      2015-10-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Control of Crystal Structures of Ferromagnetic Metal Nanowires Encapsulated in Carbon Nanotubes for Tuning of Their Magnetic Properties2015

    • Author(s)
      Eisuke Tamaki, Hideki Sato and Yuji Fujiwara
    • Organizer
      10th International Symposium on Atomic Level Characterizations for New Materials and Devices ’15 (ALC'15)
    • Place of Presentation
      くにびきメッセ(島根県・松江市)
    • Year and Date
      2015-10-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ニッケロセンを用いた強磁性金属内包カーボンナノチューブ成長2015

    • Author(s)
      瑞樹 永祐,佐藤 英樹,笠原 一希,藤原 裕司
    • Organizer
      2015年 第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県・名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] カーボンナノチューブ薄膜電極の絶縁破壊特性2015

    • Author(s)
      古松 佑介,水嶌 悠貴,佐藤 英樹
    • Organizer
      2015年 第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県・名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Preparation of catalyst film for efficient growth of carbon nanotubes filled with ferromagnetic metal2015

    • Author(s)
      E. Tamaki, H. Sato, N. Kubonaka, Y. Fujiwara
    • Organizer
      The 13th International Symposium on Sputtering & Plasma Processes
    • Place of Presentation
      京都リサーチパーク(京都府・京都市)
    • Year and Date
      2015-07-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Discharge breakdown characteristics of carbon nanotube thin film electrode2015

    • Author(s)
      Y. Komatsu, H. Sato
    • Organizer
      The 13th International Symposium on Sputtering & Plasma Processes
    • Place of Presentation
      京都リサーチパーク(京都府・京都市)
    • Year and Date
      2015-07-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Composition control of FePt nanoparticles in carbon nanotubes2015

    • Author(s)
      Y. Fujiwara, R. Muta, T. Maeda, H. Sato, K. Maeda, M. Jimbo, T. Kobayashi
    • Organizer
      The 13th International Symposium on Sputtering & Plasma Processes
    • Place of Presentation
      京都リサーチパーク(京都府・京都市)
    • Year and Date
      2015-07-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Growth characteristics of graphene film by chemical vapor deposition method using nozzle gas injection2014

    • Author(s)
      Y. Matsuura, H. Sato, H. Miyake and K. Hiramatsu
    • Organizer
      The 7th International Symposium on Surface Science (ISSS-7)
    • Place of Presentation
      Kunibiki Messe, Matsue, Japan
    • Year and Date
      2014-11-06
    • Related Report
      2014 Research-status Report
  • [Presentation] Application of vertically aligned carbon nanotube films for thermal interface materials2014

    • Author(s)
      K. Maeda, E. Tamaki and H. Sato
    • Organizer
      The 7th International Symposium on Surface Science (ISSS-7)
    • Place of Presentation
      Kunibiki Messe, Matsue, Japan
    • Year and Date
      2014-11-06
    • Related Report
      2014 Research-status Report
  • [Presentation] Effect of Underlayer on Growth of Carbon Nanotubes Filled with Iron Nanowires2014

    • Author(s)
      N. Kubonaka, H. Sato and Y. Fujiwara
    • Organizer
      The 7th International Symposium on Surface Science (ISSS-7)
    • Place of Presentation
      Kunibiki Messe, Matsue, Japan
    • Year and Date
      2014-11-04
    • Related Report
      2014 Research-status Report
  • [Presentation] 内包カーボンナノチューブシートの作製と磁気特性評価2014

    • Author(s)
      久保中 伸雄, 佐藤 貴之, 佐藤 英樹, 藤原 裕司
    • Organizer
      第47回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      名古屋大学・名古屋市
    • Year and Date
      2014-09-02
    • Related Report
      2014 Research-status Report
  • [Presentation] 熱伝導体応用のための垂直配向カーボンナノチューブ薄膜の熱伝導特性の評価2014

    • Author(s)
      前田 健太, 瑞樹 永祐, 佐藤 英樹
    • Organizer
      第47回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      名古屋大学・名古屋市
    • Year and Date
      2014-09-02
    • Related Report
      2014 Research-status Report
  • [Presentation] ノズル照射型 CVD 法を用いたグラフェン成長における基板温度依存性2014

    • Author(s)
      松浦 佑介, 佐藤 英樹, 三宅 秀人, 平松 和政
    • Organizer
      第47回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      名古屋大学・名古屋市
    • Year and Date
      2014-09-02
    • Related Report
      2014 Research-status Report
  • [Presentation] 鉄内包カーボンナノチューブ成長における下地層の影響2014

    • Author(s)
      久保中伸雄,佐藤英樹,濱口真,藤原裕司
    • Organizer
      2014年 第61回応用物理学会春季学術講演会
    • Place of Presentation
      相模原市
    • Related Report
      2013 Research-status Report
  • [Presentation] Synthesis of carbon nanotubes filled with iron nanowires and tuning of those magnetic property2013

    • Author(s)
      H. Sato, N. Kubonaka, A. Nagata, Y. Fujiwara
    • Organizer
      The 12th International Symposium on Sputtering & Plasma Processes
    • Place of Presentation
      Kyoto
    • Related Report
      2013 Research-status Report
  • [Presentation] Growth of FePt encapsulated carbon nanotubes by thermal chemical vapor deposition2013

    • Author(s)
      Y. Fujiwara, T. Kaneko, K. Hori, S. Takase, H. Sato, K. Maeda, T. Kato, T. Kobayashi, M. Jimbo, S. Iwata
    • Organizer
      The 12th International Symposium on Sputtering & Plasma Processes
    • Place of Presentation
      Kyoto
    • Related Report
      2013 Research-status Report
  • [Presentation] 鉄内包カーボンナノチューブ成長における基板への水素プラズマ照射の影響2013

    • Author(s)
      久保中伸雄,佐藤英樹,濵口真,藤原裕司
    • Organizer
      2013年 第74回応用物理学会秋季学術講演会
    • Place of Presentation
      京田辺市
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 直列に配向させた繊維状カーボンナノチューブ製造方法2016

    • Inventor(s)
      佐藤 英樹,古松 佑介,水嶌 悠貴
    • Industrial Property Rights Holder
      佐藤 英樹,古松 佑介,水嶌 悠貴
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-043335
    • Filing Date
      2016-03-07
    • Related Report
      2015 Annual Research Report

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Published: 2014-07-25   Modified: 2019-07-29  

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