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Theoretical study of metallization and superconductivity of hydrides

Research Project

Project/Area Number 25400353
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics II
Research InstitutionTohoku University

Principal Investigator

Abe Kazutaka  東北大学, 電気通信研究所, 助教 (00361197)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords金属水素化合物 / 第一原理計算 / 超伝導 / 水素化合物 / 圧力誘起金属化 / 高温超伝導
Outline of Final Research Achievements

Although the typical hydride of Ge is GeH4 at ambient pressure, GeH3 has been predicted to be stabilized beyond 175 GPa. The proposed phases are metallic, and the superconducting transition temperatures are estimated to exceed about 100 K.
We have also found that hydrides of Sb and Bi are possible at high pressures while they are highly unstable under normal conditions. SbH2, SbH3, BiH2, and BiH3 have been shown to be stabilized beyond 150, 150, 100, and 250 GPa, respectively. The phases are metallic with quite dispersive electronic structures, and the superconducting transition temperatures lie in the range from 40 to 70 K.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (5 results)

All 2016 2015 2013

All Journal Article (2 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results) Presentation (3 results)

  • [Journal Article] Stabilization and highly metallic properties of heavy group-V hydrides at high pressures2015

    • Author(s)
      Kazutaka Abe and N. W. Ashcroft
    • Journal Title

      Physical Review B

      Volume: 92 Issue: 22

    • DOI

      10.1103/physrevb.92.224109

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Quantum disproportionation: The high hydrides at elevated pressures2013

    • Author(s)
      Kazutaka Abe and N. W. Ashcroft
    • Journal Title

      Physical Review B

      Volume: 88 Issue: 17

    • DOI

      10.1103/physrevb.88.174110

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Bi及びSb水素化合物の高圧金属相2016

    • Author(s)
      阿部和多加、N. W. Ashcroft
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      東北学院大学(宮城県仙台市)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 高密度水素の分子解離圧に対する非調和零点エネルギーの効果2015

    • Author(s)
      阿部和多加, N. W. Ashcroft
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2015-03-22
    • Related Report
      2014 Research-status Report
  • [Presentation] 高圧におけるGeH3の安定性と超伝導2013

    • Author(s)
      阿部和多加、N. W. Ashcroft
    • Organizer
      日本物理学会2013年秋季大会
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2020-05-15  

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