Synthesis and detailed characterization of novel metal-substituted tungstosulphates
| Project/Area Number |
25410095
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Kochi University |
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Principal Investigator |
UEDA Tadaharu 高知大学, 教育研究部総合科学系複合領域科学部門, 准教授 (50294822)
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| Co-Investigator(Kenkyū-buntansha) |
KANENO Daisuke 高知大学, 教育研究部自然科学系理学部門, 准教授 (00361593)
ONDA Ayumu 高知大学, 教育研究部総合科学系複合領域科学部門, 講師 (80335918)
YONEMURA Toshiaki 高知大学, 教育研究部総合科学系複合領域科学部門, 教授 (90240382)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
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| Keywords | ポリオキソメタレート錯体 / 合成 / 構造 / 電気化学 / 単結晶X線構造解析 |
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| Outline of Final Research Achievements |
Novel sulfur-centered polyoxometalates, in which transition metal or rare-earth metal is incorporated in framework, were prepared and isolated as a tetra-butylammonium salt. X-ray analysis indicate they have Wells-Dawson type structure. In addition, they were characterized with IR, Raman and UV-Vis spectroscopy. Detailed voltammetric behavior of them was investigated in CH3CN
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Report
(4 results)
Research Products
(52 results)
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[Journal Article] Hydrolysis of green-tide forming Ulva spp. by microwave irradiation with polyoxometalate2014
Author(s)
Tsubaki, S., Oono K., Ueda, T., Onda, A., Yanagisawa, K., Azuma, J.
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Journal Title
Green Chem.
Volume: 16
Issue: 4
Pages: 2227-2233
DOI
Related Report
Peer Reviewed
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[Presentation] Development of New Electrochemical Evaluation Method for Antioxidant Capacity with Polyoxometalates as Potential Probes2015
Author(s)
Ueda, T., Okumura, T., Tanaka, Y., Akase, S., Taniguchi, M., Shimamura, T., Ukeda, H.
Organizer
The 66th Annual Meeting of the International Society of Electrochemistry
Place of Presentation
台北
Year and Date
2015-10-04
Related Report
Int'l Joint Research
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[Presentation] Synthesis and Characterization of transition metal-substituted Wells-Dawson type tungstosulphates, [S2XW17O61]n- (X=FeIII, CuII, MnII, NiII, ZnII)2015
Author(s)
Hirabaru, H., Ota, H., Kawamoto, D., Ohnishi, M., Yanagisawa, K., Ueda, T.
Organizer
5th Asian Conference on Coordination Chemistry
Place of Presentation
香港
Year and Date
2015-07-12
Related Report
Int'l Joint Research
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[Presentation] Keggin-type Polyoxometalates, α- and β-[PW12O40]3-: Structure and Electrochemistry2015
Author(s)
Ueda, T., Kodani, K., Ota, H., Shiro, M., Guo, S-X., Boas, J. F., Bond, A. M.
Organizer
5th Asian Conference on Coordination Chemistry
Place of Presentation
香港
Year and Date
2015-07-12
Related Report
Int'l Joint Research
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[Presentation] Synthesis, characterization and catalytic properties of new polyoxometalates2015
Author(s)
Ueda, T., Ohnishi, M., Yamashita, K., Kawamoto, D., Hirabaru, H., Shiro, M., Guo, S-X., Boas, J. F., Bond, A. M.
Organizer
7th Internation Conference on Green and Sustainable Chemistry/ 4th JACI/GSC Symposium
Place of Presentation
東京
Year and Date
2015-07-05
Related Report
Int'l Joint Research
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