| Project/Area Number |
25410095
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Kochi University |
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Principal Investigator |
UEDA Tadaharu 高知大学, 教育研究部総合科学系複合領域科学部門, 准教授 (50294822)
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| Co-Investigator(Kenkyū-buntansha) |
KANENO Daisuke 高知大学, 教育研究部自然科学系理学部門, 准教授 (00361593)
ONDA Ayumu 高知大学, 教育研究部総合科学系複合領域科学部門, 講師 (80335918)
YONEMURA Toshiaki 高知大学, 教育研究部総合科学系複合領域科学部門, 教授 (90240382)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
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| Keywords | ポリオキソメタレート錯体 / 合成 / 構造 / 電気化学 / 単結晶X線構造解析 |
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| Outline of Final Research Achievements |
Novel sulfur-centered polyoxometalates, in which transition metal or rare-earth metal is incorporated in framework, were prepared and isolated as a tetra-butylammonium salt. X-ray analysis indicate they have Wells-Dawson type structure. In addition, they were characterized with IR, Raman and UV-Vis spectroscopy. Detailed voltammetric behavior of them was investigated in CH3CN
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