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Bottom-up Formation of Nanoemulsions by Using Supercritical Water

Research Project

Project/Area Number 25410103
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional solid state chemistry
Research InstitutionJapan Agency for Marine-Earth Science and Technology

Principal Investigator

DEGUCHI Shigeru  国立研究開発法人海洋研究開発機構, 海洋生命理工学研究開発センター, 研究開発センター長 (40344296)

Co-Investigator(Kenkyū-buntansha) KINOSHITA Keigo  国立研究開発法人海洋研究開発機構, 海洋生命理工学研究開発センター, ポストドクトラル研究員 (20710073)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsナノエマルション / ボトムアップ / 自己組織化 / 超臨界水 / 熱水噴出孔 / コロイド・量子ドット / エマルション
Outline of Final Research Achievements

1) Nanoemulsions containing ultra-fine droplets of 1-10 vol% dodecane were successfully obtained by inducing phase separation of homogeneous solutions of dodecane in supercritical water. 2) Unlike conventional top-down emulsification processes, the size of oil droplets that were generated by MAGIQ depended very much on the type of emulsifiers used. Moreover, smaller droplets were obtained when hydrophobic emulsifiers were used. 3) Anisotropic growth of hexadecane droplets to rod- or disc-shaped particles were found when its nanoemulsions were stored at temperatures below its freezing point. 4)A commercial instrument for manufacturing nanoemulsions by MAGIQ has been developed with AKICO Corporation.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (46 results)

All 2016 2015 2014 2013 Other

All Journal Article (9 results) (of which Peer Reviewed: 1 results) Presentation (30 results) (of which Int'l Joint Research: 10 results,  Invited: 17 results) Book (3 results) Remarks (4 results)

  • [Journal Article] 深海熱水噴出孔にヒントを得たボトムアップのナノ乳化プロセス2016

    • Author(s)
      木下圭剛、出口 茂
    • Journal Title

      ケミカルエンジニヤリング

      Volume: 61 Pages: 34-39

    • Related Report
      2015 Annual Research Report
  • [Journal Article] 超臨界水中でのコロイド科学2016

    • Author(s)
      出口 茂
    • Journal Title

      オレオサイエンス

      Volume: 16 Pages: 81-88

    • NAID

      130007585652

    • Related Report
      2015 Annual Research Report
  • [Journal Article] ナノエマルションの短時間での効率的作成手法の実際2015

    • Author(s)
      木下圭剛、出口 茂
    • Journal Title

      COSMETIC STAGE

      Volume: 9 Pages: 54-58

    • Related Report
      2015 Annual Research Report
  • [Journal Article] 超臨界水が示す特異な性質を利用した“魔法”のナノ乳化技術2015

    • Author(s)
      木下圭剛、出口 茂
    • Journal Title

      色材協会誌

      Volume: 88 Pages: 21-24

    • NAID

      130005104047

    • Related Report
      2015 Annual Research Report
  • [Journal Article] 海洋・深海生命圏での生存戦略に着目した機能性材料の開発2015

    • Author(s)
      出口 茂、椿 玲未、木下圭剛
    • Journal Title

      工業材料

      Volume: 63 Pages: 60-63

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Bottom-up formation of dodecane-in-water nanoemulsions from hydrothermal homogeneous solutions2013

    • Author(s)
      Shigeru Deguchi、Nao Ifuku
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: 52 (25) Issue: 25 Pages: 6409-6412

    • DOI

      10.1002/anie.201301403

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 超臨界水を利用した魔法のナノ乳化プロセス2013

    • Author(s)
      出口 茂
    • Journal Title

      Cosme Tech Japan

      Volume: 3 Pages: 26-31

    • Related Report
      2013 Research-status Report
  • [Journal Article] フランクザッパはコロイド・界面化学の夢をみるか?2013

    • Author(s)
      出口 茂
    • Journal Title

      Colloid and Interface Communication

      Volume: 38 Pages: 47-48

    • Related Report
      2013 Research-status Report
  • [Journal Article] 極限環境にインスピレーションを得たナノ乳化プロセス2013

    • Author(s)
      出口 茂
    • Journal Title

      月間ファインケミカル

      Volume: 42 Pages: 10-16

    • Related Report
      2013 Research-status Report
  • [Presentation] Deep-Sea Inspired Process for Bottom-up Production of Nanoemulsions2016

    • Author(s)
      Keigo Kinoshita, Shigeru Deguchi
    • Organizer
      Formula VIII
    • Place of Presentation
      Barcelona, Spain
    • Year and Date
      2016-07-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Bottom-up Formation of Nanoemulsions under Conditions Mimicking Deep-Sea Hydrothermal Vents2016

    • Author(s)
      Keigo Kinoshita, Shigeru Deguchi
    • Organizer
      21st International Symposium on Surfactants in Solution
    • Place of Presentation
      Shandong University, China
    • Year and Date
      2016-06-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Bottom-Up Formation of Nanoemulsions from Hydrothermal Homogeneous Solutions of Oil in Water2016

    • Author(s)
      Keigo Kinoshita, Shigeru Deguchi
    • Organizer
      EMN Meeting on Droplets 2016
    • Place of Presentation
      San Sebastian, Spain
    • Year and Date
      2016-05-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Pressure-Dependent Structural Change of 2D Colloidal Array in Supercritical Ethanol2016

    • Author(s)
      Shigeru Deguchi
    • Organizer
      3rd International Mini-Symposium on Surface Forces
    • Place of Presentation
      東北大学(宮城県仙台市)
    • Year and Date
      2016-01-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Anisotropic Growth of Hexadecane Nanodroplets to Crystalline Rod-shape Particles2015

    • Author(s)
      Keigo Kinoshita, Youhei Kawabata, Daiki Ishiwata, Atsuki Kajimura, Yukishige Kondo, Tadashi Kato, Shigeru Deguchi
    • Organizer
      第25回日本MRS年次大会
    • Place of Presentation
      横浜市開港記念会館(神奈川県横浜市)
    • Year and Date
      2015-12-08
    • Related Report
      2015 Annual Research Report
  • [Presentation] MAGIQ: Novel Bottom-up Process for Making Nanoemulsions2015

    • Author(s)
      Keigo Kinoshita, Shigeru Deguchi
    • Organizer
      6th Asian Conference on Colloid and Interface Science
    • Place of Presentation
      アルカス佐世保(長崎県佐世保市)
    • Year and Date
      2015-11-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Bottom-up Emulsification under Conditions Mimicking Deep-Sea Hydrothermal Vents2015

    • Author(s)
      Keigo Kinoshita, Shigeru Deguchi
    • Organizer
      Western Pacific Colloids Meeting 2015
    • Place of Presentation
      Siem Reap, Cambodia
    • Year and Date
      2015-11-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Anisotropic Growth of Nano-Sized Hexadecane Crystals in Water2015

    • Author(s)
      Keigo Kinoshita, Youhei Kawabata, Daiki Ishiwata, Atsuki Kajimura, Yukishige Kondo, Tadashi Kato, Shigeru Deguchi
    • Organizer
      Western Pacific Colloids Meeting 2015
    • Place of Presentation
      Siem Reap, Cambodia
    • Year and Date
      2015-11-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Soft Materials under Extreme Conditions Mimicking Deep-Sea Hydrothermal Vents2015

    • Author(s)
      Shigeru Deguchi
    • Organizer
      4th Nagoya Biomimetics International Symposium
    • Place of Presentation
      WINC Aichi(愛知県名古屋市)
    • Year and Date
      2015-10-30
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 熱水噴出孔環境を模擬した化学反応場でのソフトマテリアルの生成2015

    • Author(s)
      出口 茂
    • Organizer
      第56回海中海底工学フォーラム
    • Place of Presentation
      東京大学柏キャンパス大気海洋研究所大講堂(千葉県柏市)
    • Year and Date
      2015-10-16
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] ナノエマルション中のヘキサデカンが示す異方性結晶成長2015

    • Author(s)
      梶村淳紀、木下圭剛、川端庸平、石渡大貴、近藤行成、加藤 直、出口 茂
    • Organizer
      第5回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2015-10-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] Self-Assembly in the Extreme Environments Deep below the Waves2015

    • Author(s)
      Shigeru Deguchi
    • Organizer
      iCeMS International Symposium: Hierarchical Dynamics in Soft Materials and Biological Matter
    • Place of Presentation
      京都大学(京都府京都市)
    • Year and Date
      2015-09-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] MAGIQを利用した流通型ナノ乳化装置の開発2015

    • Author(s)
      木下圭剛、本郷一秋、小林隆三、出口 茂
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学(鹿児島県鹿児島市)
    • Year and Date
      2015-09-12
    • Related Report
      2015 Annual Research Report
  • [Presentation] ナノ空間に閉じ込めたヘキサデカンが示す異方性結晶成長2015

    • Author(s)
      木下圭剛、石渡大貴、梶村淳紀、川端庸平、加藤 直、近藤行成、出口 茂
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学(鹿児島県鹿児島市)
    • Year and Date
      2015-09-12
    • Related Report
      2015 Annual Research Report
  • [Presentation] Bottom-up Process for Making Nanoemulsions by Using Supercritical Water2015

    • Author(s)
      Keigo Kinoshita, Shigeru Deguchi
    • Organizer
      International Conference of Colloids and Interface Science
    • Place of Presentation
      National Taiwan University of Science and Technology(Taipei, Taiwan)
    • Year and Date
      2015-07-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] MAGIQ乳化:油/超臨界水均一溶液の相分離を利用したボトムアップのナノ乳化2014

    • Author(s)
      出口 茂
    • Organizer
      第61回日本油化学会界面科学部会秋季セミナー
    • Place of Presentation
      花王株式会社品川研修所、東京都港区
    • Year and Date
      2014-11-04
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 超臨界水を用いたボトムアップ型のナノ乳化技術とトップダウン法との比較2014

    • Author(s)
      木下圭剛、石渡大貴、伊福菜穂、近藤行成、出口 茂
    • Organizer
      2014年色材研究発表会
    • Place of Presentation
      名古屋市工業研究所、愛知県名古屋市
    • Year and Date
      2014-10-23 – 2014-10-24
    • Related Report
      2014 Research-status Report
  • [Presentation] MAGIQ乳化:超臨界水を用いたボトムアップのナノ乳化とトップダウン法との比較2014

    • Author(s)
      石渡大貴、木下圭剛、伊福菜穂、近藤行成、出口 茂
    • Organizer
      第4回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀、東京都江戸川区
    • Year and Date
      2014-10-14 – 2014-10-16
    • Related Report
      2014 Research-status Report
  • [Presentation] オカッパリで挑む深海研究 ~極限環境生物圏にインスパイヤードされたソフトマテリアルの創成~2014

    • Author(s)
      出口 茂
    • Organizer
      関西大学先端科学技術推進機構講演会
    • Place of Presentation
      関西大学、大阪府吹田市
    • Year and Date
      2014-10-03
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] MAGIQ乳化と高圧乳化:ナノ乳化におけるボトムアップ手法とトップダウン手法の比較2014

    • Author(s)
      木下圭剛、石渡大貴、伊福菜穂、近藤行成、出口 茂
    • Organizer
      第65回コロイド及び界面化学討論会
    • Place of Presentation
      東京理科大学、東京都新宿区
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 深海の極限環境にヒントを得たボトムアップのナノ乳化手法2014

    • Author(s)
      出口 茂
    • Organizer
      2014年油化学若手の会サマースクール
    • Place of Presentation
      あいち健康プラザ、愛知県知多郡
    • Year and Date
      2014-07-29 – 2014-07-31
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Nanoemulsion Formation via Bottom-up Approach Using Supercritical Water2014

    • Author(s)
      Keigo Kinoshita, Daiki Ishiwata, Nao Ifuku, Shigeru Deguchi
    • Organizer
      NIMS Conference 2014
    • Place of Presentation
      Epochal Tsukuba、茨城県つくば市
    • Year and Date
      2014-07-01 – 2014-07-03
    • Related Report
      2014 Research-status Report
  • [Presentation] MAGIQ Process: Bottom-up Formation of Nano-Sized Oil Droplets in Water2014

    • Author(s)
      Shigeru Deguchi, Nao Ifuku, and Keigo Kinoshita
    • Organizer
      20th International Symposium on Surfactants in Solution
    • Place of Presentation
      University of Coimbra、ポルトガル
    • Year and Date
      2014-06-22 – 2014-06-27
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Bottom-Up Nanoemulsification of Hydrocarbons in Water from Hydrothermal Homogeneous Solutions2013

    • Author(s)
      Shigeru Deguchi
    • Organizer
      87th ACS 2013 Colloid & Surface Science Symposium
    • Place of Presentation
      University of California Riverside、アメリカ合衆国
    • Related Report
      2013 Research-status Report
  • [Presentation] Bottom-up process for making nanoemulsions inspired by extreme environments in the deep sea2013

    • Author(s)
      Shigeru Deguchi
    • Organizer
      International Conference on "Aqua Incognita - The Florentine Debates"
    • Place of Presentation
      Convitto della Calza、イタリア
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 超臨界水の特性を利用したボトムアップのナノ乳化プロセス2013

    • Author(s)
      出口 茂
    • Organizer
      第64回コロイド及び界面化学討論会
    • Place of Presentation
      名古屋工業大学、愛知県
    • Related Report
      2013 Research-status Report
  • [Presentation] 熱水噴出孔の物理化学

    • Author(s)
      出口 茂
    • Organizer
      首都大・第226回化学コロキウム
    • Place of Presentation
      首都大学東京、東京都
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 陸っぱり深海研究

    • Author(s)
      出口 茂
    • Organizer
      第6回豊田理研談話会
    • Place of Presentation
      豊田理化学研究所、愛知県
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 高温・高圧環境下の水の特性を利用したボトムアップのナノ乳化手法

    • Author(s)
      出口 茂
    • Organizer
      第14回コスメティックサイエンスシンポジウム
    • Place of Presentation
      太陽化学本社、東京都
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 深海の極限環境に着想を得たボトムアップのナノ乳化技術

    • Author(s)
      出口 茂
    • Organizer
      日本化粧品技術者会第265回学術講演会
    • Place of Presentation
      学士会館、東京都
    • Related Report
      2013 Research-status Report
    • Invited
  • [Book] Aqua incognita: Why ice floats on water and Galileo 400 years on2014

    • Author(s)
      Shigeru Deguchi, Keigo Kinoshita, Takaaki Kubota
    • Total Pages
      497
    • Publisher
      Connor Court
    • Related Report
      2014 Research-status Report
  • [Book] Near-critical and supercritical water and their applications for biorefineries2014

    • Author(s)
      Shigeru Deguchi, Sada-atsu Mukai
    • Total Pages
      474
    • Publisher
      Springer Science+Business Media
    • Related Report
      2014 Research-status Report
  • [Book] 光散乱法の基礎と応用2014

    • Author(s)
      出口 茂
    • Total Pages
      336
    • Publisher
      講談社
    • Related Report
      2014 Research-status Report
  • [Remarks] 深海の極限環境にヒントを得たナノ乳化装置の販売を開始

    • URL

      http://www.jamstec.go.jp/j/about/press_release/20160119/

    • Related Report
      2015 Annual Research Report
  • [Remarks] 深海の極限環境にヒントを得た乳化装置の共同開発に着手 ~ MAGIQ技術の普及に期待 ~

    • URL

      http://www.jamstec.go.jp/j/about/press_release/20150603/

    • Related Report
      2015 Annual Research Report
  • [Remarks] MAGIQ乳化:ボトムアップのナノ乳化プロセス

    • URL

      http://www.xbr.jp/yokohama-cu/deguchi/research/scw/magiq/index_j.html

    • Related Report
      2013 Research-status Report
  • [Remarks] 深海底から噴き出す熱水にヒントを得てナノテクノロジーを開発

    • URL

      http://www.jamstec.go.jp/j/about/press_release/20130514_2/

    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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