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Development of Organic Active Materials for Redox-Flow Batteries

Research Project

Project/Area Number 25410200
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Energy-related chemistry
Research InstitutionKyoto University

Principal Investigator

SHIMIZU AKIHIRO  京都大学, 工学(系)研究科(研究院), 助教 (30584263)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywordsレドックス・フロー電池 / 二次電池 / 再生可能エネルギー / 酸化還元 / 有機活物質 / 電解酸化
Outline of Final Research Achievements

To develop organic redox-flow batteries with high energy density, we designed and synthesized quinone materials with high solubility toward organic solvents. The nonaqueous redox-flow batteries using the materials showed higher energy densities than conventional aqueous redox-flow batteries.
We have also developed new electrochemical methods for alkene difunctionalization using halogen cations and for C-H amination of aromatic compounds via radical cations.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (30 results)

All 2016 2015 2014 2013 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results,  Acknowledgement Compliant: 5 results,  Open Access: 1 results) Presentation (18 results) (of which Int'l Joint Research: 3 results,  Invited: 3 results) Remarks (2 results)

  • [Journal Article] Generation, Characterization, and Reactions of Thionium Ions Based on the Indirect Cation Pool Method2016

    • Author(s)
      Akihiro Shimizu, Keiji Takeda, Shota Mishima, Kodai Saito, Songhee Kim, Toshiki Nokami, Jun-ichi Yoshida*
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 89 Issue: 1 Pages: 61-66

    • DOI

      10.1246/bcsj.20150323

    • NAID

      130005119459

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Heterocyclization Approach for Electrooxidative Coupling of Functional Primary Alkylamines with Aromatics2015

    • Author(s)
      Tatsuya Morofuji, Akihiro Shimizu, Jun-ichi Yoshida
    • Journal Title

      Journal of American Chemical Society

      Volume: 137 Issue: 31 Pages: 9816-9819

    • DOI

      10.1021/jacs.5b06526

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Reaction Integration Using Electrogenerated Cationic Intermediates2015

    • Author(s)
      J. Yoshida, A. Shimizu, Y. Ashikari, T. Morofuji, R. Hayashi, T. Nokami, A. Nagaki
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 88 Issue: 6 Pages: 763-775

    • DOI

      10.1246/bcsj.20150100

    • NAID

      130005075675

    • ISSN
      0009-2673, 1348-0634
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochemical Intramolecular C-H Amination: Synthesis of Benzoxazoles and Benzothiazoles2015

    • Author(s)
      諸藤達也、清水章弘、吉田潤一
    • Journal Title

      Chemistry European Journal

      Volume: 21 Issue: 8 Pages: 3211-3214

    • DOI

      10.1002/chem.201406398

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Switching the Reaction Pathways of Electrochemically Generated β - Haloalkoxysulfonium Ions. Synthesis of Halohydrins and Epoxides2015

    • Author(s)
      Akihiro Shimizu , Ryutaro Hayashi, Yosuke Ashikari, Toshiki Nokami, Jun - ichi Yoshida*
    • Journal Title

      Beilstein J. Org. Chem.

      Volume: 11 Pages: 242-248

    • DOI

      10.3762/bjoc.11.27

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Automated Electrochemical Assembly of the Protected Potential TMG-chitotriomycin Precursor Based on Rational Optimization of the Carbohydrate Building Block.2015

    • Author(s)
      Nokami, T.; Isoda, Y.; Sasaki, N.; Takaiso, A.; Hayase, S.; Itoh, T.; Hayashi, R.; Shimizu, A.; Yoshida, J.
    • Journal Title

      Organic Letters

      Volume: 17 Issue: 6 Pages: 1525-1528

    • DOI

      10.1021/acs.orglett.5b00406

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Redox Active Dendronized Polystyrenes Equipped with Peripheral Triarylamines2014

    • Author(s)
      野上敏材、武者直樹、諸藤達也、武田圭司、宅見正浩、清水章弘、吉田潤一
    • Journal Title

      Beilstein Journal of Organic Chemistry

      Volume: 10 Pages: 3079-3103

    • DOI

      10.3762/bjoc.10.326

    • NAID

      120005540401

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Direct C-N Coupling of Imidazoles with Aromatic and Benzylic Compounds via Electrooxidative C-H Functionalization2014

    • Author(s)
      諸藤達也・清水章弘・吉田潤一
    • Journal Title

      Journal of American Chemical Society

      Volume: 136 Issue: 12 Pages: 4496-4499

    • DOI

      10.1021/ja501093m

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Automated Solution-Phase Synthesis of Oligosaccharides via Iterative electrochemical Assembly of Thioglycosides2013

    • Author(s)
      Nokami, T.; Hayashi, R.; Saigusa, Y.; Shimizu, A.; Liu, C.-Y.; Mong, K.-K. T.; Yoshida, J.
    • Journal Title

      Org. Lett.

      Volume: 15 Issue: 17 Pages: 4520-4523

    • DOI

      10.1021/ol402034g

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Halogen and Chalcogen Cation Pools Stabilized by DMSO. Versatile Reagents for Alkene Difunctionalization2013

    • Author(s)
      Ashikari, Y.; Shimizu, A.; Nokami, T.; Yoshida, J.
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 135 Issue: 43 Pages: 16070-16073

    • DOI

      10.1021/ja4092648

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 活性種の電子状態の制御に基づく電子移動反応と有機電池材料の開発2016

    • Author(s)
      清水 章弘
    • Organizer
      第40回有機電子移動化学討論会
    • Place of Presentation
      新潟大学、新潟
    • Year and Date
      2016-06-23
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] キノンを基盤とする有機正極活物質の設計・合成と酸化還元特性2016

    • Author(s)
      清水章弘・谷澤秀弥・矢三勇介・稲富友・北條伸彦・鈴木拡哲・吉田潤一
    • Organizer
      第40回有機電子移動化学討論会
    • Place of Presentation
      新潟大学、新潟
    • Year and Date
      2016-06-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] 有機電気化学的手法による芳香族化合物と官能基を有する第一級アミンとの2016

    • Author(s)
      清水章弘,諸藤達也,吉田潤一
    • Organizer
      2016年 電気化学会第83回大会
    • Place of Presentation
      大阪大学、大阪
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] Direct Observation and Reactivity of Thionium Ions Generated by Using the Indirect Cation Pool Method2015

    • Author(s)
      Akihiro Shimizu, Keiji Takeda, Kodai Saito, Songhee Kim, Toshiki Nokami, Jun-ichi Yoshida
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Observation and Characterization of Electrochemically Generated Thionium Ions2015

    • Author(s)
      Akihiro Shimizu, Keiji Takeda, Shota Mishima, Kodai Saito, Songhee Kim, Toshiki, Nokami, Jun-ichi Yoshida*
    • Organizer
      IKCOC-13 (The 13th International Kyoto Conference on New Aspect of Organic Chemistry)
    • Place of Presentation
      リーガロイヤルホテル京都、京都
    • Year and Date
      2015-11-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 低温電解酸化による含硫黄反応中間体の発生・蓄積と求核剤との反応2015

    • Author(s)
      清水章弘・堀内俊・林竜太朗・武田圭史・三島翔太・齊藤巧泰・金松希・野上敏
    • Organizer
      第26回基礎有機化学討論会
    • Place of Presentation
      松山、愛媛
    • Year and Date
      2015-09-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 窒素原子を導入したキノン誘導体の電気化学特性2015

    • Author(s)
      清水章弘・矢三勇介・辻井豊・野上敏材・稲富友・北條伸彦・鈴木拡哲・吉田潤一
    • Organizer
      第39回有機電子移動化学討論会
    • Place of Presentation
      長崎大学、長崎
    • Year and Date
      2015-06-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] o- and p-Quinones Containing Nitrogen Atoms as Cathode Materials for Lithium Batteries2015

    • Author(s)
      Akihiro Shimizu, Yutaka Tsujii, Hiroki Kuramoto, Toshiki Nokami, Yuu Inatomi, Nobuhiko Hojo, and Jun-ichi Yoshida*
    • Organizer
      227th ECS Meeting
    • Place of Presentation
      Chicago, Illinois, USA
    • Year and Date
      2015-05-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 活性種の安定化に基づく有機電子移動化学2015

    • Author(s)
      清水章弘
    • Organizer
      文部科学省 私立大学戦略的研究基盤形成支援事業 太陽光促進のためのエネルギーベストミックス研究拠点 平成27年度 「第1回光エネルギーセミナー」
    • Place of Presentation
      近畿大学、大阪
    • Year and Date
      2015-05-09
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 電気化学的手法により発生させたチオニウムイオンのNMRによる観測と安定性の評価2015

    • Author(s)
      清水章弘、武田圭史、齊藤巧泰、金 松希、野上敏材、吉田潤一
    • Organizer
      日本化学会第95春季年会(2015)
    • Place of Presentation
      千葉県 日本大学
    • Year and Date
      2015-03-26
    • Related Report
      2014 Research-status Report
  • [Presentation] Generation, Observation, and Reactions of Thionium Ions by Indirect Cation Pool Method2014

    • Author(s)
      Akihiro Shimizu, Keiji Takeda, Kodai Saito, Songhee Kim, Toshiki Nokami, and Jun-ichi Yoshida
    • Organizer
      The Ninth International Symposium on Integrated Synthesis (ISIS-9)
    • Place of Presentation
      Awaji Yumebutai International Conference Center, Awaji Island
    • Year and Date
      2014-11-15
    • Related Report
      2014 Research-status Report
  • [Presentation] 量子化学計算を用いた二次電池有機正極材料の設計と開発2014

    • Author(s)
      清水章弘, 辻井 豊, 倉本拓樹, 野上敏材, 稲富 友, 北條伸彦, 鈴木拡哲, 吉田潤一
    • Organizer
      2014年電気化学秋季大会
    • Place of Presentation
      北海道大学高等教育推進機構
    • Year and Date
      2014-09-27
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Nitrogen-Containing Polycyclic Quinones as Cathode Materials for Lithium Batteries2014

    • Author(s)
      Akihiro Shimizu, Yutaka Tsujii, Hiroki Kuramoto, Toshiki Nokami, Yuu Inatomi, Nobuhiko Hojo, and Jun-ichi Yoshida
    • Organizer
      Electrochemistry 2014
    • Place of Presentation
      Johannes Gutenberg-Universität Mainz
    • Year and Date
      2014-09-22
    • Related Report
      2014 Research-status Report
  • [Presentation] キノンを正極材料に用いる有機電池のサイクル特性の向上と高電圧化2014

    • Author(s)
      清水章弘・倉本拓樹・辻井豊・矢三勇介・野上敏材・稲富友・北條伸彦・鈴木拡哲・吉田潤一
    • Organizer
      第38回有機電子移動化学討論会
    • Place of Presentation
      岐阜薬科大学
    • Year and Date
      2014-06-27
    • Related Report
      2014 Research-status Report
  • [Presentation] リチウムカルボキシ基を導入したキノン誘導体を正極活物質に用いた有機電池2014

    • Author(s)
      ○清水章弘・倉本拓樹・辻井 豊・野上敏材・稲富 友・北條伸彦・鈴木拡哲・吉田潤一
    • Organizer
      電気化学会第81回大会
    • Place of Presentation
      大阪
    • Related Report
      2013 Research-status Report
  • [Presentation] Design, Synthesis, and Electrochemical Properties of Cyclic 1,2-Diketones as Organic Cathode Materials for Lithium-ion Batteries2013

    • Author(s)
      ○Akihiro Shimizu, Toshiki Nokami, Takahiro Matsuo, Yuu Inatomi, Nobuhiko Hojo, Takafumi Tsukagoshi, Hiroshi Yoshizawa, Hiroki Kuramoto, and Jun-ichi Yoshida
    • Organizer
      The 223rd ECS Meeting
    • Place of Presentation
      トロント、カナダ
    • Related Report
      2013 Research-status Report
  • [Presentation] 1,2-ジケトンを基本構造とするリチウムイオン二次電池正極用有機レドックスポリマーの開発2013

    • Author(s)
      ○清水章弘・倉本拓樹・辻井 豊・野上敏材・吉田潤一
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      石川
    • Related Report
      2013 Research-status Report
  • [Presentation] Polymer-Bound Pyrene-4,5,9,10-tetraone as a Cathode Material for Lithium-Ion Batteries2013

    • Author(s)
      ○Akihiro Shimizu, Toshiki Nokami, Hiroki Kuramoto, Yutaka Tsujii, Jun-ichi Yoshida
    • Organizer
      ISOR-11, 2013 International Symposium on Organic Reaction
    • Place of Presentation
      台北、台湾
    • Related Report
      2013 Research-status Report
  • [Remarks] 京都大学大学院工学研究科 合成・生物化学専攻 吉田研究室

    • URL

      http://www.sbchem.kyoto-u.ac.jp/yoshida-lab/

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
  • [Remarks] 京都大学大学院工学研究科 合成・生物化学専攻 吉田研究室

    • URL

      http://www.sbchem.kyoto-u.ac.jp/yoshida-lab/

    • Related Report
      2013 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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