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Elucidation of electrode-reaction mechanism of manganese-based cathode materials for lithium-ion batteries

Research Project

Project/Area Number 25410256
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Device related chemistry
Research InstitutionNational Institute for Materials Science

Principal Investigator

Ozawa Kiyoshi  国立研究開発法人物質・材料研究機構, エネルギー・環境材料研究拠点, 主席研究員 (90343855)

Project Period (FY) 2013-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywordsリチウム二次電池 / クロム添加効果 / マンガンベース正極材 / 電極反応メカニズム
Outline of Final Research Achievements

We studied the electrode mechanism systems of Li2MnO3 and Ni- and Cr-doped Li2MnO3. In the latter half of the research, we also studied MoS2/C composite anode materials for lithium-ion battery system. It was found that the electrode characteristics of the materials significantly depend on the diffusion of Li ions in the cathode materials during charge-discharge cycling. The diffusion is related to the crystalline particle size and also types and amounts of transition metal ions to be added. For the study of MoS2/C composites, it was found that the electrode characteristics are improved by using graphene as carbon.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (19 results)

All 2017 2016 2015 2014 2013 Other

All Int'l Joint Research (1 results) Journal Article (17 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 17 results,  Open Access: 12 results,  Acknowledgement Compliant: 1 results) Presentation (1 results)

  • [Int'l Joint Research] University of Wollongong/University of Queensland(オーストラリア)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Comparison of reduction products from graphite oxide and graphene oxide for anode applications in lithium-ion batteries and sodium-ion batteries2017

    • Author(s)
      Yige Sun, Jie Tang, Kun Zhang, Jinshi Yuan, Jing Li, Da-Ming Zhu, Kiyoshi Ozawa and Lu-Chang Qin
    • Journal Title

      Nanoscale

      Volume: 9 Issue: 7 Pages: 2585-2595

    • DOI

      10.1039/c6nr07650e

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Nanoporous MoS2/C Composites for High Performance Lithium Ion Battery Anode Material2017

    • Author(s)
      Zengmei Wang, Gui Wei, Kiyoshi Ozawa, Yaling Cai, Zhenxiang Cheng
    • Journal Title

      Electrochimica Acta

      Volume: 239 Pages: 74-83

    • DOI

      10.1016/j.electacta.2017.04.033

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Understanding Performance Differences from Various Synthesis Methods: A Case Study of Spinel LiCr0.2Ni0.4Mn1.4O4 Cathode Material2016

    • Author(s)
      Mingzhe Chen, Zhe Hu, Zhenguo Wu, Weibo Hua, Kiyoshi Ozawa, Qinfen Gu, Yong-Mook Kang, Xiaodong Guo, Shu-Lei Chou, and Shi-Xue Dou
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 8 Issue: 39 Pages: 26051-26057

    • DOI

      10.1021/acsami.6b08327

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Ni-induced stepwise capacity increase in Ni-poor Li-rich cathode materials for high performance lithium ion batteries2015

    • Author(s)
      Delai Ye, Chenghua Sun, Yu Chen, Kiyoshi Ozawa, Denisa Hulicova-Jurcakova, Jin Zou, and Lianzhou Wang
    • Journal Title

      Nano Research

      Volume: 8 Issue: 3 Pages: 808-820

    • DOI

      10.1007/s12274-014-0563-3

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Structural variation of Li<sub>2</sub>MnO<sub>3</sub> during charge&ndash;discharge cycling2015

    • Author(s)
      Yasuhiro Nakao, Kiyoshi Ozawa, Yoshihiro Nemoto, Fumihiko Uesugi, Hiroki Fujii, and Takashi Mochiku
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 123 Issue: 1439 Pages: 589-594

    • DOI

      10.2109/jcersj2.123.589

    • NAID

      130005085543

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Understanding the Origin of Li2MnO3 Activation in Li-Rich Cathode Materials for Lithiu-Ion Batteries2015

    • Author(s)
      Delai Ye, Guang Zeng, Kazuhiro Nogita, Kiyoshi Ozawa, Marlies Hankel, Debra J. Searles, and Lianzhou Wang
    • Journal Title

      Advanced Functional Materials

      Volume: 25 Issue: 48 Pages: 7488-7496

    • DOI

      10.1002/adfm.201503276

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Interface Strain-Induced Multiferroicity of a SmFeO_3 Film2014

    • Author(s)
      Zhenxiang, Cheng, Fang Hong, Yuanxu Wang, Kiyoshi Ozawa, Hiroki Fujii, Hideo Kimura, Yi Du, Xiaolin Wang, and Shixue Dou
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 6 Issue: 10 Pages: 7356-7362

    • DOI

      10.1021/am500762c

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Tuning three-dimentional TiO2 nanotube electrode to achieve high utilization of Ti substrate for lithium storage2014

    • Author(s)
      Zhi-Jia Zhang, Qing-Yi Zeng, Shu-Lei Chou, Xin-Jun Li, Hui-Jun Li, Kiyoshi Ozawa, Hua-Kun Liu, Jia-Zhao Wang
    • Journal Title

      Electrochimica Acta

      Volume: 133 Pages: 570-577

    • DOI

      10.1016/j.electacta.2014.04.049

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Novel Germanium/Polypyrrole Composite for High Power Lithium-ion Batteries2014

    • Author(s)
      Xuanwen Gao, Wenbin Luo, Chao Zhong, David Wexler, Shue-Lei Chou, Hua-Kun Liu, Zhicong Shi, Guohua Chen, Kiyoshi Ozawa & Jia-Zhao Wang
    • Journal Title

      Scientific Reports

      Volume: 4 Issue: 1

    • DOI

      10.1038/srep06095

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Enkancing the High Rate Capability and Cycling Stability of LiMn2O4 by Coating of Solid-State Electrolyte LiNbO32014

    • Author(s)
      Zhi-Jia Zhang, Shu-Lei Chou, Qin-Fen Gu, Hua-Kun Liu, Hui-Jun Li, Kiyoshi Ozawa, and Jia-Zhao Wang
    • Journal Title

      ACS Applied Materials & Interface

      Volume: 6 Issue: 24 Pages: 22155-22165

    • DOI

      10.1021/am5056504

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Capacity-controllable Li-rich cathode materials for lithium-ion batteries2014

    • Author(s)
      Delai Ye, Kiyoshi Ozawa, Bei Wang, Denisa Hulicova-Jurcakova, Jin Zou, Chenghua Sun, Lianzhou Wang
    • Journal Title

      Nano Energy

      Volume: 6 Pages: 92-102

    • DOI

      10.1016/j.nanoen.2014.03.013

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] The effect of refinement of carbon-substituted MgB2 filling powder using various starting powders on the microstructure and critical current density of ex situ processed superconducting tapes2014

    • Author(s)
      H. Fujii, K. Ozawa, and H. Kitaguchi
    • Journal Title

      Superconducting Science and Technology

      Volume: 27 Issue: 3 Pages: 035002-035002

    • DOI

      10.1088/0953-2048/27/3/035002

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Band structure, magnetic, and transport properties of two dimentional compounds Sr_<2->xGd_xCoO_42013

    • Author(s)
      Q. W. Yao, X. L. Wang, H. Kimura, S. X. Dou, K. Konstantinov, Z. X. Cheng, F. Hong, H. Y. Zhao, H. Qiu, and K. Ozawa
    • Journal Title

      J. Appl. Phys.

      Volume: 113 Issue: 17

    • DOI

      10.1063/1.4799780

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electron diffraction and high-resolution electron microscopy studies on layered Li2-d(Mn1-xCox)1+dO32013

    • Author(s)
      Hiroki Fujii, Kiyoshi Ozawa, and Takashi Mochiku
    • Journal Title

      Journal of Solid State Chemistry

      Volume: 203 Pages: 345-352

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Polypyrrole-coated a-LiFeO2 nanocomposite with enhanced electrochemical properties for lithium-ion batteries2013

    • Author(s)
      Zhi-jia Zhang, Jia-Zhao Wang, Shu-Lei Chou, Hua-Kun Liu, Kiyoshi Ozawa, and Hui-jun Li
    • Journal Title

      Electrochimica Acta

      Volume: 108 Pages: 820-826

    • DOI

      10.1016/j.electacta.2013.06.130

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electrode Properties of Li2MnO3 (C2/m) for a Lithium-Battery Cathode in Several Charge-Discharge Potential Ranges2013

    • Author(s)
      Yasuhiro Nakao, Kiyoshi Ozawa, Hiroki Fujii, Takashi Mochiku, Hideo Iwai, Yoshinori Tsuchiya, and Naoki Igawa
    • Journal Title

      Trans. Mat. Res. Soc. Japan

      Volume: 38 Pages: 229-233

    • NAID

      130005004220

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Hollow Structured Li_3VO_4 Wrapped with Graphene Nanosheets in Situ Prepared by a One-Pot Template-Free Method as an Anode for Lithium-Ion Batteries2013

    • Author(s)
      Yi Shi, Jia-Zhao Wang, Shu-Lei Chou, David Wexler, Hui-Jun Li, Kiyoshi Ozawa, Hua-Kun Liu, and Yu-Ping Wu
    • Journal Title

      Nano Lett.

      Volume: 13 Issue: 10 Pages: 4715-4720

    • DOI

      10.1021/nl402237u

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Structural Variation of Li2MnO3 (C2/m) in Several Charge-Discharge Potential Ranges2014

    • Author(s)
      Kiyoshi Ozawa, Yasuhiro Nakao, Yoshihiro Nemoto, Hiroki Fijii, Takashi Mochiku, Yoshinori Tsuchiya, and Naoki Igawa
    • Organizer
      APEnergy 2014
    • Place of Presentation
      Brisbane Convention Centre (Brisbane, Australia)
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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