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Stabilization of oil-water interface by screening effect with counterion

Research Project

Project/Area Number 25420802
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionOkayama University

Principal Investigator

Oshitani Jun  岡山大学, 自然科学研究科, 准教授 (70314656)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
KeywordsScreening効果 / エマルション / 対イオン
Outline of Final Research Achievements

Stabilization of oil-water interface by screening effect with counterion was investigated in this study. The stabilization was evaluated using O/W emulsion by changing the surfactant concentration with addition of various salts. It was found that the stabilization is dependent on the kind of counterion; the hydration of the counterion relates to the stability. The stability of surfactant-free O/W emulsion was also evaluated based on the screening effect with proton by changing pH. Stable emulsion is formed at high pH without using the surfactant, but phase separation is remarkable at low pH. The low stability at low pH is caused by the fact that large amount of proton enhances the screening effect, which results in that the surface charge is reduced and electrostatic repulsion between the oil droplets is also reduced. The microscopic effect on the stability of emulsion was clarified by this research. These results will contribute to manufacturing of colloidal products.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (1 results)

All 2014

All Journal Article (1 results) (of which Peer Reviewed: 1 results)

  • [Journal Article] pH Effect on Properties of Surfactant-Free O/W Emulsion Prepared with Oleic Acid2014

    • Author(s)
      Yuta Akizuki, Mikio Yoshida, Naoyuki Ishida, Toshiyuki Oshiki, and Jun Oshitani
    • Journal Title

      Chemistry Letters

      Volume: 43 Pages: 605-607

    • Related Report
      2013 Research-status Report
    • Peer Reviewed

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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