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Production of ZnO using a mist of zinc acetate and negative oxygen ions

Research Project

Project/Area Number 25600125
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Plasma electronics
Research InstitutionKyoto Institute of Technology

Principal Investigator

Himura Haruhiko  京都工芸繊維大学, 電気電子工学系, 准教授 (30311632)

Co-Investigator(Kenkyū-buntansha) SANPEI AKIO  京都工芸繊維大学, 電気電子工学系, 講師 (90379066)
HASUIKE NORIYUKI  京都工芸繊維大学, 電気電子工学系, 助教 (40452370)
MASAMUNE SADAO  京都工芸繊維大学, 電気電子工学系, 教授 (00157182)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2013: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsプラズマプロセス / 酸化亜鉛薄膜 / 酢酸亜鉛 / ジエチル亜鉛 / 酸素負イオン / 酸素アニオンラジカル / プラズマエレクトロニクス / 酸化亜鉛 / 酸素ラジカル / RFプラズマ / 低温プロセス / ZnO / ZnO薄膜
Outline of Final Research Achievements

A feasibility of a zinc oxide (ZnO) plasma process at lower temperature using oxygen anion radical (O-) is studied experimentally. A pulsed 13.56 MHz inductively coupled plasma discharge have been applied to generate O-. The O- density measured by a probe-assisted laser photo-detachment method is about 1010 per cubic centimeters. To investigate the effect of O- on forming ZnO thin films, we have changed the bias voltage (Vb) of the substrate stage. However, resistivity seem to still depend on the process temperature, rather than Vb. These results may be attributed to the large amount of oxygen radical (O*). In fact, the density of O* can be estimated to be three orders of magnitude greater than the O- density. Another new experiment in which the effect of O* is completely eliminated is thus required.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (18 results)

All 2015 2014 2013 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 2 results) Presentation (13 results) Remarks (2 results)

  • [Journal Article] Development of prototype apparatus for creating ZnO at low temperature by DEZn and O- plasmas2015

    • Author(s)
      H. Himura, M. Yamamoto, N. Mizuike, A. Kiyohara
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 54 Issue: 1S Pages: 01AA05-01AA05

    • DOI

      10.7567/jjap.54.01aa05

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Feasibility of growth of ZnO cluster in penning trap2014

    • Author(s)
      H. Himura, A. Sanpei, Y. Nishioka, S. Masamune
    • Journal Title

      JPS Conf. Proc.

      Volume: 1 Pages: 015067-015067

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Feasibility of growth of ZnO cluster in penning trap2014

    • Author(s)
      H. Himura et al.
    • Journal Title

      JPS Conf. Proc.

      Volume: 1 Pages: 15067-15067

    • DOI

      10.7566/jpscp.1.015067

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 負イオンを用いた不純物を含まない小型室温プロセスへの挑戦2015

    • Author(s)
      比村 治彦・森本 貴大・堀田 啓介・南川 和生・平野 達弥・政宗 貞男・岡田 成文
    • Organizer
      プラズマ核融合学会
    • Place of Presentation
      名古屋大学 東山キャンパス 豊田講堂
    • Year and Date
      2015-11-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 低温かつ低不純物プロセス検証装置に取り付ける酸素負イオンビームおよびジエチル亜鉛噴射ノズル機構の設計・製作2015

    • Author(s)
      南川 和生・堀田 啓介・森本 貴大・平野 達弥・比村 治彦・政宗 貞男・岡田 成文
    • Organizer
      プラズマ核融合学会
    • Place of Presentation
      名古屋大学 東山キャンパス 豊田講堂
    • Year and Date
      2015-11-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 酸素負イオンプラズマとDEZnを用いたZnO薄膜生成実験II –プラズマパラメーター依存性-2014

    • Author(s)
      南川和生、山本昌良、堀田啓介、比村治彦、岡田成文、政宗貞男、三瓶明希夫
    • Organizer
      Plasma Conference 2014
    • Place of Presentation
      新潟市朱鷺メッセ
    • Year and Date
      2014-11-18 – 2014-11-21
    • Related Report
      2014 Research-status Report
  • [Presentation] 酸素負イオンプラズマとDEZnを用いたZnO薄膜生成実験III –基板温度依存性-2014

    • Author(s)
      堀田啓介、山本昌良、南川和生、比村治彦、岡田成文、政宗貞男、三瓶明希夫
    • Organizer
      Plasma Conference 2014
    • Place of Presentation
      新潟市朱鷺メッセ
    • Year and Date
      2014-11-18 – 2014-11-21
    • Related Report
      2014 Research-status Report
  • [Presentation] 酸素負イオンプラズマとDEZnを用いたZnO薄膜生成実験-低温プロセスに対する酸素負イオンの効果-2014

    • Author(s)
      山本昌良、堀田啓介、南川和生、比村治彦、岡田成文、政宗貞男、三瓶明希夫
    • Organizer
      Plasma Conference 2014
    • Place of Presentation
      新潟市朱鷺メッセ
    • Year and Date
      2014-11-18 – 2014-11-21
    • Related Report
      2014 Research-status Report
  • [Presentation] Development of new device for producing ZnO based on Coulomb recombination process2014

    • Author(s)
      M. Yamamoto, H. Himura et al.
    • Organizer
      8th International Conference on Reactive Plasmas/31st Symposium on Plasma Processing (ICRP-8/SPP-31)
    • Place of Presentation
      福岡、日本
    • Related Report
      2013 Research-status Report
  • [Presentation] Laser detachment measurement of negative oxygen ions produced in small discharge tube by 13.56 MHz RF switching method2013

    • Author(s)
      A. Kiyohara, H. Himura et al.
    • Organizer
      12th Asia Pacific Physics Conference (APPC12)
    • Place of Presentation
      千葉、日本
    • Related Report
      2013 Research-status Report
  • [Presentation] Feasibility of growth of ZnO cluster in penning trap2013

    • Author(s)
      H. Himura et al.
    • Organizer
      12th Asia Pacific Physics Conference (APPC12)
    • Place of Presentation
      千葉、日本
    • Related Report
      2013 Research-status Report
  • [Presentation] Development of negative oxygen plasma source applied to produce pure ZnO particles at room temperature2013

    • Author(s)
      M. Yamamoto, H. Himura et al.
    • Organizer
      12th International Symposium on Sputtering and Plasma Processes (ISSP2013)
    • Place of Presentation
      京都、日本
    • Related Report
      2013 Research-status Report
  • [Presentation] Translocation of zinc ion particles dissociated from zinc acetate mist for proposed new processing2013

    • Author(s)
      N. Mizuike, H. Himura et al.
    • Organizer
      12th International Symposium on Sputtering and Plasma Processes (ISSP2013)
    • Place of Presentation
      京都、日本
    • Related Report
      2013 Research-status Report
  • [Presentation] 室温下で高純度 ZnO 粒子生成に用いる酸素負イオン源の開発2013

    • Author(s)
      山本昌良、比村治彦 他
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      京都、日本
    • Related Report
      2013 Research-status Report
  • [Presentation] 小口径放電管内で13.56MHzRFスイッチングにより生成された酸素負イオンのレーザー光脱離法による計測2013

    • Author(s)
      清原彰、比村治彦 他
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      京都、日本
    • Related Report
      2013 Research-status Report
  • [Presentation] 気相中でZnO粒子を生成する新規プロセスに用いる亜鉛源の検討2013

    • Author(s)
      水池成弘、比村治彦 他
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      京都、日本
    • Related Report
      2013 Research-status Report
  • [Remarks] プラズマ基礎工学研究室活動業績

    • URL

      http://nuclear.es.kit.ac.jp/new/?p=activity

    • Related Report
      2015 Annual Research Report
  • [Remarks] プラズマ基礎工学研究室ホームページ

    • URL

      http://nuclear.es.kit.ac.jp/~himura/

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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