Study on the transition metal complexes bearing a hypervalent silicon ligand and their application to catalytic reactions
| Project/Area Number |
25620024
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | The University of Tokyo |
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Principal Investigator |
Kano Naokazu 東京大学, 理学(系)研究科(研究院), 准教授 (00302810)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | 14族元素 / 超原子価化合物 / 結合形成 / 高配位化合物 / スズ / 超原子価 / 結合 / ケイ素 / ゲルマニウム / 遷移金属 |
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| Outline of Final Research Achievements |
Transition metal complexes bearing hypervalent silicon ligands were tried in vain to be synthesized for their application to efficient transition metal catalyst. The tin analogues were successfully synthesized. Their structures and properties were revealed. The tin ligand works as the Z-type ligand in these complexes. New types of homonuclear bonding of hypervalent germanium and tin atoms,respectively, were also synthesized and studied.
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Report
(4 results)
Research Products
(8 results)
