Synthesis of One-Dimensional Metal Chain Complexes through Oxidation-Metalation Sequence
| Project/Area Number |
25620049
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Institute for Molecular Science |
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Principal Investigator |
MURAHASHI Tetsuro 分子科学研究所, 協奏分子システム研究センター, 教授 (40314380)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | 金属クラスター / 金属鎖分子 |
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| Outline of Final Research Achievements |
One-dimensional metal chain complexes have attracted much attention because of their potential applications in molecular materials stemming from the low-dimensional structures. Recently, several reliable methods to construct one-dimensional metal chain structure has developed, but current synthetic methods still suffer from the low efficiency in construction of long metal chain structures. In this project, we successfully developed a new methodology to construct a metal chain compounds. By using the oxidation-metalation sequence, we synthesized the heptanuclear metal clusters from the tetranuclear metal clusters.
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Report
(3 results)
Research Products
(5 results)
