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Synthesis of One-Dimensional Metal Chain Complexes through Oxidation-Metalation Sequence

Research Project

Project/Area Number 25620049
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic chemistry
Research InstitutionInstitute for Molecular Science

Principal Investigator

MURAHASHI Tetsuro  分子科学研究所, 協奏分子システム研究センター, 教授 (40314380)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords金属クラスター / 金属鎖分子
Outline of Final Research Achievements

One-dimensional metal chain complexes have attracted much attention because of their potential applications in molecular materials stemming from the low-dimensional structures. Recently, several reliable methods to construct one-dimensional metal chain structure has developed, but current synthetic methods still suffer from the low efficiency in construction of long metal chain structures. In this project, we successfully developed a new methodology to construct a metal chain compounds. By using the oxidation-metalation sequence, we synthesized the heptanuclear metal clusters from the tetranuclear metal clusters.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (5 results)

All 2015 2014 2013

All Presentation (5 results) (of which Invited: 4 results)

  • [Presentation] Chemistry of Multinuclear Sandwich Complexes2015

    • Author(s)
      Tetsuro Murahashi
    • Organizer
      Pure and Applied Chemistry International Conference 2015 (PACCON 2015)
    • Place of Presentation
      Amari Watergate Hotel, Bangkok, Thailand
    • Year and Date
      2015-01-22
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] パラジウム4核鎖に対するπ共役ポリエン配位子の配位挙動の解明2014

    • Author(s)
      正井航平・白戸克典・山本浩二・村橋哲郎
    • Organizer
      第4回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀 東京都江戸川区
    • Year and Date
      2014-10-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] Dynamic Structural Changes of Multinuclear Sandwich Complexes2013

    • Author(s)
      Tetsuro Murahashi
    • Organizer
      Japan-China Joint Symposium for Coordination Nanomaterials
    • Place of Presentation
      分子科学研究所 愛知県
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Dynamic Structural Changes in Multinuclear Sandwich Complexes2013

    • Author(s)
      Tetsuro Murahashi
    • Organizer
      第63回錯体化学討論会国際シンポジウム
    • Place of Presentation
      琉球大学 沖縄県
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Chemistry of Metal Chain Sandwich Complexes2013

    • Author(s)
      Tetsuro Murahashi
    • Organizer
      Japan-Canada Joint Symposium for Coordination Chemistry
    • Place of Presentation
      ホテル日航那覇 沖縄県
    • Related Report
      2013 Research-status Report
    • Invited

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Published: 2014-07-25   Modified: 2019-07-29  

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