| Project/Area Number |
25620061
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Nara Institute of Science and Technology |
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Principal Investigator |
ARATANI Naoki 奈良先端科学技術大学院大学, 物質創成科学研究科, 准教授 (60372562)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | カーボンナノチューブ / クロスカップリング / ナノ材料 |
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| Outline of Final Research Achievements |
We have tried to synthesize zig-zag typed carbon nanotubes based on the perylene bis-imide (PBI) by a bottom up organic synthetic method. At first, we have synthesized m-phenylene-bridged PBI dimer by the Suzuki-Miyaura cross-coupling reaction. The structure was confirmed by single crystal X-ray diffraction analysis. Next, its oxidative ring closure reactions were attempted. Finally we have obtained completely flat benzene-fused PBI dimer in quite low yield. The structure obtained was also confirmed by single crystal X-ray diffraction analysis. Now we are trying to make oligomeric PBI arrays to form cyclic structure by intramolecular coupling reaction.
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