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Thermally Stable Thin Polymeric Multi-Layer Fromation with ALD

Research Project

Project/Area Number 25630118
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Electronic materials/Electric materials
Research InstitutionTohoku University

Principal Investigator

FUKUSHIMA Takafumi  東北大学, 未来科学技術共同研究センター, 准教授 (10374969)

Co-Investigator(Kenkyū-buntansha) MARIAPPAN Murugesan  東北大学, 未来科学技術共同研究センター, 産学官連携研究員 (10509699)
BEA Jichel  東北大学, 未来科学技術共同研究センター, 助教 (40509874)
Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords気相堆積重合 / ポリイミド / TSV / TSV
Outline of Final Research Achievements

A novel approach to suppress the conventional Cu-TSV induced thermo-mechanical stress in 3D-LSI chip is proposed, fabricated and tested. In this approach, a thermal-chemical-vapor-deposition grown organic polyimide is conformably deposited along the side wall of the TSV. Compared to ALD, the thickness controllability is not so high, but relatively high thickness control with a resolution of 10 nm in thickness is realized. The deposition rate is approximately 100-200nm/min. The step-coverage is approximately 80% for high-aspect-ratio TSV with the depth of 50 um and the diameter of 5 um, and the resulting polyimide thin layer is very pure and shows high thermal stability. As-grown polymer was evaluated for their role in minimizing the thermo-mechanical stress in vicinal and via-space Si. It was found that replacing the conventional SiO2 dielectric liner with organic polymer greatly helps in suppressing the thermo-mechanical stress.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (9 results)

All 2015 2014 2013 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (6 results) (of which Invited: 1 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Highly Beneficial Organic Liner with Extremely Low Thermal Stress for Fine Cu-TSV in 3D-Integration2014

    • Author(s)
      M. Murugesan , T. Fukushima, J.C. Bea, Y. Sato, H. Hashimoto, K.W. Lee , and M. Koyanagi
    • Journal Title

      IEEE International Electron Devices Meeting (IEDM) Technical Digest

      Volume: 61 Pages: 374-377

    • DOI

      10.1109/iedm.2014.7047054

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] 高分子材料を用いた三次元集積技術III:気相堆積ポリイミドTSVライナーの形成と特性評価2015

    • Author(s)
      福島誉史,Murugesan Mariappan,裵 志哲,橋本宏之,佐藤 優,李 康旭,小柳光正
    • Organizer
      エレクトロニクス実装学会 第29回春季講演大会
    • Place of Presentation
      東京大学(東京都文京区本郷7-3-1)
    • Year and Date
      2015-03-16 – 2015-03-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Characterization of Vapor Deposited Polyimides and Process Integration with the Polymeric Liner for Via-Last/Backside-Via Cu-TSV Formation2014

    • Author(s)
      Takafumi Fukushima, Murugesan Mariappan, Jichoel Bea, Kang-Wook Lee, and Mitsumasa Koyanagi
    • Organizer
      International Conference on Solid State Devices and Materials (SSDM)
    • Place of Presentation
      つくば国際会議場(つくば市竹園2-20-3)
    • Year and Date
      2014-09-09 – 2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Replacing the PECVD-SiO2 in the Through-Silicon Via of High-Density 3D LSIs with Highly Scalable Low Cost Organic Liner: Merits and Demerits2014

    • Author(s)
      Murugesan Mariappan, Takafumi Fukushima, JiChel Beatrix, Hiroyuki Hashimoto, Yutaka Sato, Kangwook Lee, Tetsu Tanaka and Mitsumasa Koyanagi
    • Organizer
      the 64th Electronic Components and Technology Conference (ECTC)
    • Place of Presentation
      Walt Disney World Swan and Dolphin Resort, Lake Buena Vista, Orlando, Florida, USA
    • Year and Date
      2014-05-27 – 2014-05-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] 気相堆積重合ポリイミドを用いたTSVライナー形成2014

    • Author(s)
      福島誉史
    • Organizer
      シリコンテクノロジー分科会
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Low-Temperature and High-Step-Coverage Polyimide TSV Liner Formation by Vapor Deposition Polymerization2013

    • Author(s)
      165. T. Fukushima, M. Murugesan, J. Bea, K.W. Lee, M. Koyanagi
    • Organizer
      Extended Abstract of International Conference on Solid State Devices and Materials (SSDM)
    • Place of Presentation
      福岡
    • Related Report
      2013 Research-status Report
  • [Presentation] Revisiting the Silicon-Lattice in the High-Density 3D-LSIs in the Perspective of Device Reliability2013

    • Author(s)
      85. M. Murugesan, T. Fukushima, J.C. Bea, K.W. Lee, T. Tanaka, and M. Koyanagi
    • Organizer
      IEEE International Electron Devices Meeting (IEDM) Technical Digest
    • Place of Presentation
      米国、Washington DC
    • Related Report
      2013 Research-status Report
  • [Remarks] 三次元スーパーチップLSI試作製造拠点

    • URL

      http://www.ginti.niche.tohoku.ac.jp/

    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 半導体装置およびその製造方法2014

    • Inventor(s)
      小柳光正、福島誉史、李康旭、田中徹
    • Industrial Property Rights Holder
      小柳光正、福島誉史、李康旭、田中徹
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-098449
    • Filing Date
      2014-05-12
    • Related Report
      2014 Annual Research Report

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Published: 2014-07-25   Modified: 2019-07-29  

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