Fabrication and Physical Properties of Growth-Controlled Metal-Organic Framework Thin Films
| Project/Area Number |
25810039
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
OTSUBO Kazuya 京都大学, 理学(系)研究科(研究院), 助教 (90601005)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | 多孔性配位高分子 / 薄膜 / ナノ界面技術 / 多孔性物質 / 金属有機構造体 / ヘテロ接合 |
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| Outline of Final Research Achievements |
By using simple layer-by-layer method, crystalline thin film of two-dimensional Hofmann-type metal-organic framework was successfully fabricated. The thin-film obtained shows clear guest adsorption behavior with gate-opening-type structural transformation, which have been revealed by in-situ X-ray studies. Moreover, enlargement of the thin film controlled by the thickness suppresses this dynamic behavior remarkably showing clear crystal downsizing effect.
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Report
(3 results)
Research Products
(28 results)
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[Journal Article] Influence of Confined Polymer Structure on Proton Transport Property in Sulfonated Polyimide Thin Films2014
Author(s)
Karthik Krishnan, Tomoaki Yamada, Hiroko Iwatsuki, Mitsuo Hara, Shusaku Nagano,Kazuya Otsubo, Osami Sakata, Akihiko Fujiwara, Hiroshi Kitagawa, Yuki Nagao
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Journal Title
Electrochemistry
Volume: 82
Issue: 10
Pages: 865-869
DOI
NAID
ISSN
1344-3542, 2186-2451
Related Report
Peer Reviewed
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