Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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Outline of Final Research Achievements |
By using simple layer-by-layer method, crystalline thin film of two-dimensional Hofmann-type metal-organic framework was successfully fabricated. The thin-film obtained shows clear guest adsorption behavior with gate-opening-type structural transformation, which have been revealed by in-situ X-ray studies. Moreover, enlargement of the thin film controlled by the thickness suppresses this dynamic behavior remarkably showing clear crystal downsizing effect.
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