| Project/Area Number |
25820392
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Japan Advanced Institute of Science and Technology |
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Principal Investigator |
Nishimura Shun 北陸先端科学技術大学院大学, マテリアルサイエンス研究科, 助教 (20610067)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Keywords | 複合金属ナノ粒子触媒 / 系統的評価 / バイメタル触媒 / 選択酸化反応 / バイオマス変換反応 / AuM型バイメタルナノ粒子触媒 / 電荷移動作用 / 幾何学構造作用 / 保護配位子 / 金属担持触媒 / 金属触媒反応 / バイメタルナノ粒子触媒 / アルコール類の選択酸化反応 / リガンド効果 |
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| Outline of Final Research Achievements |
On the basis of various identical contents such as ionic energy potential value, mixed-metal ratio, kinds of capping agent or supports, the systematic investigations of catalytic properties on the multi-composite nano-catalyst have been examined. This study indicated that (i) the ionic energy potential value would be a nice function to survey the performance of various bimetallic nanoparticle catalysts, (ii) the metal ratio influenced on the internal electron transfer phenomena in the bimetallic nanoparticle catalysts, and (iii) the kinds of capping agent and support have crucial roles for local environment around the catalytic active center, and these (ii and iii) controlled the catalytic function on the multi-composite nano-catalyst.
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