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Up-conversion Emission of Organic Materials in Large Barrier height

Research Project

Project/Area Number 25870212
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Energy-related chemistry
Functional solid state chemistry
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

KENRO Totani  東京農工大学, 工学(系)研究科(研究院), 技術専門職員 (50397014)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsアップコンバージョン / 燐光 / 逆エネルギー移動 / 長寿命 / 光化学 / 光物性
Outline of Final Research Achievements

In this research, Conversion of thermal energy to photon due to thermally activated reversed energy transfer between the various types of donor and acceptor organic molecules was succeeded, applying the results of previous researches that the use of an amorphous rigid host significantly maintain excited state more than several seconds at room temperature in air. Barrier height of between the energy states of donor and acceptor is more than 0.4 eV, exhibiting conversion from red colored emission to green colored emission, and from yellow-green colored emission to blue-green colored emission. The efficiency of conversion yield increased with increasing temperature, and this will be expected in the application for the visualizing temperature as thermal sensors.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (2 results)

All 2013

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (1 results)

  • [Journal Article] Thermoresponsive Persistent Phosphorescent Color Change Using Efficient Thermally Activated Reverse Energy Transfer with a Large Energy Difference2013

    • Author(s)
      Kenro Totani, Yuya Okada, Shuzo Hirata, Martin Vacha and Toshiyuki Watanabe
    • Journal Title

      Adv. Opt. Mater

      Volume: 1(4) Issue: 4 Pages: 283-288

    • DOI

      10.1002/adom.201300013

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 大きなエネルギー差の熱活性化エネルギー移動を利用した、温度応答型燐光色変化2013

    • Author(s)
      戸谷健朗
    • Organizer
      光科学討論会
    • Place of Presentation
      愛媛大学
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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