Controlled formation and functionality of inter-cluster nano-space
| Project/Area Number |
25870387
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
Nanostructural chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
Yoshinari Nobuto 大阪大学, 理学(系)研究科(研究院), 助教 (10583338)
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| Co-Investigator(Renkei-kenkyūsha) |
KONNO Takumi 大阪大学, 大学院理学研究科, 教授 (50201497)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
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| Keywords | 金属クラスター集積体 / 多孔性材料 / 水吸着 / 含硫アミノ酸 / 結晶構造 / 金属クラスター / 配列制御 / 間隙空間 / 超親水性 / 多孔性イオン結晶 / チオラト錯体 / 水素結合 / 多核金属錯体 / クラスター間化合物 / プロトン伝導体 / システイン |
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| Outline of Final Research Achievements |
In this research project, the aggregation behavior of cationic or anionic metal clusters by combining with various counter-ions was investigated in order to construct metal cluster assemblages that possess large pores in the crystal lattice. As a result, it was found that metal cluster assemblages made up from a spherical-shaped Rh4Zn4 octanuclear cluster anion ([Rh4Zn4(cys)12O]6-) or a rod-shaped Co2Au3 pentanuclear cluster anion ([Co2Au3(pen)6]3-) show high water adsorption capability.
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Report
(4 results)
Research Products
(25 results)
