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Deterioration of Acrylic Resin used to Conservation of Excavated Bronze Cultural Properties

Research Project

Project/Area Number 26282072
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Cultural assets study and museology
Research InstitutionGangoji Institute for Research of Cultural Property

Principal Investigator

Ueda Naomi  公益財団法人元興寺文化財研究所, 研究部, 研究員 (10193806)

Co-Investigator(Kenkyū-buntansha) 山口 繁生  公益財団法人元興寺文化財研究所, 研究部, 研究員 (00752370)
川本 耕三  公益財団法人元興寺文化財研究所, 研究部, 研究員 (10241267)
塚本 敏夫  公益財団法人元興寺文化財研究所, 研究部, 研究員 (30241269)
難波 洋三  独立行政法人国立文化財機構奈良文化財研究所, 埋蔵文化財センター, 客員研究員 (70189223)
Co-Investigator(Renkei-kenkyūsha) YAMADA Takashi  公益財団元興寺文化財研究所, 研究部, 研究員 (30435903)
TANAKA Yuri  公益財団元興寺文化財研究所, 研究部, 研究員 (70611614)
YAMAOKA Namie  公益財団元興寺文化財研究所, 研究部, 研究員 (90372169)
YOSHIDA Hiroshi  愛媛大学, ミュージアム, 准教授 (30263057)
Project Period (FY) 2014-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Fiscal Year 2017: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2014: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Keywordsアクリル樹脂 / 劣化 / 出土青銅製品 / 化学分析 / 出土青銅製文化財 / 全反射赤外分光分析 / 熱分解-ガスクロマト-質量分析 / ゲルろ過クロマトグラフィー / 熱分析 / 核磁気共鳴 / 分子構造 / 膜機能 / 赤外分光分析 / ゲルろ過クロマトグラフィ / 溶剤 / 熱分解‐ガスクロマト/質量分析 / ゲル透過クロマトグラフィ / 保管・展示環境
Outline of Final Research Achievements

Changes in the molecular structure of the acrylic resin for impregnation used for conservation treatment of bronze artifacts excavated from Kojindani site were analyzed by infrared spectroscopy, pyrolysis-gas chromatograph/mass spectrometry, gel permeation chromatography, etc.. As a result, it was changed of the molecular structure compared with the fresh resin.
It was confirmed whether these changes were deterioration which degrades the function. As a result, contamination of adhesives and the like used at the time of conservation treatment was observed in addition to the impregnating resin. For that reason, we did not reach the evaluation of functionality at the present time.In addition, as a result of forcibly deteriorating the fresh resin by heating or addition of moisture, it was found that changes were caused by heating under high humidity. However, it was also found that no change was observed in the presence of solvent even in high temperature and high pressure environment.

Report

(5 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (6 results)

All 2018 2017 2016 2015

All Presentation (6 results) (of which Int'l Joint Research: 2 results)

  • [Presentation] 出土青銅製文化財の保存処理に使用されたアクリル樹脂の劣化について(4)2018

    • Author(s)
      山田卓司・山口繁生・田中由里・塚本敏夫・川本耕三・植田直見
    • Organizer
      日本文化財科学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 出土金属製品の保存処理に使用されたアクリル樹脂の劣化について2017

    • Author(s)
      植田直見・山田卓司・山口繁生・田中由理・塚本敏夫・川本耕三
    • Organizer
      第6回東アジア文化遺産シンポジウム
    • Place of Presentation
      上海復旦大学
    • Year and Date
      2017-08-24
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 出土青銅製文化財の保存処理に使用されたアクリル樹脂の劣化について(3)2017

    • Author(s)
      植田直見・山田卓司・山口繁生・田中由里・塚本敏夫・川本耕三
    • Organizer
      日本文化財科学会
    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
  • [Presentation] 出土金属製品の保存処理に使用されたアクリル樹脂の劣化について2017

    • Author(s)
      植田直見・山田卓司・山口繁生・田中由里・塚本敏夫・川本耕三
    • Organizer
      第6回東アジア文化遺産シンポジウム
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 出土青銅製文化財の保存処理に使用されたアクリル樹脂の劣化について(2)2016

    • Author(s)
      山田卓司・川本耕三・山口繁生・塚本敏夫・田中由理・植田 直見
    • Organizer
      日本文化財科学会
    • Place of Presentation
      奈良大学
    • Year and Date
      2016-06-04
    • Related Report
      2015 Annual Research Report
  • [Presentation] 出土青銅製文化財の保存処理に使用されたアクリル樹脂の劣化について2015

    • Author(s)
      植田 直見・塚本敏夫・山田卓司・山口繁生・田中由理・川本耕三
    • Organizer
      2015東アジア文化遺産保存国際シンポジウム
    • Place of Presentation
      奈良春日野国際フォーラム 甍~I・RA・KA~(能楽ホール)
    • Year and Date
      2015-08-26
    • Related Report
      2015 Annual Research Report

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Published: 2014-04-04   Modified: 2019-03-29  

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