Organic-inorganic hybrid materials constituted of alternating oxo-copolymers

• Project/Area Number: 26288108
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Partial Multi-year Fund
• Section: 一般
• Research Field: Inorganic industrial materials
• Research Institution: Osaka Prefecture University
• Principal Investigator: takahashi Masahide 大阪府立大学, 工学(系)研究科(研究院), 教授 (20288559)
• Co-Investigator(Kenkyū-buntansha): 徳留 靖明 大阪府立大学, 工学(系)研究科(研究院), 准教授 (50613296)
• Project Period (FY): 2014-04-01 – 2017-03-31
• Project Status: Completed (Fiscal Year 2016)
• Budget Amount: ¥16,510,000 (Direct Cost: ¥12,700,000、Indirect Cost: ¥3,810,000); Fiscal Year 2016: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000); Fiscal Year 2015: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000); Fiscal Year 2014: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
• Keywords: 有機ー無機ハイブリッド材料 / ゾルーゲル / かご形分子 / ナノ材料 / 複合材料・物性 / 有機-無機ハイブリッド材料 / 酸化物高分子 / ガラス / 分子制御 / 有機ｰ無機ハイブリッド

Outline of Final Research Achievements

Organic-inorganic hybrid materials of alternating oxo-copolymers with organic-functional group as side group have been prepared. Special attention was paid to synthesis of oligomers with well-defined network structures. As a results, designed main chain structures of oxo-polyhedrons were prepared. The polymers prepared from the oligomers with well-defined structures were prepared in which the network structures are completely designed. These oxo-copolymers showed better thermal properties compared with the polymers with a random main chains.

Research Products

• [Int'l Joint Research] グラーツ工科大学(オーストリア)
• [Int'l Joint Research] アデレード大学(オーストラリア)
• [Int'l Joint Research] ポルト大学(ポルトガル)
• [Int'l Joint Research] マンチェスター大学(英国)
• [Int'l Joint Research] ブエノスアイレス大学/サンマルティン大学(アルゼンチン)
• [Journal Article] Centimetre scale micropore alignment in oriented polycrystalline Metal-Organic Framework films via heteroepitaxial growth (2017)
  • Author(s): Falcaro P., Okada K., Hara T., Ikigaki K., Tokudome Y., Thornton A.W., Hill A.J., Williams T., Doonan C., Takahashi M.,
  • Journal Title: Nature Mater. Volume: 16 Issue: 3 Pages: 342-348
  • DOI: 10.1038/nmat4815
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] High-Density Protein Loading on Hierarchically Porous LDH-Aluminum Hydroxide Composites with a Rational Mesostructure (2016)
  • Author(s): Tokudome Y., Fukui M., Tarutani N., Nishimura S., Prevot V., Forano C., Poologasundarampillai G., Lee P., Takahashi M.,
  • Journal Title: Langmuir Volume: 32 Issue: 35 Pages: 8826-8833
  • DOI: 10.1021/acs.langmuir.6b01925
  • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Single-nanometer sized low-valence metal hydroxide crys-tals: synthesis via epoxide-mediated alkalinization and as-sembly towards functional mesoporous materials (2016)
  • Author(s): Naoki Tarutani, Yasuaki Tokudome, Matias Jobbagy, Federico A. Viva, Galo J. A. A. Soler-Illia, Masahide Takahashi
  • Journal Title: Chemistry of Materials Volume: 28 Issue: 16 Pages: 5606-5610
  • DOI: 10.1021/acs.chemmater.6b02510
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Superhydrophobic adhesive surface on titanate nanotube brushes through surface modification by capric acid (2016)
  • Author(s): Okada K., Tokudome Y., Takahashi M.,
  • Journal Title: J. Sol-Gel Sci. Technol., Volume: 79 Issue: 2 Pages: 389-394
  • DOI: 10.1007/s10971-016-4106-0
  • Acknowledgement Compliant
• [Journal Article] Layered Double Hydroxide Nanocluster: Aqueous, Concentrated, Stable, and Catalytically-Active Colloids Towards Green Chemistry (2016)
  • Author(s): Tokudome Y., Morimoto T., Tarutani N., Vaz P., Nunes C., Prevot V., Stenning G., Takahashi M.
  • Journal Title: ACS Nano Volume: 10 Issue: 5 Pages: 5550-5559
  • DOI: 10.1021/acsnano.6b02110
  • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Functional interfaces of titanate nanotubes with controlled orientation/aggregation (2016)
  • Author(s): Takahashi M.
  • Journal Title: Journal of the Ceramic Society of Japan Volume: 124 Issue: 5 Pages: 495-499
  • DOI: 10.2109/jcersj2.16008
  • NAID: 130005149943
  • ISSN: 1348-6535, 1882-0743
  • Peer Reviewed / Open Access
• [Journal Article] Thermo-responsive wrinkles on hydrogels for soft linear actuators (2016)
  • Author(s): Tokudome Y., Kuniwaki H., Suzuki K., Carboni D., Poologasundarampillai G., Takahashi M.
  • Journal Title: Adv. Mater. Interfaces, Volume: 3 Issue: 12 Pages: 1-4
  • DOI: 10.1002/admi.201500802
  • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Large Scale Preparation of Morphology-Controlled Microporous Silica Particles via Gradual Injection of Reactants with Different Surfactant (2016)
  • Author(s): Shimogaki T., Tokoro H., Tabuchi M., Koike N., Yamashina Y., Takahashi M.
  • Journal Title: J. Sol-Gel Sci. Technol. Volume: 78 Issue: 3 Pages: 1-7
  • DOI: 10.1007/s10971-015-3942-7
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Morphology Control of BiFeO3 Aggregates via Hydrothermal Synthesis (2016)
  • Author(s): Suzuki K., Tokudome Y., Tsuda H., Takahashi M.,
  • Journal Title: J. Appl. Cryst Volume: 49 Issue: 1 Pages: 168-174
  • DOI: 10.1107/s1600576715023845
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Morphology Control of BiFeO3 Aggregates via Hydrothermal Synthesis (2016)
  • Author(s): Suzuki K., Tokudome Y., Tsuda H., Takahashi M.
  • Journal Title: J. Appl. Cryst. Volume: 49 Issue: 127 Pages: 168-174
  • DOI: 10.1039/c5ra19914j
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Fabrication of Hierarchically Porous Monolithic Layered Double Hydroxide Composites with Tunable Microcages as an Effective and Selective Oxyanion Adsorbent (2015)
  • Author(s): Tarutani N., Tokudome Y., Nakanishi K., Takahashi M.
  • Journal Title: RSC Adv. Volume: 5 Issue: 70 Pages: 57187-57192
  • DOI: 10.1039/c5ra05942a
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Morphology Control of Microporous Silica Particles Obtained by Gradual Injection of Reactants (2015)
  • Author(s): Shimogaki T., Tokoro H., Tabuchi M., Koike N., Yamashina Y., Takahashi M.,
  • Journal Title: J. Sol-Gel Sci. Technol Volume: 76 Issue: 1 Pages: 156-163
  • DOI: 10.1007/s10971-015-3762-9
  • Peer Reviewed / Open Access
• [Journal Article] Sol to gel silica transition in fast evaporating systems observed by in situ time resolved infrared spectroscopy (2015)
  • Author(s): Innocenzi P., Malfatti L., Carboni D., Takahashi M.,
  • Journal Title: ChemPhysChem, Volume: 16 Issue: 9 Pages: 1933-1939
  • DOI: 10.1002/cphc.201500126
  • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Positioning of the HKUST-1 Metal-Organic Framework (Cu3(BTC)2) Through Conversion of Insoluble Cu-based Precursors (2015)
  • Author(s): T. Toyao, K. Liang, K. Okada, R. Ricco, M. J. Styles, Y Tokudome, Y. Horiuchi, A. J. Hill, M. Takahashi, M. Matsuoka, P. Falcaro
  • Journal Title: Inorganic Chemistry Frontiers Volume: 2 Issue: 5 Pages: 1-1
  • DOI: 10.1039/c4qi00215f
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Energy transfer induced by carbon quantum dots in porous zinc oxide nanocomposite films (2015)
  • Author(s): Suzuki K., Malfatti L., Carboni D., Loche D., Casula M., Moretto A., Maggini M., Takahashi M., Innocenzi P.
  • Journal Title: J. Phys. Chem. C Volume: 119 Issue: 5 Pages: 2837-2843
  • DOI: 10.1021/jp510661d
  • Peer Reviewed / Open Access
• [Journal Article] Transparent and robust siloxane-based hybrid lamella film as a water vapor barrier coating (2014)
  • Author(s): Tokudome Y., Hara, T., Abe R., Takahashi M.,
  • Journal Title: ACS Appl. Mater. Interfaces Volume: 6 Issue: 21 Pages: 19355-19359
  • DOI: 10.1021/am5054477
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Copper conversion into Cu(OH)2 nanotubes for positioning Cu3(BTC)2 MOF crystals: controlling the growth on flat plates, 3D architectures and as patterns (2014)
  • Author(s): K. Okada, R. Ricco, Y. Tokudome, M. J. Styles, A. J. Hill, M. Talahashi, P. Falcaro
  • Journal Title: Advanced Functional Materials Volume: 24 Issue: 14 Pages: 1969-1977
  • DOI: 10.1002/adfm.201303303
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Micropattern formation by molecular migration via UV-induced dehydration of block copolymer (2014)
  • Author(s): K. Okada, Y. Tokudome, R. Makiura, K. Konstas, L. Malfatti, P. Innocenzi, H. Ogawa, T. Kanaya, P. Falcaro, M. Takahashi
  • Journal Title: Advanced Functional Materials Volume: 24 Issue: 19 Pages: 2801-2809
  • DOI: 10.1002/adfm.201302812
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Presentation] Epitaxial growth of ‘single-crystal-like’ MOF on metal hydroxides (2016)
  • Author(s): Takahashi M.
  • Organizer: Fundamentals and Application of Advanced Porous Materials
  • Place of Presentation: the University of Adelaide
  • Year and Date: 2016-12-08
  • Int'l Joint Research / Invited
• [Presentation] Metal hydroxides as platform for interfacial functionalities (2016)
  • Author(s): Takahashi M.
  • Organizer: Brazilian Meeting on Inorganic Chemistry (BMIC)
  • Place of Presentation: Sao Pedro
  • Year and Date: 2016-09-25
  • Int'l Joint Research / Invited
• [Presentation] Thermoresponsive Wrinkles on Hydrogels for Micro Soft Actuators (2016)
  • Author(s): Takahashi M.
  • Organizer: 2nd international conference on Nano Materials
  • Place of Presentation: Mauritious
  • Year and Date: 2016-09-07
  • Int'l Joint Research / Invited
• [Presentation] Metal Hydroxides as a New Platform for Functional Nano Materials (2015)
  • Author(s): Takahashi M.
  • Organizer: iCeMS International Symposium on Processing and Engineering of Porous Materials
  • Place of Presentation: Kyoto University, Kyoto, Japan
  • Year and Date: 2015-11-27
  • Int'l Joint Research / Invited
• [Presentation] Metal Hydroxides as a New Platform for Functional Nano Materials (2015)
  • Author(s): Takahashi M.
  • Organizer: The International Symposium on Photocatalysis at Fuzhou University
  • Place of Presentation: Fuzou University, Fuzou, China
  • Year and Date: 2015-11-07
  • Int'l Joint Research / Invited
• [Presentation] Metal hydroxide nanotube brushes for functional interface (2015)
  • Author(s): Takahashi M.
  • Organizer: Nano Mercosur 2015
  • Place of Presentation: University of Buenos Aires, Buenos Aires, Argentina
  • Year and Date: 2015-09-07
  • Int'l Joint Research / Invited
• [Presentation] Stimuli-responsive microarchitectures with peristaltic capabilities based on bilayered hybrid materials (2015)
  • Author(s): Takahashi M.
  • Organizer: Nanoapp 2015 Conference
  • Place of Presentation: Hotel Habasku, Maribor, Slovenia
  • Year and Date: 2015-06-23
  • Int'l Joint Research / Invited
• [Presentation] 分子レベルで構造制御したケイリン酸ガラスの作製と物性評価 (2015)
  • Author(s): 古金卓也、徳留靖明、高橋雅英
  • Organizer: 日本セラミックス協会2015年年会
  • Place of Presentation: 岡山大学
  • Year and Date: 2015-03-14 – 2015-03-16
• [Presentation] Chemical approach for organic-inorganic hybrid glassy materials of predetermined network structures: preparation and optical applications (2014)
  • Author(s): Masahide Takahashi
  • Organizer: International Symposium on Non-Oxide and New Optical Glasses
  • Place of Presentation: チェジュ島、韓国
  • Year and Date: 2014-08-22 – 2014-08-25
  • Invited
• [Presentation] 分子設計による形態制御ケイリン酸ガラスの作製と物性評価 (2014)
  • Author(s): 古金卓也, 徳留靖明，高橋雅英
  • Organizer: 第9回 日本セラミックス協会 関西支部 学術講演会
  • Place of Presentation: 大阪府立大学
  • Year and Date: 2014-07-24
• [Presentation] Highly doped organic-inorganic hybrid materials for memory and laser applications (2014)
  • Author(s): Masahide Takahashi
  • Organizer: 13th International Conference on Modern Materials and Technologies
  • Place of Presentation: Montecacini terme, Italy
  • Year and Date: 2014-06-08 – 2014-06-18
  • Invited