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Thin-Thick Transition of Foam Film Driven by Surface Phase Transition of Cationic Surfactant - Alkane Mixed Adsorbed Film

Research Project

Project/Area Number 26400434
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Biological physics/Chemical physics/Soft matter physics
Research InstitutionKyushu University

Principal Investigator

Matsubara Hiroki  九州大学, 理学研究院, 准教授 (00372748)

Research Collaborator IKEDA Norihiro  福岡女子大学, 国際文理学部, 教授 (30211030)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords界面活性剤 / 吸着膜相転移 / 泡膜の安定性 / 電気二重層 / 泡膜 / 分離圧 / 界面吸着膜
Outline of Final Research Achievements

A basic unit of foam is a thin aqueous film stabilized by surfactant adsorbed films and, in order to prevent foam film from rapturing, some sort of repulsion across the foam film is required. The metastable foam film stabilized by electrical double layer repulsion between adsorbed films is called a common black film (CBF). One of the unique features of CBFs is the thinning transition to a Newton black film (NBF) in which the electrical repulsion is diminished by added electrolyte, and the overlap of the hydration shells of surfactant head groups stabilized the foam film. In this work, we demonstrated that the first example of the temperature-driven thinning transition between different-thickness CBFs. The phase transition of the surfactant-alkane mixed adsorbed film was used for this purpose. Similar procedure was also applied to stabilize OW emulsions.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (41 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (1 results) Journal Article (13 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 13 results,  Open Access: 1 results,  Acknowledgement Compliant: 3 results) Presentation (26 results) (of which Int'l Joint Research: 3 results,  Invited: 7 results) Book (1 results)

  • [Int'l Joint Research] Durham University(英国)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Line tension and its influence on droplets and particles at surfaces.2017

    • Author(s)
      B. M. Law, S. P. McBride, J. Y. Wang, H. S. Wi, G. Paneru, S. Betelu, B. Ushijima, Y. Takata, B. Flanders, F. Bresme, H. Matsubara, T. Takiue, M. Aratono
    • Journal Title

      Progress in Surface Science

      Volume: 92 Issue: 1 Pages: 1-39

    • DOI

      10.1016/j.progsurf.2016.12.002

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] A competitive relationship between wetting of oil lens and condensed film formation of fluorinated alkanol at the air-water interface2016

    • Author(s)
      Y. Tokiwa, K. Ibi, T. Toyomasu, H. Sakamoto, T. Takiue, N. Ikeda, M. Aratono, H. Matsubara
    • Journal Title

      International Journal of Nanotechnology

      Volume: 13 Issue: 10/11/12 Pages: 734-747

    • DOI

      10.1504/ijnt.2016.080355

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A competitive relationship between wetting of oil lens and condensed film formation of fluorinated alkanol at the air-water interface2016

    • Author(s)
      Y. Tokiwa, K. Ibi, T. Toyomasu, H. Sakamoto, T. Takiue, N. Ikeda, M. Aratono, H. Matsubara
    • Journal Title

      Journal of Nanoscience and Nanotechnology

      Volume: --

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of Hydrophobic Chain Structure on Phase Transition and Domain Formation of Hybrid Alcohol Films Adsorbed at the Hexane/Water Interface2015

    • Author(s)
      K. Mitani, Y. Imai, T. Ina, K. Nitta, H. Tanida, T. Uruga, H. Matsubara, M. Aratono, T. Takiue
    • Journal Title

      J. Phys. Chem. B

      Volume: 119 Issue: 38 Pages: 12436-12445

    • DOI

      10.1021/acs.jpcb.5b07632

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Adsorbed Film of n-Tetradecylphosphocholine at the Tetradecane/Water Interface Studied by Interfacial Tensiometry and X-ray Reflection.2015

    • Author(s)
      S. Hiraki, T. Goto, K. Nitta, H. Tanida, T. Uruga, H. Matsubara, M. Aratono, T. Takiue
    • Journal Title

      Colloids and Surfaces A

      Volume: 482 Pages: 454-463

    • DOI

      10.1016/j.colsurfa.2015.06.033

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of Alkane Chain Length and Counterion on the Freezing Transition of Cationic Surfactant Adsorbed Film at Alkane Mixture-Water Interfaces2015

    • Author(s)
      Y. Tokiwa, H. Sakamoto, T. Takiue, M. Aratono, H. Matsubara
    • Journal Title

      J. Phys. Chem. B

      Volume: 119 Issue: 20 Pages: 6235-6241

    • DOI

      10.1021/acs.jpcb.5b02448

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Liquid droplet coalescence and fragmentation at the aqueous-air surface2015

    • Author(s)
      P. Govind, B.M. Law, K. Ibi, B. Ushijima, F. Bret, M. Aratono, H. Matsubara
    • Journal Title

      Langmuir

      Volume: 31 Issue: 1 Pages: 132-139

    • DOI

      10.1021/la502163e

    • Related Report
      2015 Research-status Report 2014 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Probing the self-aggregation behavior and counter ion distribution of a copper surfactant complex2014

    • Author(s)
      R. Kaur, S. Gupta, S.K. Mehta, Y. Imai, T. Takiue, H. Matsubara, M. Aratono
    • Journal Title

      New Journal of Chemistry

      Volume: 38 Issue: 8 Pages: 3925-3932

    • DOI

      10.1039/c4nj00620h

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of molecular orientation on monolayer and multilayer formations of fluorocarbon alcohol and fluorocarbon-α,ω-diol Mixture at the hexane/water Interface2014

    • Author(s)
      R. Fukuhara, H. Tanida, K. Nitta, T. Ina, T. Uruga, H. Matsubara, M. Aratono, T. Takiue
    • Journal Title

      J. Phys. Chem. B

      Volume: 118 Issue: 43 Pages: 12451-12461

    • DOI

      10.1021/jp507049z

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic study on the interaction of imidazolium salts and POE-type nonionic surfactant in the adsorbed film2014

    • Author(s)
      H.H. Li, T. Takiue, H. Matsubara, M. Aratono
    • Journal Title

      Collid Polym. Sci.

      Volume: 292 Issue: 5 Pages: 1209-1215

    • DOI

      10.1007/s00396-014-3172-5

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Miscibility of imidazolium and pyridinium ionic liquids including BF4- ions at the air/water interface.2014

    • Author(s)
      H. Takumi, Y. Imai, N. Toh, H. Matsubara, T. Takiue, M. Aratono
    • Journal Title

      Colloids and Surfaces A

      Volume: 441 Pages: 59-65

    • DOI

      10.1016/j.colsurfa.2013.08.064

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Surface Freezing and Molecular Miscibility of Binary Alkane-Alkane and Fluoroalkane-Alkane Liquid Mixtures2014

    • Author(s)
      T. Takiu, M. Shimasaki, M. Tsuura, H. Sakamoto, H. Matsubara, M. Aratono
    • Journal Title

      J. Phys. Chem. B

      Volume: 118 Issue: 6 Pages: 1519-1526

    • DOI

      10.1021/jp406431m

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Line tension of alkane lenses on aqueous surfactant solutions at phase transitions of coexisting interfaces2014

    • Author(s)
      H. Matsubara, B. Ushijima, B.M. Law, T. Takiue, M. Aratono
    • Journal Title

      Adv. Colloid Interface Sci.

      Volume: 206 Pages: 186-194

    • DOI

      10.1016/j.cis.2013.07.001

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Unique Colloidal Systems from Simple Components -Utilization of 2D Phase Transition-2017

    • Author(s)
      Hiroki Matsubara
    • Organizer
      IRTG 1524 colloquium on Self-Assembled Soft-Matter Nanostructures at Interfaces
    • Place of Presentation
      Technische Universitat Berlin
    • Year and Date
      2017-03-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] シンプルな構成要素から誘起される複雑・多様な界面現象~吸着膜相転移の視点から~2016

    • Author(s)
      松原弘樹
    • Organizer
      広島大学大学院総合科学研究科 要素-システム研究セミナー
    • Place of Presentation
      広島大学
    • Year and Date
      2016-11-18
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 陽イオン界面活性剤-アルカン混合吸着膜の対イオン結合度に吸着膜の相転移と表面電荷密度が及ぼす影響2016

    • Author(s)
      今井洋輔
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      旭川医科大学
    • Year and Date
      2016-09-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] Stability control of OW emulsion by surface phase transition2016

    • Author(s)
      Hiroki Matsubara
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      旭川医科大学
    • Year and Date
      2016-09-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] 界面活性剤混合吸着膜の組成と分子間相互作用が泡膜の物性に与える影響2016

    • Author(s)
      藤田大助
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      旭川医科大学
    • Year and Date
      2016-09-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] 油/水界面における陽イオン界面活性剤-長鎖アルコール混合系の凝縮膜形成2016

    • Author(s)
      益永章裕
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      旭川医科大学
    • Year and Date
      2016-09-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] 陽イオン界面活性剤-アルカン混合吸着膜の相転移に誘起される泡膜の膜厚転移2016

    • Author(s)
      松原弘樹
    • Organizer
      日本物理学会秋季年会
    • Place of Presentation
      金沢大学
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 構造制御された吸着膜の相互作用の研究から泡・エマルションの安定性の問題へ2015

    • Author(s)
      松原弘樹
    • Organizer
      花王株式会社和歌山研究所セミナー
    • Place of Presentation
      花王株式会社和歌山研究所
    • Year and Date
      2015-12-21
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 陽イオン界面活性剤-非イオン界面活性剤混合吸着膜により形成された泡膜中における対イオン結合度の調整機構2015

    • Author(s)
      秦雄亮、吉村美紀、池田宜弘、瀧上隆智、荒殿誠、松原弘樹
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学
    • Year and Date
      2015-09-10
    • Related Report
      2015 Research-status Report
  • [Presentation] 薄膜圧バランス法による泡膜の分離圧等温線の測定2015

    • Author(s)
      船津光子、池田宜弘、瀧上隆智、荒殿誠、松原弘樹
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学
    • Year and Date
      2015-09-10
    • Related Report
      2015 Research-status Report
  • [Presentation] Regulation of Counterion Binding in the Foam Films Stabilized by Cationic-Nonionic Surfactant Mixed Adsorbed Films2015

    • Author(s)
      H. Matsubara
    • Organizer
      International Conference of Colloids and Interface Science, 2015
    • Place of Presentation
      台湾科技大学
    • Year and Date
      2015-07-22
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Effect of phase transition of surfactant adsorbed films on the stability of foam and emulsion systems2015

    • Author(s)
      H. Matsubara
    • Organizer
      Energy Materials Nanotechnology
    • Place of Presentation
      Phuket, Thailand
    • Year and Date
      2015-05-08 – 2015-05-11
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Effect of phase transition of surfactant adsorbed films on the stability of foam and emulsion systems2015

    • Author(s)
      H. Matsubara
    • Organizer
      EMN Meeting on Droplets
    • Place of Presentation
      Holiday Inn Resort Phuket
    • Year and Date
      2015-05-08
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] アルカンー水界面における陽イオン界面活性剤の凝縮膜形成に与える溶媒の炭化水素鎖長と対イオンの効果2014

    • Author(s)
      常盤祐平,瀧上隆智,荒殿誠,松原弘樹
    • Organizer
      第31回九州コロイドコロキウム
    • Place of Presentation
      佐賀大学
    • Year and Date
      2014-12-19 – 2014-12-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 水表面でのフルオロアルカノールのアルカン溶液の濡れ挙動と 界面膜状態2014

    • Author(s)
      井樋幸輝,瀧上隆智,荒殿誠,松原弘樹
    • Organizer
      第31回九州コロイドコロキウム
    • Place of Presentation
      佐賀大学
    • Year and Date
      2014-12-19 – 2014-12-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 陽イオン-非イオン界面活性剤混合系の吸着膜組成と 泡膜の安定性に関する研究2014

    • Author(s)
      秦雄亮,池田宜弘,瀧上隆智,荒殿誠,松原弘樹
    • Organizer
      第31回九州コロイドコロキウム
    • Place of Presentation
      佐賀大学
    • Year and Date
      2014-12-19 – 2014-12-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 臭化ヘキサデシルトリメチルアンモニウムで安定化された 泡膜とO/W型エマルション膜の黒膜構造の比較2014

    • Author(s)
      船津光子,吉村美紀,松原弘樹,荒殿誠,池田宜弘
    • Organizer
      第31回九州コロイドコロキウム
    • Place of Presentation
      佐賀大学
    • Year and Date
      2014-12-19 – 2014-12-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 陽イオン界面活性剤-アルカン混合吸着膜の相転移に 誘起される泡膜の膜厚転移2014

    • Author(s)
      松原弘樹,田中宏樹,荒殿誠,瀧上隆智,池田宜弘
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 空気-界面活性物質油溶液-水系における吸着膜相転移とアルカンレンズの濡れ挙動2014

    • Author(s)
      井樋幸輝,瀧上隆智,荒殿誠,松原弘樹
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 臭化ヘキサデシルトリメチルアンモニウムで安定化された泡膜とO/W型エマルション膜の黒膜構造の比較2014

    • Author(s)
      船津光子,吉村美紀,松原弘樹,荒殿誠,池田宜弘
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 陽イオン-非イオン界面活性剤混合系の吸着膜組成と泡膜の安定性に関する研究2014

    • Author(s)
      秦雄亮,池田宜弘,瀧上隆智,荒殿誠,松原弘樹
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] アルカン-水界面における陽イオン界面活性剤の 凝縮膜形成に与える溶媒と対イオンの効果2014

    • Author(s)
      常盤祐平,瀧上隆智,荒殿誠,松原弘樹
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] Line tension of alkane lenses on aqueous surfactant solutions at phase transitions of coexisting interfaces2014

    • Author(s)
      H. Matsubara, B. Ushijima, B.M. Law, T. Takiue, M. Aratono
    • Organizer
      Annual Meeting of Taiwan Colloid and Interface Science Society
    • Place of Presentation
      Tainan, Taiwan
    • Year and Date
      2014-07-10
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] NaBr 存在下での塩化ヘキサデシルトリメチルアンモニウム-ペンタエチレングリ-ルモノドデシルエーテル混合吸着膜とその泡膜に関する研究2014

    • Author(s)
      秦雄亮,吉村美紀,田中宏樹,池田宜弘,瀧上隆智,荒殿誠,松原弘樹
    • Organizer
      第51回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2014-06-28
    • Related Report
      2014 Research-status Report
  • [Presentation] Thickness transition of foam films driven by the freezing transition of cationic surfactant adsorbed films2014

    • Author(s)
      H. Matsubara, H. Tanaka, T. Takiue, N. Ikeda, M. Aratono
    • Organizer
      20th Surfactant in Solutions
    • Place of Presentation
      Coimbra, Portugal
    • Year and Date
      2014-06-22 – 2014-06-27
    • Related Report
      2014 Research-status Report
  • [Presentation] Effect of solvents and counterions on the condensed film formation of cationic surfactants at alkane-water interfaces2014

    • Author(s)
      Y. Tokiwa, T. Takiue, M. Aratono, H. Matsubara
    • Organizer
      20th Surfactant in Solutions
    • Place of Presentation
      Coimbra, Portugal
    • Year and Date
      2014-06-22 – 2014-06-27
    • Related Report
      2014 Research-status Report
  • [Book] Impact of line tension on colloidal systems2016

    • Author(s)
      松原弘樹、瀧上隆智、荒殿誠
    • Total Pages
      14
    • Publisher
      Wiley
    • Related Report
      2015 Research-status Report

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Published: 2014-04-04   Modified: 2022-02-16  

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