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Construction of Structure Models of Iron Hydroxide Nanominerals Using Scanning Transmission Electron Microscopy (STEM)

Research Project

Project/Area Number 26400512
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Petrology/Mineralogy/Economic geology
Research InstitutionNiigata University

Principal Investigator

KONISHI HIROMI  新潟大学, 自然科学系, 教授 (30705215)

Co-Investigator(Kenkyū-buntansha) 赤井 純治  新潟大学, 自然科学系, フェロー (30101059)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
KeywordsSTEM / ferrihydrite / schwertmannite / 走査透過電子顕微鏡 / フェリハイドライト / シュベルトマナイト / Siliceous ferrihydrite / Siliceous magnetite / 鉄還元バクテリア / 鉄水酸化物 / ラマン分光法
Outline of Final Research Achievements

We attempted to construct structure models of ferrihydrite and schwertmannite based on the Z-contrast images obtained by scanning transmission electron microscopy. Particles identified as 6-line ferrihydrite by electron diffraction and X-ray diffraction have ABAC, AB, and irregular stacking sequences. Unlike the models previously proposed, Fe occupies octahedral holes, but little or no Fe occupies the tetrahedral holes. Schwertmannite has been thought to have a structure similar to akageneite, but in the Z-contrast images, tunnels made of Fe octahedrons like those in akageneite were not observed.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (12 results)

All 2016 2015 Other

All Int'l Joint Research (1 results) Journal Article (4 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 4 results) Presentation (7 results) (of which Int'l Joint Research: 4 results)

  • [Int'l Joint Research] University of Wisconsin-Madison(米国)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Occurrences and distribution of "invisible" precious metals in sulfide deposits from the Edmond hydrothermal field, Central Indian Ridge2016

    • Author(s)
      Wu, ZW, Sun, XM, Xu, HF, Konishi, H, Wang, Y, Wang, C, Dai, YZ, Deng, XG, Yu, M
    • Journal Title

      ORE GEOLOGY REVIEWS

      Volume: 79 Pages: 105-132

    • DOI

      10.1016/j.oregeorev.2016.05.006

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Role of nano-goethite in controlling U(VI) sorption-desorption in subsurface soil2016

    • Author(s)
      Jung, HB, Xu, HF, Konishi, H, Roden, EE]
    • Journal Title

      JOURNAL OF GEOCHEMICAL EXPLORATION

      Volume: 169 Pages: 80-88

    • DOI

      10.1016/j.gexplo.2016.07.014

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Interstratification of graphene-like carbon layers within black talc from Southeastern China: Implications to sedimentary talc formation2016

    • Author(s)
      Li, CM, Wang, RC, Xu, HF, Lu, XC, Konishi, H, He, K
    • Journal Title

      AMERICAN MINERALOGIST

      Volume: 101 Issue: 7 Pages: 1668-1678

    • DOI

      10.2138/am-2016-5600

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Interactions Between Fe(III)-Oxides and Fe(III)-Phyllosilicates During Microbial Reduction 1: Synthetic Sediments2016

    • Author(s)
      Wu, T, Kukkadapu, RK, Griffin, AM, Gorski, CA, Konishi, H, Xu, HF, Roden, EE
    • Journal Title

      GEOMICROBIOLOGY JOURNAL

      Volume: 33 Issue: 9 Pages: 793-806

    • DOI

      10.1080/01490451.2015.1117546

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 鉄還元細菌によるヒ酸・亜ヒ酸吸着フェリハイドライトの変化とヒ素の挙動2016

    • Author(s)
      眞鍋達郎、小西博巳
    • Organizer
      日本鉱物科学会
    • Place of Presentation
      金沢市、金沢大学
    • Year and Date
      2016-09-23
    • Related Report
      2016 Annual Research Report
  • [Presentation] Fate of As(V) and As(III) during Bacterial Iron Reduction of Ferrihydrite2016

    • Author(s)
      Manabe, T., Konishi, H.
    • Organizer
      Goldschmidt2016
    • Place of Presentation
      Yokohama
    • Year and Date
      2016-06-26
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fate of As(V) and As(III) during Bacterial Iron Reduction of Ferrihydrite2016

    • Author(s)
      Manabe T & Konishi H
    • Organizer
      Goldschmidt 2016
    • Place of Presentation
      パシフィコ横浜(神奈川県・横浜)
    • Year and Date
      2016-06-26
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 鉄還元細菌によるAs,Zn 吸着フェリハイドライトの変化2015

    • Author(s)
      眞鍋達郎・小西博巳
    • Organizer
      日本鉱物科学会
    • Place of Presentation
      東京大学(東京)
    • Year and Date
      2015-09-25
    • Related Report
      2015 Research-status Report
  • [Presentation] 鉄還元細菌の活動によりSi ferrihydriteから変化したSiを含む磁鉄鉱と鉄に富む層状ケイ酸塩鉱物2015

    • Author(s)
      小西博巳・眞鍋達郎
    • Organizer
      日本鉱物科学会
    • Place of Presentation
      東京大学(東京)
    • Year and Date
      2015-09-25
    • Related Report
      2015 Research-status Report
  • [Presentation] Reduction of As- and Zn-Loaded Ferrihydrite by Iron-Reducing Bacteria2015

    • Author(s)
      Manabe T & Konishi H
    • Organizer
      Goldschmidt 2015
    • Place of Presentation
      Prague, CZ
    • Year and Date
      2015-08-16
    • Related Report
      2015 Research-status Report 2014 Research-status Report
    • Int'l Joint Research
  • [Presentation] Iron-Rich Clays and Si-Bearing Magnetite Produced by Iron-Reducing Bacteria2015

    • Author(s)
      Konishi H & Manabe T
    • Organizer
      Goldschmidt 2015
    • Place of Presentation
      Prague, CZ
    • Year and Date
      2015-08-16
    • Related Report
      2015 Research-status Report 2014 Research-status Report
    • Int'l Joint Research

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Published: 2014-04-04   Modified: 2022-02-16  

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