| Project/Area Number |
26410094
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Tokyo University of Science (2016-2017)
Nara Institute of Science and Technology (2014-2015) |
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Principal Investigator |
YUASA Junpei 東京理科大学, 理学部第一部応用化学科, 講師 (00508054)
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| Project Period (FY) |
2014-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 超分子 / 円偏光 / 配列 / 配位化合物 / DNA / 金属錯体 / ナノサイズ / 分子間相互作用 / 光化学 / 超分子化学 / ミスマッチDNA / カルバゾール / 金属イオン |
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| Outline of Final Research Achievements |
The aim of this research project is programmed-alignment of molecules using mismatched DNA template. To this aim, we have developed various planer type complexes that might be accessible for the mismatched DNA template. Through this research project, we obtained the several successful results, including, ratiometric luminescence thermometry (Chem. Com. 2014; Dalton Transactions, 2018), D2-Symmetrical Alternating Circular Helicate (JACS 2018), smart sensing methodology for object identification (Angewandte Chem 2018), Chiral Supramolecular Polymerization of lanthanide complexes (Chem. Com. 2016), and also novel photoactivatable lanthanide complexes (Chem. Com. 2017).
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