| Project/Area Number |
26410099
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Kagawa University (2015-2016)
Tokyo University of Science (2014) |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
TADOKORO Makoto 東京理科大学, 理学部, 教授 (60249951)
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | N-heteroacene / 有機機能性材料 / 有機無機機能性材料 / 超分子化学 / 刺激応答性材料 / ラジカルアニオン / レドックス / N-Heteroacene / 電子アクセプター / 自己組織化 / 有機薄膜材料 / 刺激応答性発光材料 / 液晶材料 / n型半導体 |
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| Outline of Final Research Achievements |
In this project, our object is to develop the organic functional materials and organic-inorganic materials based N-heteroacenes. We have synthesized self-organized liquid-crystalline N-heteroacenes. This liquid-crystalline phase should be stabilized by the induced dipole moment. Also, we have synthesized metal complexes based on N-heteroacene as organic ligand. we have synthesized stimuli-responsive fluorescent N-heteroacene showing blue emission in thin coated film. When this film is exposed to HCl vapor, the fluorescent color is changed from blue to orange.
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