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Development and Functional Evaluation of Novel Separation Materials of Metallohosts and Ionic Liquids

Research Project

Project/Area Number 26410145
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Analytical chemistry
Research InstitutionChiba University

Principal Investigator

KATSUTA SHOICHI  千葉大学, 大学院理学研究院, 教授 (40277273)

Co-Investigator(Renkei-kenkyūsha) KUDO YOSHIHIRO  千葉大学, 大学院理学研究院, 准教授 (00195463)
BESSHO KOTARO  大学共同利用機関法人高エネルギー加速器研究機構, 放射線科学センター, 准教授 (10300675)
Project Period (FY) 2014-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords溶媒抽出 / イオン液体 / メタロホスト / 白金族金属 / リチウム / マイクロ抽出 / 分離濃縮 / 微量分析 / イオン性薬毒物 / 金属酸化物ナノ粒子 / ロジウム / パラコート / 海水 / 抽出吸光光度分析法 / 分離技術
Outline of Final Research Achievements

(1) Through the detailed investigation of the ionic liquid extraction behavior of platinum group metals (Pd2+, Pt4+, Rh3+) in hydrochloric acid, we have found the ionic liquid having a highly efficient and selective extraction ability toward these metals and the optimum conditions for the extraction.
(2) We have developed a solvent extraction-spectrophotometric determination method for lithium ion using a macrocyclic metallohost compound and successfully applied it to the determination of sub-ppm level lithium in seawater samples.
(3) We have developed an ionic liquid microextraction system enabling ultra-high concentration of toxic organic cations (paraquat and diquat). The trace toxicants in water samples could be sensitively determined with HPLC-UV after separation and concentration (more than 1000-fold) by this method.

Report

(5 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (39 results)

All 2018 2017 2016 2015 2014 Other

All Journal Article (11 results) (of which Peer Reviewed: 10 results,  Open Access: 7 results,  Acknowledgement Compliant: 3 results) Presentation (27 results) (of which Int'l Joint Research: 3 results,  Invited: 3 results) Remarks (1 results)

  • [Journal Article] Extraction of palladium(II) and platinum(IV) from hydrochloric acid solutions with trioctylammonium nitrate ionic liquid without dilution2018

    • Author(s)
      Shoichi Katsuta and Junko Tamura
    • Journal Title

      Journal of Solution Chemistry

      Volume: 印刷中 Issue: 8 Pages: 1293-1308

    • DOI

      10.1007/s10953-018-0745-9

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Application of a Lithium-ion Selective Metallacrown to Extraction–Spectrophotometric Determination of Lithium in Saline Water2018

    • Author(s)
      Shoichi Katsuta, Yuki Saito, and Suguru Takahashi
    • Journal Title

      Analytical Sciences

      Volume: 34 Issue: 2 Pages: 189-193

    • DOI

      10.2116/analsci.34.189

    • NAID

      130006342060

    • ISSN
      0910-6340, 1348-2246
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Adsorption behavior of trace beryllium(II) onto metal oxide nanoparticles dispersed in water2017

    • Author(s)
      Shoichi Katsuta, Naoki Kanaya, Kotaro Bessho, and Hideaki Monjushiro
    • Journal Title

      International Journal of Chemistry

      Volume: 9 Issue: 4 Pages: 62-70

    • DOI

      10.5539/ijc.v9n4p62

    • Related Report
      2017 Annual Research Report
    • Open Access
  • [Journal Article] Solid-phase extraction of lithium in seawater with porous polymer resin impregnated with lithium-ion selective metallohost2017

    • Author(s)
      Shoichi Katsuta and Toshihiro Nakamura
    • Journal Title

      Bulletin of the Society of Sea Water Science, Japan

      Volume: 71 Pages: 298-299

    • NAID

      130007492399

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Extraction of gold(III) from hydrochloric acid into various ionic liquids: relationship between extraction efficiency and aqueous solubility of ionic liquids2016

    • Author(s)
      Shoichi Katsuta, Yuta Watanabe, Yusuke Araki, and Yoshihiro Kudo
    • Journal Title

      ACS Sustainable Chemistry & Engineering

      Volume: 4 Issue: 2 Pages: 564-571

    • DOI

      10.1021/acssuschemeng.5b00976

    • Related Report
      2016 Research-status Report 2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Solvent extraction of cadmium picrate by 18-crown-6 ether into several less-polar diluents and nitrobenzene: re-evaluation of the corresponding overall extraction systems2015

    • Author(s)
      Yoshihiro Kudo, Shoichi Katsuta, Yuuki Ohsawa, and Kohei Nozaki
    • Journal Title

      Journal of Thermodynamics & Catalysis

      Volume: 6 Issue: 02

    • DOI

      10.4172/2157-7544.1000146

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] 2,6-Bis(amido)benzoic acid with internal hydrogen bond as Bronsted acid catalyst for Friedel-Crafts reaction of indoles2015

    • Author(s)
      Katsuhiko Moriyama, Toru Sugiue, Yuki Saito, Shoichi Katsuta, and Hideo Togo
    • Journal Title

      Advanced Synthesis & Catalysis

      Volume: 357 Issue: 9 Pages: 2143-2149

    • DOI

      10.1002/adsc.201401189

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] The laws governing ionic liquid extraction of cations: partition of 1-ethylpyridinium monocation and paraquat dication in ionic liquid/water biphasic systems2015

    • Author(s)
      Takuya Hamamoto, Miho Okai, and Shoichi Katsuta
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 119 Issue: 20 Pages: 6317-6325

    • DOI

      10.1021/acs.jpcb.5b02923

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] On an expression of extraction constants without the interfacial equilibrium-potential differences for the extraction of univalent and divalent metal picrates by crown ethers into 1,2-dichloroethane and nitrobenzene2015

    • Author(s)
      Yoshihiro Kudo and Shoichi Katsuta
    • Journal Title

      American Journal of Analytical Chemistry

      Volume: 6 Issue: 04 Pages: 350-363

    • DOI

      10.4236/ajac.2015.64034

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Extraction Properties of <i>p</i>-Methyloxacalix[3]arene Methyl Ether for Alkali Metal Ions2015

    • Author(s)
      Naoki Kanaya, Shumpei Matsuhashi, and Shoichi Katsuta
    • Journal Title

      Solvent Extraction Research and Development, Japan

      Volume: 22 Issue: 1 Pages: 17-24

    • DOI

      10.15261/serdj.22.17

    • NAID

      130005071505

    • ISSN
      1341-7215, 2188-4765
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Extraction Properties of p-Methyloxacalix[3]arene Methyl Ether for Alkali Metal Ions2015

    • Author(s)
      Naoki Kanaya, Shumpei Matsuhashi, and Shoichi Katsuta
    • Journal Title

      Solvent Extraction Research and Development, Japan

      Volume: 22 Pages: 17-24

    • NAID

      130005071505

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 機能性金属錯体を用いた塩水中微量リチウムイオンの高選択的分離と定量2018

    • Author(s)
      勝田正一
    • Organizer
      日本海水学会分析科学研究会ミニシンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Extraction separation of rhodium(III) from hydrochloric acid solutions with trioctylammonium-based ionic liquids2017

    • Author(s)
      Shoichi Katsuta, Kanshi Kawahara, and Junko Tamura
    • Organizer
      The 21st International Solvent Extraction Conference (ISEC2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] メタロホスト担持樹脂を用いた海水中リチウムイオンの分離と定量2017

    • Author(s)
      中村俊裕,勝田正一
    • Organizer
      日本分析化学会第66年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 種々のイオン液体/水二相系における8-キノリノールとその共役酸・塩基の分配挙動2017

    • Author(s)
      辺 洪明,勝田正一
    • Organizer
      日本分析化学会第66年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 種々のイオン液体によるセシウム及びナトリウムイオンの抽出挙動2017

    • Author(s)
      石橋和樹,勝田正一
    • Organizer
      日本分析化学会第66年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] トリオクチルアンモニウム系イオン液体を用いたパラジウム(II)の高倍率抽出濃縮2017

    • Author(s)
      河原完至,樋口祥多,勝田正一
    • Organizer
      日本分析化学会第66年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] アニオン性薬物のイオン液体抽出における溶媒効果の検討とその応用2017

    • Author(s)
      濵本拓也, 菅澤麻衣, 勝田正一
    • Organizer
      日本分析化学会第66年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] プロトン性イオン液体を用いた塩酸溶液からのロジウム,パラジウム,白金の抽出分離2016

    • Author(s)
      河原完至,勝田正一
    • Organizer
      第35回溶媒抽出討論会
    • Place of Presentation
      産業技術総合研究所つくばセンター(茨城県・つくば市)
    • Year and Date
      2016-11-28
    • Related Report
      2016 Research-status Report
  • [Presentation] イオン液体/水界面への吸着を利用した酸化銅ナノ粒子のマイクロ抽出:銅汚染水中のコロイド種定量分析への応用2016

    • Author(s)
      武田千広,別所光太郎,文珠四郎秀昭,勝田正一
    • Organizer
      第35回溶媒抽出討論会
    • Place of Presentation
      産業技術総合研究所つくばセンター(茨城県・つくば市)
    • Year and Date
      2016-11-28
    • Related Report
      2016 Research-status Report
  • [Presentation] プロトン性イオン液体を用いた抽出不活性ロジウム(Ⅲ)の定量的抽出分離2016

    • Author(s)
      河原完至,田村純子,勝田正一
    • Organizer
      日本分析化学会第65年会
    • Place of Presentation
      北海道大学工学部(北海道・札幌市)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] イオン液体を用いた水中の金属酸化物ナノ粒子の迅速分離・濃縮2016

    • Author(s)
      武田千広,別所光太郎,文珠四郎秀昭,勝田正一
    • Organizer
      日本分析化学会第65年会
    • Place of Presentation
      北海道大学工学部(北海道・札幌市)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 一価無機イオンの水-イオン液体間移行自由エネルギーの評価2016

    • Author(s)
      石橋和樹,湯川裕晴,勝田正一
    • Organizer
      日本分析化学会第65年会
    • Place of Presentation
      北海道大学工学部(北海道・札幌市)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] Optimization of ionic liquids as solvents for extraction of ionic species2016

    • Author(s)
      Shoichi Katsuta
    • Organizer
      Workshop on Soft Molecule Activation
    • Place of Presentation
      千葉大学西千葉キャンパス(千葉県千葉市)
    • Year and Date
      2016-03-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 金属酸化物ナノ粒子のイオン液体/水界面への吸着特性2015

    • Author(s)
      武田千広, 金谷直樹, 別所光太郎, 文珠四郎秀昭, 勝田正一
    • Organizer
      第34回溶媒抽出討論会
    • Place of Presentation
      金沢工業大学扇が丘キャンパス(石川県野々市市)
    • Year and Date
      2015-10-23
    • Related Report
      2015 Research-status Report
  • [Presentation] メタロホストを用いた抽出吸光光度法による海水中のリチウムの定量2015

    • Author(s)
      齋藤祐貴, 高橋 俊, 勝田正一
    • Organizer
      日本分析化学会第64年会
    • Place of Presentation
      九州大学伊都キャンパス(福岡県福岡市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Presentation] イオン液体1-エチル-3-メチルイミダゾリウム・ビス(ノナフルオロブタンスルホニル)アミドによる水中パラコートのマイクロ抽出2015

    • Author(s)
      濵本拓也, 勝田正一
    • Organizer
      日本分析化学会第64年会
    • Place of Presentation
      九州大学伊都キャンパス(福岡県福岡市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Presentation] ジベンゾ-24-クラウン-8-アルカリ金属イオン錯体のイオン液体中における安定性と水/イオン液体間移行自由エネルギー2015

    • Author(s)
      勝田正一, 松橋俊平
    • Organizer
      日本分析化学会第64年会
    • Place of Presentation
      九州大学伊都キャンパス(福岡県福岡市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Presentation] 疎水性イオン液体/水界面への金属酸化物ナノ粒子の吸着挙動2015

    • Author(s)
      武田千広, 金谷直樹, 別所光太郎, 文珠四郎秀昭, 勝田正一
    • Organizer
      日本分析化学会第64年会
    • Place of Presentation
      九州大学伊都キャンパス(福岡県福岡市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Presentation] イソキノリン及びキノリン誘導体を側鎖とするラリアートエーテルの錯形成反応2015

    • Author(s)
      高橋 俊, 奥川直紀, 東郷秀雄, 勝田正一
    • Organizer
      日本分析化学会第64年会
    • Place of Presentation
      九州大学伊都キャンパス(福岡県福岡市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Presentation] Theory and rules for ionic liquid extraction of cations2015

    • Author(s)
      Takuya Hamamoto, Miho Okai, and Shoichi Katsuta
    • Organizer
      6th International Congress on Ionic Liquids (COIL-6)
    • Place of Presentation
      Jeju(South Korea)
    • Year and Date
      2015-06-16
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] プロトン性イオン液体による塩酸溶液からのロジウムの抽出2014

    • Author(s)
      田村純子, 勝田正一
    • Organizer
      第33回溶媒抽出討論会
    • Place of Presentation
      ホテルプラザ神戸
    • Year and Date
      2014-12-11
    • Related Report
      2014 Research-status Report
  • [Presentation] イオン液体/水界面への吸着による水中の酸化銅(II)ナノ粒子の分離除去2014

    • Author(s)
      武田千広, 重永達彦, 金谷直樹, 別所光太郎, 文珠四郎秀昭, 勝田正一
    • Organizer
      第33回溶媒抽出討論会
    • Place of Presentation
      ホテルプラザ神戸
    • Year and Date
      2014-12-11
    • Related Report
      2014 Research-status Report
  • [Presentation] プロトン性イオン液体によるレアメタルの抽出2014

    • Author(s)
      勝田正一
    • Organizer
      レアメタル分析研究懇談会・環境分析研究懇談会合同講演会
    • Place of Presentation
      東京理科大学森戸記念館
    • Year and Date
      2014-11-19
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 1-ブチル-3-メチルイミダゾリウム系疎水性イオン液体と水との間におけるイオン移行自由エネルギーの評価2014

    • Author(s)
      湯川裕晴, 工藤義広, 勝田正一
    • Organizer
      第60回ポーラログラフィーおよび電気分析化学討論会
    • Place of Presentation
      京都工芸繊維大学
    • Year and Date
      2014-11-15
    • Related Report
      2014 Research-status Report
  • [Presentation] 水からイオン液体1-ブチル-3-メチルイミダゾリウム・ヘキサフルオロホスファートへの単独イオンの移行自由エネルギー2014

    • Author(s)
      湯川裕晴, 勝田正一
    • Organizer
      日本分析化学会第63年会
    • Place of Presentation
      広島大学
    • Year and Date
      2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] イオン液体/水二相系におけるイオン性物質の分配を支配する諸因子2014

    • Author(s)
      勝田正一, 濵本拓也, 渡邉悠太, 岡井美歩
    • Organizer
      日本分析化学会第63年会
    • Place of Presentation
      広島大学
    • Year and Date
      2014-09-17
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] イオン液体抽出による水中の酸化銅ナノ粒子の除去2014

    • Author(s)
      武田千広, 重永達彦, 金谷直樹, 別所光太郎, 文珠四郎秀昭, 勝田正一
    • Organizer
      日本分析化学会第63年会
    • Place of Presentation
      広島大学
    • Year and Date
      2014-09-17
    • Related Report
      2014 Research-status Report
  • [Remarks] 千葉大学 大学院理学研究院/融合理工学府化学コース 分析化学研究室ホームページ

    • URL

      http://bunseki-sc-chiba.sakura.ne.jp/index.html

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2019-03-29  

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