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Synthesis of new phenolic polymers with highly regular linear structures

Research Project

Project/Area Number 26620097
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Polymer chemistry
Research InstitutionKanazawa University

Principal Investigator

Ogoshi Tomoki  金沢大学, 物質化学系, 教授 (00447682)

Co-Investigator(Kenkyū-buntansha) YAMAGISHI TADA-AKI  金沢大学, 物質化学系, 教授 (90220251)
Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords直鎖状フェノール性高分子 / オリゴマー / 蛍光発光 / 位置選択的結合切断 / 酸化―還元 / フェノール樹脂 / 構造制御 / 蛍光 / ジグザグ構造 / H会合体 / 直鎖状フェノール樹脂 / ヒドロキノン / ベンゾキノン / 酸化 / キンヒドリン / ガス吸着
Outline of Final Research Achievements

In this study, we successfully synthesized linear phenolic polymers. First, we produced linear phenolic polymers by position selective cleavage of methylene bridges between phenolic units by oxidation. Second, linear phenolic polymers were obtained by designing phenolic monomers to inhibit the formation of three dimensional phenolic polymers. The obtained phenolic polymer network showed very interesting fluorescence property in solid and solution states.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (9 results)

All 2016 2015 2014

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results,  Open Access: 1 results) Presentation (6 results) (of which Invited: 6 results) Book (1 results)

  • [Journal Article] Host-Guest Complexation of Perethylated Pillar[5]arene with Alkanes in the Crystal State2015

    • Author(s)
      Ogoshi, T. Sueto, R. Yoshikoshi K. Sakata, Y. Akine, S. Yamagishi, T.
    • Journal Title

      Angew Chem Int Ed

      Volume: 54 Issue: 34 Pages: 9849-9852

    • DOI

      10.1002/anie.201503489

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Porous Carbon Fibers Containing Angstrom-Level Controlled Pores from Pillar[6]arene Cavity Size by Calcination of Two Dimensional Porous Sheets2015

    • Author(s)
      Ogoshi T.; Yoshikoshi K.; Sueto R.; Nishihara H.; Yamagishi T.
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: in press

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 柱状環状ホスト分子Pillar[n]arene を基盤とした超分子材料の創製2016

    • Author(s)
      生越友樹
    • Organizer
      日本化学会第96春期年会特別企画
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 柱状環状ホスト分子“Pillar[n]arene”超分子集合体を基にしたカーボンポーラス材料の創製2015

    • Author(s)
      生越友樹
    • Organizer
      第42回炭素材料学会年会 次世代の会
    • Place of Presentation
      関西大学千里山キャンパス
    • Year and Date
      2015-12-04
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] フェノール性環状ホスト分子・高分子を基にしたイオン性超分子マテリアルの創製2015

    • Author(s)
      生越友樹
    • Organizer
      第188回溶融塩委員会
    • Place of Presentation
      名古屋大学東山キャンパス(名古屋市千種区)
    • Year and Date
      2015-11-23
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Supramolecular Assembly Based on Facile and Versatile Macrocycles Pillararenes2014

    • Author(s)
      Ogoshi, T.
    • Organizer
      International Polymer Conference 2014
    • Place of Presentation
      Epochal Tsukuba, Tsukuba, Japan
    • Year and Date
      2014-12-04
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Pillar[n]arenes: Easy-to-Make and Versatile Receptors for Supramolecular Chemistry2014

    • Author(s)
      Ogoshi, T.
    • Organizer
      IUMRS-ICA2014
    • Place of Presentation
      Fukuoka University, Fukuoka, Japan
    • Year and Date
      2014-08-25
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Pillararenes: Easy-to-Make and Versatile Receptors for Supramolecular Chemistry2014

    • Author(s)
      Ogoshi, T.
    • Organizer
      2014 International Symposium on Frontiers of Molecular Recognition and Function
    • Place of Presentation
      Chinese Academy of Science, Beijing, China
    • Year and Date
      2014-06-06
    • Related Report
      2014 Research-status Report
    • Invited
  • [Book] Pillararenes2016

    • Author(s)
      Ogoshi, T.
    • Total Pages
      320
    • Publisher
      Royal Society of Chemistry
    • Related Report
      2015 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2017-05-10  

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