Project/Area Number |
26620097
|
Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
Allocation Type | Multi-year Fund |
Research Field |
Polymer chemistry
|
Research Institution | Kanazawa University |
Principal Investigator |
Ogoshi Tomoki 金沢大学, 物質化学系, 教授 (00447682)
|
Co-Investigator(Kenkyū-buntansha) |
YAMAGISHI TADA-AKI 金沢大学, 物質化学系, 教授 (90220251)
|
Project Period (FY) |
2014-04-01 – 2016-03-31
|
Project Status |
Completed (Fiscal Year 2015)
|
Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
|
Keywords | 直鎖状フェノール性高分子 / オリゴマー / 蛍光発光 / 位置選択的結合切断 / 酸化―還元 / フェノール樹脂 / 構造制御 / 蛍光 / ジグザグ構造 / H会合体 / 直鎖状フェノール樹脂 / ヒドロキノン / ベンゾキノン / 酸化 / キンヒドリン / ガス吸着 |
Outline of Final Research Achievements |
In this study, we successfully synthesized linear phenolic polymers. First, we produced linear phenolic polymers by position selective cleavage of methylene bridges between phenolic units by oxidation. Second, linear phenolic polymers were obtained by designing phenolic monomers to inhibit the formation of three dimensional phenolic polymers. The obtained phenolic polymer network showed very interesting fluorescence property in solid and solution states.
|