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Synthesis of conjugated materials by catalytic C-H coupling of biomass-derived compounds

Research Project

Project/Area Number 26620146
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Green/Environmental chemistry
Research InstitutionKobe University

Principal Investigator

Mori Atsunori  神戸大学, 工学(系)研究科(研究院), 教授 (90210111)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsバイオマス / フルフラール / 有機機能材料 / フラン環 / チアゾール / オキサゾール / 共役系拡張 / C-Hカップリング / グルコース / システイン / セリン / カップリング反応
Outline of Final Research Achievements

Synthesis of organic materials with extended conjugation is carried out with furfural, which is derived from biomass-derived glucose.The formyl group of furfural is transformed into several heteroaromatic structures, which induces functionalization at the 3 and 5-positions of the furan ring affording pai-conjugation-extended compounds through carbon-carbon, carbon-heteroatom, and carbon-metal bonds.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (7 results)

All 2016 2015 2014

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 2 results) Presentation (3 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Synthesis of Furan-Oxazole Conjugated Fluorescent Materials from Biomass-Derived Furfural through Cross-Coupling Reactions2016

    • Author(s)
      Y. Murase, K. Ashida, S. Tanaka, K. Okano, A. Mori
    • Journal Title

      Heterocycles

      Volume: 93 Issue: 1 Pages: 140-140

    • DOI

      10.3987/com-15-s(t)9

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preparation of Fluorescent Materials from Biomass-Derived Furfural and Natural Amino Acid Cysteine through Cross-Coupling Reactions for Extended π-Conjugation2015

    • Author(s)
      Shota Tanaka, Kana Ashida, Go Tatsuta, Atsunori Mori
    • Journal Title

      Synlett

      Volume: 印刷中 Issue: 11 Pages: 1946-1950

    • DOI

      10.1055/s-0034-1380460

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis and properties of regioregular poly (3-substituted thiophene) bearing disiloxane moiety in the substituent. Remarkably high solubility in hexane.2014

    • Author(s)
      Atsunori Mori, Kenji Ide, Shunsuke Tamba, Satoru Tsuji, Yuka Toyomori, Takeshi Yasuda.
    • Journal Title

      Chemistry Letters

      Volume: 43 Issue: 5 Pages: 640-642

    • DOI

      10.1246/cl.131222

    • NAID

      130004868129

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Heterobiaryl as winding-vine shaped molecular asymmetry2016

    • Author(s)
      Atsunori Mori, Y. Okayama, Y. Toyomori, K. Maruhashi, D. Matsuoka
    • Organizer
      251st American Chemical Society National Meeting, San Diego
    • Place of Presentation
      San Diego (USA)
    • Year and Date
      2016-03-12
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] バイオマス由来のフルフラールとアミノ酸を原料に用いるπ共役系有機材料の合成2014

    • Author(s)
      蘆田佳奈・田中将太・立田 豪・森 敦紀
    • Organizer
      第61回有機金属化学討論会
    • Place of Presentation
      九州大学
    • Year and Date
      2014-09-23 – 2014-09-25
    • Related Report
      2014 Research-status Report
  • [Presentation] 有機金属錯体触媒化学の最新技術-効率的材料合成をめざして2014

    • Author(s)
      森 敦紀
    • Organizer
      有機合成化学協会中国四国支部 第70回パネル討論会
    • Place of Presentation
      広島大学
    • Year and Date
      2014-05-17
    • Related Report
      2014 Research-status Report
    • Invited
  • [Patent(Industrial Property Rights)] フリルチアゾール化合物2014

    • Inventor(s)
      森 敦紀
    • Industrial Property Rights Holder
      神戸大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-171695
    • Filing Date
      2014-08-26
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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