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Development of novel organic light-emitting diodes displaying circularly polarized luminescence

Research Project

Project/Area Number 26620168
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Organic and hybrid materials
Research InstitutionKyushu University

Principal Investigator

Yasuda Takuma  九州大学, 稲盛フロンティア研究センター, 教授 (00401175)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2014: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords発光ダイオード / 有機半導体 / 偏光 / フルカラー / 不斉空間
Outline of Final Research Achievements

To maximize the efficiency of organic light-emitting diodes (OLEDs), a promising mechanism for electroluminescence, thermally activated delayed fluorescence (TADF), has recently been established. In this study, donor-acceptor-structured luminescent molecules were developed and investigated as new TADF emitters. This set of materials allows systematic fine tuning of the band gap and exhibits efficient TADF emissions that cover the entire visible range from blue to red. On this basis, new circularly polarized luminescent materials having axial chirality have also been developed. OLEDs with high maximum external electroluminescence quantum efficiencies of up to 20% have been demonstrated by using these new emitters.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (32 results)

All 2016 2015 2014

All Journal Article (14 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 14 results,  Open Access: 3 results,  Acknowledgement Compliant: 7 results) Presentation (18 results) (of which Int'l Joint Research: 6 results,  Invited: 9 results)

  • [Journal Article] A Phenoxaborin-Based High-Efficiency Blue Delayed Fluorescence Material2016

    • Author(s)
      In Seob Park, Masaki Numata, Chihaya Adachi, and Takuma Yasuda
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 89 Issue: 3 Pages: 375-377

    • DOI

      10.1246/bcsj.20150399

    • NAID

      130005137567

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Full-Color Delayed Fluorescence Materials Based on Wedge-Shaped Phthalonitriles and Dicyanopyrazines: Systematic Design, Tunable Photophysical Properties, and OLED Performance2016

    • Author(s)
      In Seob Park, Sae Youn Lee, Chihaya Adachi, and Takuma Yasuda
    • Journal Title

      Advanced Functional Materials

      Volume: 26 Issue: 11 Pages: 1813-1821

    • DOI

      10.1002/adfm.201505106

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Thermally Activated Delayed Fluorescence Polymers for Efficient Solution-Processed Organic Light-Emitting Diodes2016

    • Author(s)
      Sae Youn Lee, Takuma Yasuda, Hideaki Komiyama, Jiyoung Lee, and Chihaya Adachi
    • Journal Title

      Advanced Materials

      Volume: 28 Issue: 21 Pages: 4019-4024

    • DOI

      10.1002/adma.201505026

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] High-Efficiency Blue Organic Light-Emitting Diodes Based on Thermally Activated Delayed Fluorescence from Phenoxaphosphine and Phenoxathiin Derivatives2016

    • Author(s)
      Sae Youn Lee, Chihaya Adachi, and Takuma Yasuda
    • Journal Title

      Advanced Materials

      Volume: 28 Issue: 23 Pages: 4626-4631

    • DOI

      10.1002/adma.201506391

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Aggregation-Induced Delayed Fluorescence Based on Donor/Acceptor-Tethered Janus Carborane Triads: Unique Photophysical Properties for Non-Doped OLEDs2016

    • Author(s)
      Ryuhei Furue, Takuro Nishimoto, In Seob Park, Jiyoung Lee, and Takuma Yasuda
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 55 Issue: 25 Pages: 7171-7175

    • DOI

      10.1002/anie.201603232

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Nearly 100% Internal Quantum Efficiency in Undoped Electroluminescent Devices Employing Pure Organic Emitters2015

    • Author(s)
      Qisheng Zhang, Daniel Tsang, Hirokazu Kuwabara, Yasuhiro Hatae, Bo Li, Takehiro Takahashi, Sae Youn Lee, Takuma Yasuda, and Chihaya Adachi
    • Journal Title

      Advanced Materials

      Volume: 27 Issue: 12 Pages: 2096-2100

    • DOI

      10.1002/adma.201405474

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High Efficiency Pure Blue Thermally Activated Delayed Fluorescence Molecules Having 10H-Phenoxaborin and Acridan Units2015

    • Author(s)
      Masaki Numata, Takuma Yasuda, and Chihaya Adachi
    • Journal Title

      Chemical Communications

      Volume: 51 Issue: 46 Pages: 9443-9446

    • DOI

      10.1039/c5cc00307e

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organic Light-Emitting Diodes Based on Donor-Substituted Phthalimide and Maleimide Fluorophores2015

    • Author(s)
      Myung Eun Jang, Takuma Yasuda, Jiyoung Lee, Sae Youn Lee, and Chihaya Adachi
    • Journal Title

      Chemistry Letters

      Volume: 44 Issue: 9 Pages: 1248-1250

    • DOI

      10.1246/cl.150454

    • NAID

      130005096886

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] X-Shaped Benzoylbenzophenone Derivatives with Crossed Donors and Acceptors for Highly Efficient Thermally Activated Delayed Fluorescence2015

    • Author(s)
      Sae Youn Lee, Takuma Yasuda,* and Chihaya Adachi*
    • Journal Title

      Daiton Transactions

      Volume: 2015 Issue: 18 Pages: 8356-8359

    • DOI

      10.1039/c4dt03608e

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Donor–Acceptor Structured 1,4-Diazatriphenylene Derivatives Exhibiting Thermally Activated Delayed Fluorescence: Design and Synthesis, Photophysical Properties and OLED Characteristics2014

    • Author(s)
      Takehiro Takahashi, Katsuyuki Shizu, Takuma Yasuda,* Kazunori Togashi, and Chihaya Adachi*
    • Journal Title

      Science and Technology of Advanced Materials

      Volume: 15 Issue: 3 Pages: 034202-034202

    • DOI

      10.1088/1468-6996/15/3/034202

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Thermally Activated Delayed Fluorescence from a Spiro-Diazafluorene Derivative2014

    • Author(s)
      Hiroshi Ohkuma, Tetsuya Nakagawa, Katsuyuki Shizu, Takuma Yasuda,* and Chihaya Adachi*
    • Journal Title

      Chemistry Letters

      Volume: 43 Issue: 7 Pages: 1017-1019

    • DOI

      10.1246/cl.140360

    • NAID

      130004868224

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Efficiency Enhancement of Organic Light-Emitting Diodes Incorporating a Highly Oriented Thermally Activated Delayed Fluorescence Emitter2014

    • Author(s)
      Christian Mayr, Sae Youn Lee, Tobias D Shmidt, Takuma Yasuda, Chihaya Adachi, and Wolfgang Brütting
    • Journal Title

      Advanced Functional Materials

      Volume: 24 Issue: 33 Pages: 5232-5239

    • DOI

      10.1002/adfm.201400495

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Luminous Butterflies: Efficient Exciton Harvesting by Benzophenone Derivatives for Full-Color Delayed Fluorescence OLEDs2014

    • Author(s)
      Sae Youn Lee, Takuma Yasuda,* Yu Seok Yang, Qisheng Zhang, and Chihaya Adachi*
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 53 Issue: 25 Pages: 6520-6524

    • DOI

      10.1002/ange.201402992

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 高効率熱活性化遅延蛍光材料の開発と有機ELへの展開2014

    • Author(s)
      安田 琢麿・李 世淵・安達 千波矢
    • Journal Title

      科学と工業

      Volume: 88 Pages: 363-367

    • NAID

      40020233820

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] スチルベン骨格を有する新規有機半導体の合成と光学特性および有機EL特性2016

    • Author(s)
      諌山 康平・相澤 直矢・安田 琢麿
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] ドナー・アクセプター型熱活性化遅延蛍光分子の濃度消光機構の解明2016

    • Author(s)
      相澤 直矢・イ ジヨン・安田 琢麿
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] ホウ素クラスター骨格を有する有機半導体分子の特異な発光特性2016

    • Author(s)
      古江 龍侑平・パク インソプ・李 ジヨン・相澤 直矢・安田 琢麿
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 有機光電変換を利用したアップコンバージョン発光デバイスの開発2016

    • Author(s)
      橘 弘樹・日高 優・相澤 直矢・安田 琢麿
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Luminescent fusion materials for optoelectronic devices2015

    • Author(s)
      Takuma Yasuda
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2015-12-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Design of full-color thermally activated delayed fluorescence emitters based on benzonitrile derivatives and their application in organic light-emitting diodes2015

    • Author(s)
      In Seob Park, Takuma Yasuda, Sae Youn Lee, and Chihaya Adachi
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2015-12-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of efficient blue thermally activated delayed fluorescence emitters and clarification of concentration quenching mechanism2015

    • Author(s)
      Jiyoung Lee, Masaki Numata, Woong Shin, Yu Seok Yang, Chihaya Adachi, and Takuma Yasuda
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2015-12-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Self-Organizing Organic Semiconductors for Electronics Devices2015

    • Author(s)
      Takuma Yasuda
    • Organizer
      Japan-Korea Joint Symposium 2015
    • Place of Presentation
      Fukuoka
    • Year and Date
      2015-10-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 有機半導体の精密分子設計・制御が拓く有機光エレクトロニクス2015

    • Author(s)
      安田 琢麿
    • Organizer
      平成27年度第3回光エネルギーセミナー
    • Place of Presentation
      近畿大学
    • Year and Date
      2015-07-25
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Highly Efficient Thermally Activated Delayed Fluorescence Emitters Based on Benzonitrile Derivatives and Their Application in OLEDs2015

    • Author(s)
      In Seob Park, Takuma Yasuda, Sae Youn Lee, and Chihaya Adachi
    • Organizer
      16th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Madrid, Spain
    • Year and Date
      2015-07-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of Thermally Activated Delayed Fluorescence Emitters and Clarification of Concentration Quenching Mechanism2015

    • Author(s)
      Jiyoung Lee, Takuma Yasuda, Masaki Numata, Woong Shin, Yu Seok Yang, and Chihaya Adachi
    • Organizer
      16th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Madrid, Spain
    • Year and Date
      2015-07-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機半導体分子集積を基軸とした有機エレクトロニクスデバイスデバイスの開拓2015

    • Author(s)
      安田 琢麿
    • Organizer
      日本学術振興会「先端ナノデバイス・材料テクノロジー第151委員会」平成27年度第1回研究会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2015-07-03
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] A New Paradigm in Design for High Efficiency Organic Light-Emitting Materials and Devices2014

    • Author(s)
      Takuma Yasuda
    • Organizer
      11th International Conference on Nano-Molecular Electronics
    • Place of Presentation
      Kobe
    • Year and Date
      2014-12-17 – 2014-12-19
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 有機エレクトロニクス材料技術の最前線2014

    • Author(s)
      安田 琢麿
    • Organizer
      第3回 環境・エネルギー・資源シンポジウム
    • Place of Presentation
      宮崎
    • Year and Date
      2014-10-31
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 有機半導体分子集積を基軸とした電荷輸送・光電変換材料の開発2014

    • Author(s)
      安田 琢麿
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学
    • Year and Date
      2014-09-25
    • Related Report
      2014 Research-status Report
  • [Presentation] TADF材料技術の最先端2014

    • Author(s)
      安田 琢麿
    • Organizer
      有機エレクトロニクス材料研究会ワークショップ
    • Place of Presentation
      秋葉原UDXカンファレンスホール
    • Year and Date
      2014-07-11
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] A New Paradigm in Design for High Efficiency Organic Light-Emitting Materials and Devices2014

    • Author(s)
      Takuma Yasuda
    • Organizer
      NIMS Conference 2014: A Strong Future from Soft Materials
    • Place of Presentation
      Tsukuba International Congress Center, Ibaraki
    • Year and Date
      2014-07-02
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] A New Paradigm in Materials Design for High Efficiency OLEDs2014

    • Author(s)
      Takuma Yasuda
    • Organizer
      The 5th International Conference on White LEDs and Solid State Lighting
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2014-06-03
    • Related Report
      2014 Research-status Report
    • Invited

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Published: 2014-04-04   Modified: 2017-05-10  

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