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Synthesis and Anion Recognition Behavior of Conjugated Polymers by Direct Arylation Polycondensation

Research Project

Project/Area Number 26620173
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Polymer/Textile materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

Michinobu Tsuyoshi  東京工業大学, 理工学研究科, 准教授 (80421410)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords高分子合成 / 有機導体 / 環境材料
Outline of Final Research Achievements

1,8-Carbazole-based conjugated polymers were synthesized by environmentally-friendly polymerization methods. When direct arylation polycondensation was applied, the desired polymers could not be obtained due to the steric reason. In contrast, poly(1,8-carbazole)s could be produced by the azide-alkyne click polymerization. The resulting poly(1,8-carbazole)s showed the specific fluorescence changes in response to the cyanate anion and tin cation.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (9 results)

All 2016 2015 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 4 results) Presentation (4 results) Remarks (1 results)

  • [Journal Article] Troger’s Base-Containing Aromatic Polymers with Unexpected Properties Endowed by the Insertion of Alkyne Spacers2016

    • Author(s)
      W. Li, T. Michinobu
    • Journal Title

      Macromol. Chem. Phys.

      Volume: 217 Issue: 7 Pages: 863-870

    • DOI

      10.1002/macp.201500494

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Novel Design of Carbazole-Basesd Donor-Acceptor Molecules for Fullerene-Free Organic Photovoltaic Devices2016

    • Author(s)
      T. Michinobu, N. Yamada, Y. Washino, K. Nakayama
    • Journal Title

      J. Nanosci. Nanotechnol.

      Volume: 16

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Structural Effects of Dibromocarbazoles on Direct Arylation Polycondensation with 3,4-Ethylenedioxythiophene2016

    • Author(s)
      W. Li, T. Michinobu
    • Journal Title

      Polym. Chem.

      Volume: 7 Issue: 18 Pages: 3165-3171

    • DOI

      10.1039/c6py00381h

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] New Semiconducting Polymers Based on Benzobisthiadiazole Analogues: Tuning of Charge Polarity in Thin Film Transistors via Heteroatom Substitution2015

    • Author(s)
      Y. Wang, H. Masunaga, T. Hikima, H. Matsumoto, T. Mori, T. Michinobu
    • Journal Title

      Macromolecules

      Volume: 48 Issue: 12 Pages: 4012-4023

    • DOI

      10.1021/acs.macromol.5b00802

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Direct Arylation Synthesis of Carbazole-Based Conjugated Polymers and Their Applications to Electrochromic Materials2016

    • Author(s)
      W. Li, T. Michinobu
    • Organizer
      第65回高分子年次大会
    • Place of Presentation
      神戸国際会議場・展示場
    • Year and Date
      2016-05-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 1,8-位連結カルバゾールを主鎖に含む高分子のクリック合成と金属イオン認識能の評価2015

    • Author(s)
      多根 静香、道信 剛志
    • Organizer
      繊維学会関東支部平成27年度学生論文発表会
    • Place of Presentation
      東京農工大学
    • Year and Date
      2015-12-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 1,8-位連結カルバゾールを主鎖に含む高分子のクリック合成と金属イオン認識能の評価2015

    • Author(s)
      多根 静香、道信 剛志
    • Organizer
      平成27年度繊維学会秋季研究発表会
    • Place of Presentation
      京都工芸繊維大学
    • Year and Date
      2015-10-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] 1,8-ジエチニルカルバゾール誘導体のクリック重合とイオンセンサーへの応用2015

    • Author(s)
      多根 静香、道信 剛志
    • Organizer
      平成27年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2015-06-10
    • Related Report
      2015 Annual Research Report 2014 Research-status Report
  • [Remarks] 東京工業大学 道信研究室

    • URL

      http://www.op.titech.ac.jp/lab/michinobu/jp/index.html

    • Related Report
      2015 Annual Research Report 2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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