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Fabrication of amorphous carbon nano-particles using plasma CVD methods and its application for photocatalyst and artificial retina

Research Project

Project/Area Number 26630350
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Structural/Functional materials
Research InstitutionYamaguchi University

Principal Investigator

Honda Kensuke  山口大学, 理工学研究科, 教授 (60334314)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsアモルファスカーボン / 半導体材料 / ナノ粒子 / 光電変換機能
Outline of Final Research Achievements

The objective of this study is to establish the plasma CVD method to control the size and optical gaps of Si-added a-C semiconductor nano-particles whose optical gaps can be selected by changing Si atom% incorporated in Si-added a-C.
When porous aluminum plate was inserted in plasma during plasma CVD synthesis of Si-added a-C, high-power area were formed in pores of aluminum plate and Si-added a-C nanoparticles were obtained. The diameter of Si-added a-C nanoparticles was be able to be controlled from 212 nm to 15 nm by changing the position of aluminum plate in plasma, total pressure of reaction chamber and thickness of aluminum plate during plasma CVD synthesis. The optical gaps of Si-added a-C nanoparticles was be able to be regulated in the range from 2.1 eV to 2.7 eV.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (10 results)

All 2016 2015 2014

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results) Presentation (7 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Dioxomolybdenum(VI) and Dioxotungsten(VI) Complexes: Efficient Catalytic Activity for Crosslinking Reaction in Ethylene-Vinyl Acetate Copolymer / Alkoxysilane Composites2015

    • Author(s)
      K. Adachi, S. Toyomura, Y. Miyakuni, S. Yamazaki, K. Honda, T. Hirano
    • Journal Title

      Polym. Adv. Technol.

      Volume: 26 Issue: 6 Pages: 597-605

    • DOI

      10.1002/pat.3491

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Control of electric conductivity and electrochemical activity of hydrogenated amorphous carbon by incorporating boron atoms2014

    • Author(s)
      Kensuke Honda, Hiroshi Naragino, and Yohsuke Shimai
    • Journal Title

      J. Electrochem. Soc.

      Volume: 161 Issue: 10 Pages: B207-B215

    • DOI

      10.1149/2.0261410jes

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] a-C半導体粒子を用いた可視光応答型の水素生成光触媒の創製2016

    • Author(s)
      岡藤 圭吾・小林 龍太朗・永田 祥弥・本多 謙介
    • Organizer
      日本化学会第96春季年会 2016年
    • Place of Presentation
      京都府京田辺市 同志社大学京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Fabrication of a-C semiconductor nanoparticles and controlling of the size and semiconductor properties using high-density plasma in localized are2016

    • Author(s)
      Ryutaro Kobayashi, Yoshiya Nagata, Kensuke Honda
    • Organizer
      ISPlasma2016/IC-PLANTS2016
    • Place of Presentation
      Nagoya University, Nagoya, Aichi
    • Year and Date
      2016-03-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Amorphous Carbon Semiconductor Capable of Controlling Its Optical Gap and Conductivity by Incorporating Two Types of Foreign Atoms2015

    • Author(s)
      Kensuke Honda, Yoshiya Nagata, Masahiro Yamada, Yohsuke Shimai
    • Organizer
      ISPlasma2015/IC-PLANTS2015
    • Place of Presentation
      Nagoya University, Nagoya,Japan
    • Year and Date
      2015-03-30
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] ホローカソードプラズマによるa-C半導体ナノ粒子のサイズ及び光学ギャップ制御2015

    • Author(s)
      本多謙介・永田祥弥・小林龍太朗
    • Organizer
      日本化学会第95春季年会 2015年
    • Place of Presentation
      日本大学 千葉県船橋市
    • Year and Date
      2015-03-27
    • Related Report
      2014 Research-status Report
  • [Presentation] 外部電場により疎水性から両親媒性にスイッチング可能なナノ構造材料の創製2015

    • Author(s)
      花村遼・正入木佑輔・兼安志朗・本多謙介
    • Organizer
      日本化学会第95春季年会 2015年
    • Place of Presentation
      日本大学 千葉県船橋市
    • Year and Date
      2015-03-27
    • Related Report
      2014 Research-status Report
  • [Presentation] 量子ドット合成のための超微細細孔を持つ自己規則化プロセスによるポーラスアルミナ高規則媒体の開発2015

    • Author(s)
      正入木佑輔・花村遼・兼安志朗・本多謙介
    • Organizer
      日本化学会第95春季年会 2015年
    • Place of Presentation
      日本大学 千葉県船橋市
    • Year and Date
      2015-03-26
    • Related Report
      2014 Research-status Report
  • [Presentation] Fabrication of B-doped DLC based interdigitated array microelectrodes and high sensitive detection of redox analytes with higher standard potential than H2O/O22014

    • Author(s)
      Kensuke Honda, Ryohei Kawajiri, Yohsuke Shimai
    • Organizer
      68.65th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Lausanne, Switzerland
    • Year and Date
      2014-09-03
    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] アモルファスカーボンナノ粒子の製造方法及びアモルファスカーボンナノ粒子2015

    • Inventor(s)
      本多 謙介
    • Industrial Property Rights Holder
      国立大学法人 山口大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-045860
    • Filing Date
      2015-03-09
    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2017-05-10  

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