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Catalyst Development by Synergistic Effects of Complex Metal Oxide Clusters

Research Project

Project/Area Number 26708009
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Functional solid state chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

SUZUKI Kosuke  東京大学, 工学(系)研究科(研究院), 助教 (40595667)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥19,890,000 (Direct Cost: ¥15,300,000、Indirect Cost: ¥4,590,000)
Fiscal Year 2016: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2015: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2014: ¥11,180,000 (Direct Cost: ¥8,600,000、Indirect Cost: ¥2,580,000)
Keywords触媒 / ポリオキソメタレート / 金属多核構造 / 光触媒 / ナノ材料 / 構造・機能材料 / 超分子化学
Outline of Final Research Achievements

The visible-light-responsive molecular catalysts were successfully developed by utilizing synergistic effects of molecular metal oxide clusters with multinuclear metal cores or organic molecules. These catalysts showed the intramolecular charge transfer properties by irradiation with visible light. In addition, they showed selective, efficient photocatalysis for the oxidation reactions of amines and sulfides using molecular oxygen as the oxidant as well as the reductive deoxygenation reactions of sulfoxides and pyridine N-oxides using alcohols as the reducing agents.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (39 results)

All 2017 2016 2015 2014

All Journal Article (13 results) (of which Peer Reviewed: 13 results,  Acknowledgement Compliant: 10 results) Presentation (26 results) (of which Int'l Joint Research: 6 results,  Invited: 2 results)

  • [Journal Article] Phosphovanadomolybdic acid catalyzed direct C-H trifluoromethylation of (hetero)arenes using NaSO2CF3 as the CF3 source and O2 as the terminal oxidant2017

    • Author(s)
      Li, C.; Suzuki, K.; Yamaguchi, K.; Mizuno, N.
    • Journal Title

      New J. Chem.

      Volume: 41 Issue: 4 Pages: 1417-1420

    • DOI

      10.1039/c6nj03654f

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis and Disassembly/Reassembly of Giant Ring-Shaped Polyoxotungstate Oligomers2016

    • Author(s)
      Takuo Minato, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka Mizuno
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 55 Issue: 33 Pages: 9630-9633

    • DOI

      10.1002/anie.201604094

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hexanuclear Tin(II) and Mixed Valence Tin(II,IV) Oxide Clusters within Polyoxometalates2016

    • Author(s)
      Kosuke Suzuki, Takumi Hanaya, Rinta Sato, Takuo Minato, Kazuya Yamaguchi, Noritaka Mizuno
    • Journal Title

      Chemical Communication

      Volume: 52 Issue: 70 Pages: 10688-10691

    • DOI

      10.1039/c6cc05284c

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Deoxygenation of Pyridine N-Oxides through Photoredox Catalysis of a Dilacunary Silicotungstate2016

    • Author(s)
      J. Jeong, K. Suzuki, M. Hibino, K. Yamaguchi, N. Mizuno
    • Journal Title

      ChemistrySelect

      Volume: 1 Issue: 15 Pages: 5042-5048

    • DOI

      10.1002/slct.201601146

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photoredox catalysis for oxygenation/deoxygenation between sulfides and sulfoxides by visible-light-responsive polyoxometalates2016

    • Author(s)
      K. Suzuki, J. Jeong, K. Yamaguchi, N. Mizuno
    • Journal Title

      New J. Chem.

      Volume: 40 Issue: 2 Pages: 1014-1021

    • DOI

      10.1039/c5nj01045d

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Sequential Synthesis of 3d-3d’-4f Heterometallic Heptanuclear Clusters in between Lacunary Polyoxometalates2016

    • Author(s)
      R. Sato, K. Suzuki, T. Minato, K. Yamaguchi, N. Mizuno
    • Journal Title

      Inorg. Chem.

      Volume: 55 Issue: 5 Pages: 2023-2029

    • DOI

      10.1021/acs.inorgchem.5b02358

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Water- and Temperature-Triggered Reversible Structural Transformation of Tetranuclear Cobalt(II) Cores Sandwiched by Polyoxometalates2016

    • Author(s)
      Yosuke Kuriyama, Yuji Kikukawa, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka Mizuno
    • Journal Title

      Chemistry A European Journal

      Volume: 22 Issue: 12 Pages: 3962-3966

    • DOI

      10.1002/chem.201600139

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Cascade Approach to Hetero-Pentanuclear Manganese-Oxide Clusters in Polyoxometalates and Their Single-Molecule Magnet Properties2015

    • Author(s)
      Kosuke Suzuki, Rinta Sato, Takuo Minato, Masahiro Shinoe, Kazuya Yamaguchi, Noritaka Mizuno
    • Journal Title

      Dalton Transaction

      Volume: 44 Issue: 32 Pages: 14220-14226

    • DOI

      10.1039/c5dt01363a

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Visible-Light-Responsive Multielectron Redox Catalysis of Lacunary Polyoxometalates Induced by Substrate Coordination to Their Lacuna2015

    • Author(s)
      K. Suzuki, J. Jeong, K. Yamaguchi, N. Mizuno
    • Journal Title

      Chem. Asian J.

      Volume: 10 Issue: 1 Pages: 144-148

    • DOI

      10.1002/asia.201403072

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Field-Induced Slow Magnetic Relaxation of Octahedrally Coordinated Mononuclear Fe(III)-, Co(II)-, and Mn(III)-Containing Polyoxometalates2015

    • Author(s)
      R. Sato, K. Suzuki, T. Minato, M. Shinoe, K. Yamaguchi, N. Mizuno
    • Journal Title

      Chem. Commun.

      Volume: 51 Issue: 19 Pages: 4081-4084

    • DOI

      10.1039/c4cc09435b

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Visible-Light-Induced Photoredox Catalysis with a Tetracerium-Containing Silicotungstate2014

    • Author(s)
      K. Suzuki, F. Tang, Y. Kikukawa, K. Yamaguchi, N. Mizuno
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 53 Issue: 21 Pages: 5356-5360

    • DOI

      10.1002/anie.201403215

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of α-Dawson-Type Silicotungstate [Si2W18O62]8- and Protonation and Deprotonation Inside the Aperture via Intramolecular Hydrogen Bonds2014

    • Author(s)
      T. Minato, K. Suzuki, K. Kamata, N. Mizuno
    • Journal Title

      Chem. Eur. J.

      Volume: 20 Issue: 20 Pages: 5946-5952

    • DOI

      10.1002/chem.201400390

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hydrogen Evolution Using the Visible-Light-Induced Metal-to-Polyoxometalate Multiple Electron Transfer2014

    • Author(s)
      K. Suzuki, F. Tang, Y. Kikukawa, K. Yamaguchi, N. Mizuno
    • Journal Title

      Chem. Lett.

      Volume: 43 Issue: 9 Pages: 1429-1431

    • DOI

      10.1246/cl.140450

    • NAID

      130004427164

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Phosphovanadomolybdic Acid Catalyzed Trifluoromethylation of Arenes2017

    • Author(s)
      Chifeng Li, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka Mizuno
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応義塾大学(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Sequential Synthesis of Heterometallic Nonanuclear Clusters by Utilizing Lacunary Polyoxometalates2017

    • Author(s)
      Takuo Minato, Yusuke Ohata, Rinta Sato, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka Mizuno
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応義塾大学(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 二欠損型シリコタングステート可視光応答型光触媒によるピリジンN-オキシドの選択的脱酸素反応2017

    • Author(s)
      鄭進宇,鈴木康介,山口和也,水野哲孝
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応義塾大学(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] p-ブロック元素を導入したシリコタングステートの合成と特性2017

    • Author(s)
      鈴木康介,花屋巧,佐藤林太,山口和也,水野哲孝
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応義塾大学(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 金属多核構造を導入したリング状ホスホタングステートの合成2016

    • Author(s)
      米里健太郎,鈴木康介,山口和也,水野哲孝
    • Organizer
      第6回CSJ化学フェスタ2016
    • Place of Presentation
      タワーホール船堀(東京都・江戸川区)
    • Year and Date
      2016-11-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 欠損型ポリオキソメタレートを用いた混合原子価スズ酸化物クラスターの合成と光触媒特性2016

    • Author(s)
      花屋巧,鈴木康介,佐藤林太,湊拓生,山口和也,水野哲孝
    • Organizer
      第6回CSJ化学フェスタ2016
    • Place of Presentation
      タワーホール船堀(東京都・江戸川区)
    • Year and Date
      2016-11-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Aerobic Oxidative Trifluoromethylation of Aromatic Compounds Catalyzed by Vanadium-Containing Phosphomolybdic Acids2016

    • Author(s)
      李赤峰,鈴木康介,山口和也,水野哲孝
    • Organizer
      第6回CSJ化学フェスタ2016
    • Place of Presentation
      タワーホール船堀(東京都・江戸川区)
    • Year and Date
      2016-11-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 可視光応答型シリコタングステートを用いた有機硫黄化合物の選択的光酸化還元反応2016

    • Author(s)
      鈴木康介,鄭進宇,山口和也,水野哲孝
    • Organizer
      第118回触媒討論会
    • Place of Presentation
      岩手大学(岩手県・盛岡市)
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Syntheses and Single-Molecule Magnet Properties of Hetero-Multinuclear Manganese-Oxide Clusters Possessing Large Spin Ground State2016

    • Author(s)
      Takuo Minato, Yusuke Ohata, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka Mizuno
    • Organizer
      錯体化学会第66回討論会
    • Place of Presentation
      福岡大学(福岡県・博多市)
    • Year and Date
      2016-09-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] 混合原子価スズ酸化物を有するポリオキソメタレートの合成と光触媒特性2016

    • Author(s)
      花屋巧,鈴木康介,佐藤林太,湊拓生,山口和也,水野哲孝
    • Organizer
      錯体化学会第66回討論会
    • Place of Presentation
      福岡大学(福岡県・博多市)
    • Year and Date
      2016-09-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] Visible-light-responsive photoredox catalysis of polyoxometalates2016

    • Author(s)
      Kosuke Suzuki, Kazuya Yamaguchi, Noritaka Mizuno
    • Organizer
      International Symposium on Pure & Applied Chemistry 2016
    • Place of Presentation
      Kuching (Malaysia)
    • Year and Date
      2016-08-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Stimuli-Responsive Reversible Structural Transformation of Multinuclear Metal Cores Sandwiched by Polyoxometalates2016

    • Author(s)
      Kosuke Suzuki, Kazuya Yamaguchi, Noritaka Mizuno
    • Organizer
      42nd International Conference on Coordination Chemistry (ICCC 2016)
    • Place of Presentation
      Brest (France)
    • Year and Date
      2016-07-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Rearrangement of Ring-Shaped Manganese-Substituted Phosphotungstates2016

    • Author(s)
      Takuo Minato, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka Mizuno
    • Organizer
      42nd International Conference on Coordination Chemistry (ICCC 2016)
    • Place of Presentation
      Brest (France)
    • Year and Date
      2016-07-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水および温度応答性コバルト多核構造を有するポリオキソメタレートの合成と可逆構造変換2016

    • Author(s)
      鈴木康介,栗山陽介,菊川雄司,山口和也,水野哲孝
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      京都府,京田辺市,同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] リング状Mn置換ホスホタングステートの合成とアニオン構造の再構築2016

    • Author(s)
      湊拓生,鈴木康介,山口和也,水野哲孝
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      京都府,京田辺市,同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Visible-light-responsive photoredox catalysis of silicotungstates2015

    • Author(s)
      Kosuke Suzuki, Noritaka Mizuno
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      ホノルル,アメリカ
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Visible-light-responsive multielectron redox catalysis utilizing electron transfer from coordinated alcohols to lacunary polyoxometalates2015

    • Author(s)
      Jinu Jeong, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka Mizuno
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      ホノルル,アメリカ
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Inorganic anionic cage [α-Si2W18O62]8– with reversible proton capturing inside the aperture via intramolecular hydrogen bonds2015

    • Author(s)
      Takuo Minato, Kosuke Suzuki, Keigo Kamata, Noritaka Mizuno
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      ホノルル,アメリカ
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 欠損型シリコタングステートを用いた可視光応答型酸化還元触媒反応2015

    • Author(s)
      鈴木康介,鄭進宇,山口和也,水野哲孝
    • Organizer
      第48回酸化反応討論会
    • Place of Presentation
      京都府,京都市,同志社大学
    • Year and Date
      2015-10-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] 欠損型ポリオキソメタレートを用いた異種金属五核構造の逐次合成と単分子磁石特性2015

    • Author(s)
      湊拓生,鈴木康介,佐藤林太,篠江真広,山口和也,水野哲孝
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      奈良県,奈良市,奈良女子大学
    • Year and Date
      2015-09-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] Visible-light-responsive multielectron redox catalysis of lacunary polyoxometalates utilizing their lacuna2015

    • Author(s)
      鄭進宇,鈴木康介,山口和也,水野哲孝
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      奈良県,奈良市,奈良女子大学
    • Year and Date
      2015-09-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] 金属酸化物クラスターを用いた触媒および高機能材料の開発2015

    • Author(s)
      鈴木康介
    • Organizer
      触媒学会若手会 第26回フレッシュマンゼミナール
    • Place of Presentation
      東京都,新宿区,早稲田大学
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 欠損型ポリオキソメタレートへの基質の配位による可視光応答型多電子酸化還元光触媒の開発2015

    • Author(s)
      鄭進宇,鈴木康介,山口和也,水野哲孝
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      千葉,日本大学
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 欠損型ポリオキソメタレートを用いた可視応答型多電子酸化還元触媒の開発2014

    • Author(s)
      鄭進宇,鈴木康介,山口和也,水野哲孝
    • Organizer
      第4回CSJ化学フェスタ2014
    • Place of Presentation
      東京,タワーホール船堀
    • Year and Date
      2014-10-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] 欠損型ポリオキソメタレートアルコキサイドの合成2014

    • Author(s)
      湊拓生,鈴木康介,水野哲孝
    • Organizer
      第4回CSJ化学フェスタ2014
    • Place of Presentation
      東京,タワーホール船堀
    • Year and Date
      2014-10-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] セリウム四核構造を導入したシリコタングステートの合成と可視光応答型酸化還元触媒特性2014

    • Author(s)
      鈴木康介,湯飛,菊川雄司,山口和也,水野哲孝
    • Organizer
      第114回触媒討論会
    • Place of Presentation
      広島,広島大学
    • Year and Date
      2014-09-25
    • Related Report
      2014 Annual Research Report

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Published: 2014-04-04   Modified: 2018-03-22  

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