Catalyst Development by Synergistic Effects of Complex Metal Oxide Clusters
| Project/Area Number |
26708009
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Partial Multi-year Fund |
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| Research Field |
Functional solid state chemistry
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| Research Institution | The University of Tokyo |
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Principal Investigator |
SUZUKI Kosuke 東京大学, 工学(系)研究科(研究院), 助教 (40595667)
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥19,890,000 (Direct Cost: ¥15,300,000、Indirect Cost: ¥4,590,000)
Fiscal Year 2016: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2015: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2014: ¥11,180,000 (Direct Cost: ¥8,600,000、Indirect Cost: ¥2,580,000)
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| Keywords | 触媒 / ポリオキソメタレート / 金属多核構造 / 光触媒 / ナノ材料 / 構造・機能材料 / 超分子化学 |
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| Outline of Final Research Achievements |
The visible-light-responsive molecular catalysts were successfully developed by utilizing synergistic effects of molecular metal oxide clusters with multinuclear metal cores or organic molecules. These catalysts showed the intramolecular charge transfer properties by irradiation with visible light. In addition, they showed selective, efficient photocatalysis for the oxidation reactions of amines and sulfides using molecular oxygen as the oxidant as well as the reductive deoxygenation reactions of sulfoxides and pyridine N-oxides using alcohols as the reducing agents.
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Report
(4 results)
Research Products
(39 results)
