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Supramolecular Photolithography for the development of 4D Materials

Research Project

Project/Area Number 26810072
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Polymer chemistry
Research InstitutionTokyo Metropolitan University

Principal Investigator

Nishiyabu Ryuhei  首都大学東京, 都市環境科学研究科, 助教 (00432865)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords超分子化学 / 自己組織化 / 超分子 / 分子集合体 / 光ピンセット / 集光レーザー / 光造形 / 4Dマテリアル
Outline of Final Research Achievements

A new bottom-up approach allowing the construction of materials in solution by remote control has been developed using a focused laser beam to induce formation of molecular assemblies at the focal point.
An amphiphilic perylene dye was synthesized by introducing hydrophilic oligo ether chains into the perylene moiety. Irradiation of a focused Nd-YAG laser beam with 1056 nm to an aqueous solution of the synthesized dye led to formation of an architecture at the focal point, indicating the presented method could be applicable to a method for the construction of materials in solution by remote control.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (36 results)

All 2016 2015 2014 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results,  Acknowledgement Compliant: 3 results,  Open Access: 1 results) Presentation (25 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results) Remarks (1 results)

  • [Journal Article] 2,3-Naphtho-Fused BODIPYs as Near-Infrared Absorbing Dyes2016

    • Author(s)
      Sho Yamazawa, Mika Nakashima, Yukie Suda, Ryuhei Nishiyabu, and Yuji Kubo
    • Journal Title

      The Jpurnal of Organic Chemsitry

      Volume: 81 Issue: 3 Pages: 1310-1315

    • DOI

      10.1021/acs.joc.5b02720

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Multi-thiophene-substituted NIR boron-dibenzopyrromethene dyes: synthesis and their spectral properties2015

    • Author(s)
      Yukie Suda, Ryuhei Nishiyabu, Yuji Kubo
    • Journal Title

      Tetrahedron

      Volume: 71 Issue: 24 Pages: 4174-4182

    • DOI

      10.1016/j.tet.2015.04.094

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hierarchical supramolecules and organization using boronic acids building blocks2015

    • Author(s)
      Yuji Kubo, Ryuhei Nishiyabu and Tony D. James
    • Journal Title

      Chemical Communications

      Volume: 51 Issue: 11 Pages: 2005-2020

    • DOI

      10.1039/c4cc07712a

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Thermo-responsive white-light emission based on tetraphenylethylene- and rhodamine B-containing boronate nanoparticles2015

    • Author(s)
      Ayumi Ozawa, Ai Shimizu, Ryuhei Nishiyabu and Yuji Kubo
    • Journal Title

      Chemical Communications

      Volume: 51 Issue: 1 Pages: 118-121

    • DOI

      10.1039/c4cc07405j

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Boron-dibenzopyrromethene-based organic dyes for application in dye-sensitized solar cells2014

    • Author(s)
      Yuji Kubo, Daichi Eguchi, Asaki Matsumoto, Ryuhei Nishiyabu, Hidenori Yakushiji, Koichiro Shigaki and Masayoshi Kaneko
    • Journal Title

      Journal Material Chemistry A

      Volume: 2 Issue: 15 Pages: 5204-5211

    • DOI

      10.1039/c3ta15340a

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Nanospherical aggregation of isothiouronium-terminated amphiphilic polythiophene: Preparation and vapor-phase detection of volatile organic compounds2014

    • Author(s)
      Shunsuke Ozawa, Ryuhei Nishiyabu and Yuji Kubo
    • Journal Title

      Journal of Nanoscience and Nanotechnology

      Volume: 14 Issue: 9 Pages: 6624-6631

    • DOI

      10.1166/jnn.2014.9343

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Boronate microparticle-supported nano-palladium and nano-gold catalysts for chemoselective hydrogenation of cinnamaldehyde in environmentally preferable solvents2014

    • Author(s)
      Seika Fujiwara, Naoto Takanashi, Ryuhei Nishiyabu and Yuji Kubo
    • Journal Title

      Green Chemistry

      Volume: 16 Issue: 6 Pages: 3230-3236

    • DOI

      10.1039/c4gc00383g

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Intramolecular indicator displacement assay for anions: supramolecular sensor for glyphosate2014

    • Author(s)
      Tsuyoshi Minami, Yuanli Liu, Ali Akdeniz, Petr Koutnik, Nina A. Esipenko, Ryuhei Nishiyabu, Yuji Kubo and Pavel Anzenbacher, Jr.
    • Journal Title

      Journal of the American Chemical Society

      Volume: 136 Issue: 32 Pages: 11396-11401

    • DOI

      10.1021/ja504535q

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] A boronate hydrogel film containing organized two-component dyes as a multicolor fluorescent sensor for heavy metal ions in water2014

    • Author(s)
      Ryuhei Nishiyabu, Shiho Ushikubo, Yuka Kamiya and Yuji Kubo
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 2 Issue: 38 Pages: 15846-15852

    • DOI

      10.1039/c4ta03268c

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of a borylated boron-dibenzopyrromethene dye enabling the visual detection of H2O2 vapor2014

    • Author(s)
      Asaki Matsumoto, Ryuhei Nishiyabu and Yuji Kubo
    • Journal Title

      RSC Advances

      Volume: 4 Issue: 72 Pages: 37973-37978

    • DOI

      10.1039/c4ra06061j

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Boronate Molecular Assembles: Chemically Tailorable Platforms for Developing Multi-Color Emissive Chemosensors2016

    • Author(s)
      Ryuhei Nishiyabu, Yuji Kubo
    • Organizer
      Tenth International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments
    • Place of Presentation
      立命館大学
    • Year and Date
      2016-05-31
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 2,3-ナフト縮合型BODIPY の合成と性質2016

    • Author(s)
      中島美香・山澤翔・西藪隆平・久保由治
    • Organizer
      日本化学会第96春季年会(2016)
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] 色素グラフト型ボロネートゲルにおけるフォトン・アップコンバージョン特性2016

    • Author(s)
      松本寛人・薩た雄介・西藪隆平・久保由治
    • Organizer
      日本化学会第96春季年会(2016)
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 2,3,1-ベンゾジアザボリン型アニオンセンサーの合成2016

    • Author(s)
      薩た雄介・松本寛人・西藪隆平・Tony D. James・久保由治
    • Organizer
      日本化学会第96春季年会(2016)
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] AIE特性を持つボロネートナノ粒子の調製と白色発光型ナノサーモメーターへの応用2015

    • Author(s)
      小澤歩未・西藪隆平・久保由治
    • Organizer
      第42回有機典型元素化学討論会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2015-12-03
    • Related Report
      2015 Annual Research Report
  • [Presentation] 光誘起水分解反応のための光増感剤/触媒ハイブリッド2015

    • Author(s)
      ムリヤーナヤン・西藪隆平・久保由治・石井和之・スピッチャレオーネ
    • Organizer
      第26回基礎有機化学討論会
    • Place of Presentation
      愛媛大学・松山大学
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 重原子を有する近赤外線吸収色素の合成2015

    • Author(s)
      山澤翔・西藪隆平・久保由治
    • Organizer
      第26回基礎有機化学討論会
    • Place of Presentation
      愛媛大学・松山大学
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] マルチチエニル基置換ジベンゾ-BODIPY 系近赤外線吸収色素の合成と性質2015

    • Author(s)
      須田優紀江・浅羽拓郎・西藪隆平・久保由治
    • Organizer
      第26回基礎有機化学討論会
    • Place of Presentation
      愛媛大学・松山大学
    • Year and Date
      2015-09-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] アップコンバージョン特性を有するボロネートゲルの調製2015

    • Author(s)
      松本寛人・神谷夕夏・西藪隆平・嶋田哲也・高木慎介・久保由治
    • Organizer
      第13回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      東北大学
    • Year and Date
      2015-06-06
    • Related Report
      2015 Annual Research Report
  • [Presentation] ルテニウム担持型ボロネートナノ粒子を触媒利用したレブリン酸の水素化反応2015

    • Author(s)
      柿崎大樹、藤原成香、西藪隆平、久保由治、古後真紀子、萬ヶ谷康弘
    • Organizer
      日本化学会第95春季年会(2015)
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] ボロネートゲル中におけるアップコンバージョン特性の評価2015

    • Author(s)
      松本寛人、神谷夕夏、善積貴也、西藪隆平、久保由治
    • Organizer
      日本化学会第95春季年会(2015)
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 自己集合性アントラセンイミド誘導体の合成とその性質2015

    • Author(s)
      飯塚俊介、齋藤智紀、西藪隆平、久保由治
    • Organizer
      日本化学会第95春季年会(2015)
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-28
    • Related Report
      2014 Research-status Report
  • [Presentation] アニオン応答型アセンイミド集合体の構築2015

    • Author(s)
      齋藤智紀、飯塚俊介、西藪隆平、久保由治
    • Organizer
      日本化学会第95春季年会(2015)
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-28
    • Related Report
      2014 Research-status Report
  • [Presentation] 光学活性酒石酸から誘導される AIE ボロン酸エステル会合体の性質2015

    • Author(s)
      中本昇吾、小澤歩未、藤原成香、西藪隆平、久保由治
    • Organizer
      日本化学会第95春季年会(2015)
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-28
    • Related Report
      2014 Research-status Report
  • [Presentation] 近赤外光吸収特性を有するボロンジナフトピロメテン系色素の合成2015

    • Author(s)
      山澤翔、浅羽拓郎、須田優紀江、西藪隆平、久保由治
    • Organizer
      日本化学会第95春季年会(2015)
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-28
    • Related Report
      2014 Research-status Report
  • [Presentation] 自己組織化ボロネートヒドロゲルの疎水化とその色素吸着特性2015

    • Author(s)
      西藪隆平、小川雄大、久保由治
    • Organizer
      日本化学会第95春季年会(2015)
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-28
    • Related Report
      2014 Research-status Report
  • [Presentation] マルチチエニル基導入型ボロンジベンゾピロメテン系色素の合成と性質2014

    • Author(s)
      須田優紀江、西藪隆平、久保由治
    • Organizer
      第41回有機典型元素化学討論会
    • Place of Presentation
      宇部市文化会館文化ホール
    • Year and Date
      2014-11-27
    • Related Report
      2014 Research-status Report
  • [Presentation] Chemically Tailorable Boronate Platforms for Developing Multi-Color Emissive Chemosensors in Water2014

    • Author(s)
      Ryuhei Nishiyabu、Yuji Kubo
    • Organizer
      4th International Conference on Molecular Sensors and Molecular Logic Gates
    • Place of Presentation
      華東理工大学(上海・中国)
    • Year and Date
      2014-11-11
    • Related Report
      2014 Research-status Report
  • [Presentation] ボロン酸エステルポリマーの階層的自己組織化を利用した白色発光ケモセンサー2014

    • Author(s)
      西藪隆平、杉野康行、久保由治
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学文教キャンパス
    • Year and Date
      2014-09-25
    • Related Report
      2014 Research-status Report
  • [Presentation] ポリビニルアルコールをマトリックスにするボロネートヒドロゲルの調製とマルチカラー発光ケモセンサーへの展開2014

    • Author(s)
      西藪隆平、牛久保志穂、神谷夕夏、久保由治
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学文教キャンパス
    • Year and Date
      2014-09-24
    • Related Report
      2014 Research-status Report
  • [Presentation] テトラフェニルエテンを有するボロン酸エステル体の合成と発光性自己集合挙動2014

    • Author(s)
      小澤歩未、清水藍、西藪隆平、久保由治
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学川内北キャンパス
    • Year and Date
      2014-09-08
    • Related Report
      2014 Research-status Report
  • [Presentation] 過酸化水素を可視化検出できるボロンジベンゾピロメテン系色素の合成2014

    • Author(s)
      松本亜早希、西藪隆平、久保由治
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学川内北キャンパス
    • Year and Date
      2014-09-08
    • Related Report
      2014 Research-status Report
  • [Presentation] Pd担持型ボロン酸エステル型自己集合粒子の調製とグリーン触媒機能2014

    • Author(s)
      藤原成香、西藪隆平、久保由治
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学川内北キャンパス
    • Year and Date
      2014-09-07
    • Related Report
      2014 Research-status Report
  • [Presentation] 水分散性ボロネートマイクロ粒子の表面機能化2014

    • Author(s)
      藤原成香、杉野康行、西藪隆平、久保由治
    • Organizer
      第12回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2014-06-01
    • Related Report
      2014 Research-status Report
  • [Presentation] AIE型ボロネートナノ粒子の調製とその性質2014

    • Author(s)
      小澤歩未、杉野康行、西藪隆平、久保由治
    • Organizer
      第12回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2014-05-31
    • Related Report
      2014 Research-status Report
  • [Remarks]

    • URL

      http://www.comp.tmu.ac.jp/kubolab/kubolabtop.html

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2017-05-10  

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