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Characteristic properties of Ion Exchange in a Phosphoester Coordination Polymer

Research Project

Project/Area Number 26810080
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Analytical chemistry
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

Tasaki-Handa Yuiko  国立研究開発法人産業技術総合研究所, 環境管理研究部門, 主任研究員 (20586599)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords配位高分子 / イオン交換 / リン酸エステル / レアアース / ランタノイド
Outline of Final Research Achievements

1) To further investigate the characteristic ion exchange properties in phosphoester coordination polymer, XAFS measurement was conducted. It was found that the local structure of not light lanthanide (Ln3+) but heavy Ln3+ is changed when two kinds of Ln3+ coexist in a coordination polymer. 2) Formation of organogels, following lyophilization of phosphoester coordination polymers enhanced the kinetics of ion exchange reaction. 3) Different phosphoesters had some problems, i.e. high solubility in water and low reactivity, therefore they did not offer beneficial information on the relation between the structure and the ion exchange properties. 4) We found that selective ion exchange reaction occurred also in coordination polymers based on carboxylate.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (4 results)

All 2015 2014

All Presentation (4 results) (of which Invited: 1 results)

  • [Presentation] 配位高分子を利用する レアアース相互分離2015

    • Author(s)
      半田友衣子 安倍雪絵 大井健太 成田弘一 田中幹也 脇坂昭弘
    • Organizer
      資源・素材学会秋季大会
    • Place of Presentation
      愛媛大学
    • Year and Date
      2015-09-08
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Unique and tunable affinity of lanthanide ion exchange in phosphodiester coordination polymers2014

    • Author(s)
      半田 友衣子、安倍 雪絵、大井 健太、成田 弘一、田中 幹也、脇坂 昭弘
    • Organizer
      International Conference of Ion Exchange 2014
    • Place of Presentation
      Okinawa Convention Center
    • Year and Date
      2014-11-09
    • Related Report
      2014 Research-status Report
  • [Presentation] Unique affinity of central lanthanide ion exchange in phosphodiester coordination polymers2014

    • Author(s)
      半田 友衣子、安倍 雪絵、大井 健太、成田 弘一、田中 幹也、脇坂 昭弘
    • Organizer
      MOF2014
    • Place of Presentation
      Kobe Convention Center
    • Year and Date
      2014-09-28
    • Related Report
      2014 Research-status Report
  • [Presentation] リン酸ジエステル配位高分子におけるランタノイドイオン交換:高分子骨格ゆがみが関与する特徴的なイオン交換選択性2014

    • Author(s)
      半田友衣子、安倍雪絵、大井健太、成田弘一、田中幹也、脇坂昭弘
    • Organizer
      日本分析化学会 第74回分析化学討論会
    • Place of Presentation
      日本大学郡山キャンパス
    • Year and Date
      2014-05-24
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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