| Project/Area Number |
26810099
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Green/Environmental chemistry
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| Research Institution | Institute for Molecular Science |
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Principal Investigator |
OSAKO Takao 分子科学研究所, 生命・錯体分子科学研究領域, 助教 (90500984)
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
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| Keywords | ポリマー担持触媒 / フロー反応 / 酸素酸化反応 / ユビキタス金属 / ユビキタスメタル / 担持銅錯体 / アルキルアミン系配位子 / 酸化的カップリング / 1,3-ジイン |
|---|
| Outline of Final Research Achievements |
Development of heterogeneous polymer-supported ubiquitous metal catalysts was investigated to realize the aqueous flow aerobic oxidation reactions using oxygen under highly green-sustainable conditions. As the results, new polystyrene and polystyrene poly(ethylene glycol)-supported alkylamine and pyridylamine copper catalysts were successfully developed and applied to a series of oxidation reactions with oxygen such as the oxidative homocoupling of terminal alkynes and aerobic oxidation and azide-alkyne cycloaddition under batch and flow conditions.
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