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Fabrication of high dielectric BaTiO3 film by a control of defect structures using transmission electron microscopy

Research Project

Project/Area Number 26889078
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Inorganic materials/Physical properties
Research InstitutionJapan Fine Ceramics Center

Principal Investigator

KOBAYASHI Shunsuke  一般財団法人ファインセラミックスセンター, その他部局等, 研究員 (60714623)

Project Period (FY) 2014-08-29 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywordsチタン酸バリウム / 薄膜 / 誘電率 / 透過型電子顕微鏡 / 歪み / BaTiO3 / ドメイン / STEM / 走査型透過電子顕微鏡 / 強誘電体 / パルスドレーザー堆積法
Outline of Final Research Achievements

High dielectric material is very important for technological applications. Especially, ferroelectric perovskite oxide films have been intensively investigated due to an expectation for a high dielectric constant. In this study, we aim to fabricate the high dielectric BaTiO3 film by tuning stoichiometry in a film and forming atomically flat interface between an electrode and a film. In the present BaTiO3 film, the dielectric constant showed ε = 11,005 at Tc (690 K) and also over 2,000 (300 ~690 K), which is significantly higher than previously reported values.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • Research Products

    (8 results)

All 2016 2015 2014

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (7 results) (of which Invited: 1 results)

  • [Journal Article] High Electron Mobility of Nb-Doped SrTiO3 Films Stemming from Rod-Type Sr Vacancy Clusters2015

    • Author(s)
      S. Kobayashi, Y. Mizumukai, T. Ohnishi, N. Shibata, Y. Ikuhara and T. Yamamoto
    • Journal Title

      ACS Nano

      Volume: 9 Issue: 11 Pages: 10769-10777

    • DOI

      10.1021/acsnano.5b05720

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 走査型透過電子顕微鏡を用いたBaTiO3薄膜のナノドメイン構造解析2016

    • Author(s)
      小林 俊介、加藤 丈晴、 幾原 雄一、 山本 剛久
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2016-03-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] 斜方晶系GdScO3基板に成膜したBaTiO3薄膜の相転移挙動2015

    • Author(s)
      小林 俊介、加藤 丈晴、 平山 司、 幾原 雄一、 山本 剛久
    • Organizer
      2015年秋季 第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 走査型透過電子顕微鏡を用いたBaTiO3薄膜の界面構造解析2015

    • Author(s)
      小林 俊介、大石 修、加藤 丈晴、 平山 司、 幾原 雄一、 山本 剛久
    • Organizer
      日本顕微鏡学会 第71回記念学術講演会
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2015-05-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] 走査型透過電子顕微鏡を用いたBaTiO3薄膜の界面構造解析2015

    • Author(s)
      小林俊介、大石修、加藤丈晴、平山司、幾原雄一、山本剛久
    • Organizer
      日本顕微鏡学会第71回記念学術講演会
    • Place of Presentation
      国立京都国際会館(京都)
    • Year and Date
      2015-05-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] ペロブスカイト酸化物薄膜における欠陥構造制御と物性発現2014

    • Author(s)
      小林俊介
    • Organizer
      生研材料学セミナー
    • Place of Presentation
      東京大学(東京)
    • Year and Date
      2014-12-22
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ペロブスカイト酸化物中の酸素欠損に伴う陽イオン原子変位の可視化2014

    • Author(s)
      小林俊介, Scott Findlay, 奥西栄治, 幾原雄一, 山本剛久
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 高誘電率BaTiO3薄膜の作製と透過型電子顕微鏡による構造解析2014

    • Author(s)
      小林 俊介, 加藤 丈晴, 平山 司, 幾原 雄一, 山本 剛久
    • Organizer
      日本セラミックス協会 第27回秋季シンポジウム
    • Place of Presentation
      鹿児島大学 (鹿児島)
    • Year and Date
      2014-09-09
    • Related Report
      2014 Annual Research Report

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Published: 2014-09-09   Modified: 2017-05-10  

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