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2012 Fiscal Year Final Research Report

Incorporation mechanism of hydrogen into some minerals and its dynamical behavior at high pressure

Planned Research

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Project AreaEarth Science Based on the High Pressure and Temperature Neutron Experiments
Project/Area Number 20103002
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionHokkaido University

Principal Investigator

NAGAI Takaya  北海道大学, 大学院・理学研究院, 教授 (20243131)

Co-Investigator(Kenkyū-buntansha) AKASAKA Masahide  島根大学, 総合理工学研究科, 教授 (20202509)
KURIBAYASHI Takahiro  東北大学, 大学院・理学研究科, 助教 (20302086)
NFUKAZAWA Hiroshi  独立行政法人日本原子力研究開発機構, 量子ビーム応用研究部門, 主任研究員 (30370464)
SANO Asami  独立行政法人日本原子力研究開発機構, 量子ビーム応用研究部門, 研究員 (30547104)
UTSUMI Wataru  独立行政法人日本原子力研究開発機構, 量子ビーム応用研究部門, 研究推進室長 (60193918)
Project Period (FY) 2008 – 2012
Keywords含水鉱物 / 氷 / 結晶構造 / 高温高圧 / 水素結合 / 中性子回折
Research Abstract

More and more application of neutron diffraction technique is expected in the field of mineral physics in the near future. Crystallographic information about hydrogen positions in some important hydrous minerals was successfully obtained in quite wide range of pressure-temperature conditions. These could give some new insights of hydrogen positions in some mantle minerals, a pressure-induced hydrogen-bond symmetrization mechanism, the relationship between specific thermal expansion and dynamical behavior of hydrogen atoms, and the relationship between cationic substitution and hydrogen positions in some crustal minerals.

  • Research Products

    (49 results)

All 2013 2012 2011 2010 2009 2008 Other

All Journal Article (20 results) (of which Peer Reviewed: 20 results) Presentation (27 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Distribution of cations at two tetrahedral sites in Ca_2MgSi_2O_7-Ca_2Fe^<3+>AlSiO_7 series synthetic melilite and its relation to ncommensurate structure2013

    • Author(s)
      Hamada M. and Akasaka M
    • Journal Title

      Physics and Chemistry of Minerals

      Volume: 40 Pages: 259-270

    • DOI

      Doi:10.1007/s00269-013-0566-8

    • Peer Reviewed
  • [Journal Article] Compression behaviors of distorted rutile-type hydrous phases, MOOH (M=Ga, In, Cr) and CrOOD2012

    • Author(s)
      Sano-Furukawa A, Yagi T., Okada T., Gotou H. and Kikegawa T.
    • Journal Title

      Physics and Chemistry of Minerals

      Volume: 39 Pages: 75-383

    • DOI

      Doi0.1007/s00269-012-0487-y

    • Peer Reviewed
  • [Journal Article] Oxidation state of Fe in olivine in andesitic scoria from Kasayama volcano, Hagi, Yamaguchi Prefecture, Japan2012

    • Author(s)
      Ejima T., Akasaka M, Nagao T. and Ohfuji H
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 107 Pages: 215-225

    • DOI

      Doi:10.2465/ jmps.120605

    • Peer Reviewed
  • [Journal Article] 中性子散乱実験により明らかにする鉱物中の水素結合とその役割2012

    • Author(s)
      佐野亜沙美
    • Journal Title

      波紋

      Volume: 22 Pages: 162-165

    • Peer Reviewed
  • [Journal Article] Pressure responses of portlandite and H-D isotope effects on pressure-induced phase transitions2011

    • Author(s)
      Iizuka R., Kagi H., Komatsu K., Ushijima D., Nakano S., Sano-Furukawa A., Nagai T. and Yagi T
    • Journal Title

      Physics and Chemistry of Minerals

      Volume: 38 Pages: 777-785

    • DOI

      Doi10.1007/s00269 -011-0450-3

    • Peer Reviewed
  • [Journal Article] Investigation of hydrogen site of hydrous wadsleyite: A neutron diffraction study2011

    • Author(s)
      Sano-Furukawa A., Kuribayashi T., Komatsu K., Yagi T. and Ohtani E.
    • Journal Title

      Physics of the Earth and Planetary Interiors

      Volume: 189 Pages: 56-62

    • DOI

      Doi:10.1016/j.pepi.2011.07.003

    • Peer Reviewed
  • [Journal Article] Structure and properties of ferroelectric water ice2011

    • Author(s)
      Fukazawa H., Arakawa M, Kagi H., Fernandez-Baca J.A. and Chakoumakos B.C.
    • Journal Title

      Physics and Chemistry of ice

      Pages: 421-428

    • Peer Reviewed
  • [Journal Article] Oxidation state of Fe in olivine in a lherzolite xenolith from Oku district, Oki-Dogo Island, Shimane Prefecture, Japan2011

    • Author(s)
      Ejima T. and Akasaka M.
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 106 Pages: 110-125

    • DOI

      Doi:10.2465/jmps.110125

    • Peer Reviewed
  • [Journal Article] 電子マイクロプローブ分析によるかんらん石中のFe2+/Fe3+比の見積もり:メスバウアー分光法による検証2011

    • Author(s)
      江島輝美, 赤坂正秀
    • Journal Title

      岩石鉱物科学

      Volume: 40 Pages: 55-62

    • DOI

      Doi:10.2465/gkk.10091

    • Peer Reviewed
  • [Journal Article] スラブやマントル鉱物の結晶構造中における水素原子の振る舞い2011

    • Author(s)
      栗林貴弘
    • Journal Title

      日本結晶学会誌

      Volume: 53 Pages: 19-24

    • Peer Reviewed
  • [Journal Article] X-ray Rietveld and ^<57>Fe Mossbauer studies of epidote and piemontite on the join Ca_2Al_2Fe^<3+>Si_3O_<12>(OH)-Ca_2Al_2Mn^<3+>Si_3O_<12>(OH) formed by hydrothermal synthesis2010

    • Author(s)
      Nagashima, M. and Akasaka, M
    • Journal Title

      American Mineralogist

      Volume: 95 Pages: 1237-1246

    • DOI

      Doi:10.2138/am.2010.3418

    • Peer Reviewed
  • [Journal Article] Crystal chemistry of chromian pumpellyite from Osayama, Okayama Prefecture, Japan2010

    • Author(s)
      Hamada, M. Akasaka, M., Seto, S. and Makino, K
    • Journal Title

      American Mineralogist

      Volume: 95 Pages: 1294-1304

    • DOI

      Doi:10.2138/am.2010.3376

    • Peer Reviewed
  • [Journal Article] Infrared absorption spectra of δ-AlOOH and its deuteride at high pressure and implication to pressure response of the hydrogen bonds2010

    • Author(s)
      Kagi K., Ushijima D, Sano-Furukawa A., Komatsu K, Iizuka R., Nagai T. and Nakano S
    • Journal Title

      Jour. Physics: Conference Series

    • DOI

      Doi:0.1088/1742-6596/215/1/012052

    • Peer Reviewed
  • [Journal Article] Annealing effects on hydrogen ordering in KOD-doped ice observed using neutron diffraction2010

    • Author(s)
      Arakawa M., Kagi H. and Fukazawa H
    • Journal Title

      Journal of Molecular Structure

      Volume: 972 Pages: 111-114

    • DOI

      Doi:10.1016/j.molstruc.2010.02. 016

    • Peer Reviewed
  • [Journal Article] CO_2 motion in carbon dioxide deuterohydrate determined by applying maximum entropy method to neutron powder diffraction data2010

    • Author(s)
      Igawa N., Taguchi T., Hoshikawa A., Fukazawa H., Yamauchi H., Utsumi W. and Ishii Y
    • Journal Title

      Journal of Physics and Chemistry of Solids

      Volume: 71 Pages: 899-905

    • DOI

      Doi:10.1016/j.jpcs.2010.03.039

    • Peer Reviewed
  • [Journal Article] Change in compressibility of delta-AlOOH and delta-AlOOD at high pressure: A study of isotope effect and hydrogen-bond ymmetrization2009

    • Author(s)
      Sano-Furukawa A., Kagi H., Nagai T., Nakano S., Fukura S., Ushijima D., Iizuka R., Ohtani E. and Yagi T
    • Journal Title

      American Mineralogist

      Volume: 94 Pages: 1255-1261

    • DOI

      Doi:10.2138/am.2009.3109

    • Peer Reviewed
  • [Journal Article] Neutron Powder Diffraction under High Pressure at J-PARC2009

    • Author(s)
      Utsumi W, Kagi H, Komatsu K, Arima H, Nagai T, Okuchi T, Kamiyama T, Uwatoko Y, Matsubayashi K and Yagi T
    • Journal Title

      Nuclear Instruments and Methods of Physics Research Section A

      Volume: 600 Pages: 50-52

    • DOI

      Doi:10.1016/j.nima.2008.11.065

    • Peer Reviewed
  • [Journal Article] J-PARCでの高圧高温専用ビームラインの実現に向けて2009

    • Author(s)
      永井隆哉,有馬寛,奥地拓生,鍵裕之,八木健彦
    • Journal Title

      高圧力の科学と技術

      Volume: 19 Pages: 15-23

    • Peer Reviewed
  • [Journal Article] Existence of ferroelectric ice on planets -a neutron diffraction study2009

    • Author(s)
      Fukazawa H., Hoshikawa A., Chakoumakos B.C. and Fernandez-Baca J.A.
    • Journal Title

      Nuclear Instruments and Methods of Physics Research Section A

      Volume: 600 Pages: 279-281

    • DOI

      Doi:10.1016/j.nima.2008.11. 044

    • Peer Reviewed
  • [Journal Article] Synchrotron x-ray study of norbergite, Mg_<2.98>Fe_<0.01>Ti_<0.02>Si_<0.99>O_8(OH_<0.31>F_<1.69>), crystal structure under high-pressure up to 8.2 Gpa2008

    • Author(s)
      Kuribayashi T., Tanaka M. and Kudoh Y
    • Journal Title

      Physics and Chemistry of Minerals

      Volume: 35 Pages: 559-568

    • DOI

      Doi:10.1007/s00269-008-0248-0

    • Peer Reviewed
  • [Presentation] Hydrogen position refinement in super hydrous phase B structure under high-pressure conditions2012

    • Author(s)
      Kuribayashi T
    • Organizer
      IUCr Commission on High Pressure 2012 Meeting "Advances in Crystallography at High Pressures"
    • Place of Presentation
      Mito, Japan
    • Year and Date
      20120923-27
  • [Presentation] anvil press for neutron diffraction experiment at J-PARC2012

    • Author(s)
      Sano-Furukawa A., Hattori T., Arima H., Utsumi W., Kagi H. and Yagi T
    • Organizer
      Joint 2012 COMPRES Annual Meeting and High-Pressure Mineral Physics Seminar-8
    • Place of Presentation
      Lake Taho, USA
    • Year and Date
      20120709-13
  • [Presentation] 中性子回折によるポートランダイトの熱膨張機構の研究2012

    • Author(s)
      永井隆哉,佐野亜沙美,飯塚理子,鍵裕之
    • Organizer
      日本鉱物科学会2012年度年会
    • Place of Presentation
      京都大学(京都府)
    • Year and Date
      2012-09-20
  • [Presentation] 東南極セーヌロンダーネ山地産含バナジウムざくろ石:X線単結晶構造解析と赤外分光分析2012

    • Author(s)
      赤坂正秀,平田みお,濱田麻希,永嶌真理子,牧野邦明,小山内康人
    • Organizer
      日本鉱物科学会2012年度年会
    • Place of Presentation
      京都大学(京都府)
    • Year and Date
      2012-09-20
  • [Presentation] 中性子回折を用いたMg(OD)_2の高温での構造変化の研究2012

    • Author(s)
      永井隆哉,佐野亜沙美,飯塚理子,鍵裕之
    • Organizer
      2012年度地球惑星科学連合大会
    • Place of Presentation
      幕張メッセ(千葉県)
    • Year and Date
      2012-05-22
  • [Presentation] Determination of hydrogen sites of nominally anhydrous minerals of the mantle transition zone2011

    • Author(s)
      Kuribayashi T., Sano-Furukawa A., Komatsu K., Yagi T. and Ohtani E
    • Organizer
      1^<st>V Asia-Oceania Conference on Neutron Scattering
    • Place of Presentation
      Tsukuba, Japan
    • Year and Date
      20111121-23
  • [Presentation] Determination of hydrogen sites of nominally anhydrous mineral of the mantle transition zone2011

    • Author(s)
      Sano-Furukawa A., Kuribayashi T., Komatsu K., Yagi T. and Ohtani E
    • Organizer
      1^<st> Asia-Oceania Conference on Neutron Scattering
    • Place of Presentation
      Tsukuba, Japan
    • Year and Date
      20111121-23
  • [Presentation] Neutron diffraction study on δ-AlOOH at high pressure2011

    • Author(s)
      Sano-Furukawa A., Komatsu K., Hattori T., Nagai T., Kagi H., Molaison J.J., Moreia-Dos Santos A.F. and Tulk C.A.
    • Organizer
      AIRAPT-23
    • Place of Presentation
      Mumbai, India
    • Year and Date
      20110925-30
  • [Presentation] Hydrogen motions of Mg(OD)_2 and Ca(OD)_2 at several temperatures2011

    • Author(s)
      Nagai T., Sano-Furukawa A., Iizuka R., Chakoumakos B.C. and Fernandez-Baca J.A.
    • Organizer
      International Union of Crystallography (IUCr) 2011
    • Place of Presentation
      Madrid, Spain
    • Year and Date
      20110822-30
  • [Presentation] Mg(OD)_2の高温中性子回折実験2011

    • Author(s)
      永井隆哉,佐野亜沙美,飯塚理子,鍵裕之
    • Organizer
      日本鉱物科学会2011年度年会
    • Place of Presentation
      茨城大学(水戸市)
    • Year and Date
      2011-09-11
  • [Presentation] Mg(OD)_2の高温中性子回折実験について2011

    • Author(s)
      永井隆哉
    • Organizer
      2011年地球惑星科学連合
    • Place of Presentation
      幕張メッセ(千葉県)
    • Year and Date
      2011-05-25
  • [Presentation] 含重水素紅簾石の合成と生成相の評価2011

    • Author(s)
      赤坂正秀, 永嶌真理子, 濱田麻希, 佐野亜沙美, 江島輝美
    • Organizer
      地球惑星科学連合
    • Place of Presentation
      幕張メッセ(千葉県)
    • Year and Date
      2011-05-25
  • [Presentation] Neutron powder diffraction study using HRPD at JRR-3 and WAND at HFIR -Recent results on H-bond- (invited)2011

    • Author(s)
      Fukazaw H
    • Organizer
      Korean Physics Society April Meeting
    • Place of Presentation
      Daejeon, Korea
    • Year and Date
      2011-04-14
  • [Presentation] 米国パルス中性子施設SNS のSNAP における高圧中性子実験2010

    • Author(s)
      佐野亜沙美・服部高典・内海渉・小松一生・鍵裕之・永井隆哉
    • Organizer
      第51回高圧討論会
    • Place of Presentation
      戦災復興会館(仙台市)
    • Year and Date
      20101020-22
  • [Presentation] 熱重量測定による脱水反応速度への同位体効果2010

    • Author(s)
      永井隆哉,小林紗和
    • Organizer
      日本鉱物科学会2010年度年会
    • Place of Presentation
      島根大学(松江市)
    • Year and Date
      20100923-25
  • [Presentation] Ca 単斜輝石の6配位席と4配位席おけるFe^<3+>とGa^<3+>の分布2010

    • Author(s)
      赤坂 正秀・浜田 麻希・永嶌 真理子・大橋 晴夫
    • Place of Presentation
      島根大学(松江市)
    • Year and Date
      20100923-25
  • [Presentation] Formation of a perovskite solid solution between MgSiO_3 and MnSiO_3 at the lower mantle condition2010

    • Author(s)
      Nagai T., Ishido T. and Fujino K
    • Organizer
      the 20th General Meeting of International Mineralogical Association
    • Place of Presentation
      Budapest
    • Year and Date
      20100821-27
  • [Presentation] X-ray and neutron Rietveld study of synthetic Ca_2Al_<3->pMn^<3+>__pSi_3O_<12>(OD)-piemontite2010

    • Author(s)
      Akasaka M., Nagashima M., Hamada M., Sano-Furukawa A. and Ejima T
    • Organizer
      International Mineralogical Association
    • Place of Presentation
      Budapest
    • Year and Date
      20100821-27
  • [Presentation] Structure and Properties of Ferroelectric Water Ices -accelerating evolution of icy grain-2010

    • Author(s)
      Fukazawa H., Arakawa M., Kagi H., Chakoumakos B.C. and Fernandez-Baca J.A.
    • Organizer
      12th International Conference on Physics and Chemistry of ice
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2010-09-07
  • [Presentation] 熱重量測定によるCa(OH)_2とCa(OD)_2の脱水反応の速度論的解析2010

    • Author(s)
      永井隆哉,小林紗和,栗林貴弘
    • Organizer
      2010年日本地球惑星科学連合
    • Place of Presentation
      幕張メッセ(千葉県)
    • Year and Date
      2010-05-23
  • [Presentation] 単結晶MEM 解析によるsuper B 相の1 GPa および3.5 GPaの高圧下における水素位置の推定2010

    • Author(s)
      栗林貴弘,工藤康弘
    • Organizer
      2010年日本地球惑星科学連合
    • Place of Presentation
      幕張メッセ(千葉県)
    • Year and Date
      2010-05-23
  • [Presentation] 合成Ca_2Al_3-pMn_<3+>pSi_3O_12(OD)-紅簾石のX線・中性子結晶構造解析2010

    • Author(s)
      赤坂正秀,永嶌真理子,濱田麻希,佐野亜沙美,江島輝美
    • Organizer
      2010年日本地球惑星科学連合
    • Place of Presentation
      幕張メッセ(千葉県)
    • Year and Date
      2010-05-23
  • [Presentation] マントル遷移層構成鉱物の構造解析2009

    • Author(s)
      佐野亜沙美,八木健彦,小松一生,栗林貴弘
    • Organizer
      日本中性子科学会
    • Place of Presentation
      東海村(茨城県)
    • Year and Date
      2009-11-09
  • [Presentation] Properties of ferroelectric and hydrogen ordered ices in space2009

    • Author(s)
      Fukazawa H
    • Organizer
      XVIII International Conference on "Horizons in Hydrogen Bond Research
    • Place of Presentation
      Paris
    • Year and Date
      2009-09-15
  • [Presentation] 中性子回折実験によるCa(OD)_2の重水素位置の精密化2009

    • Author(s)
      永井隆哉,佐野亜佐美,鍵裕之,飯塚理子,栗林貴弘
    • Organizer
      日本鉱物科学会2009年度年会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2009-09-08
  • [Presentation] Ca_2Al_<3-p>Mn^<3+>pSi_3O_<12>(OD)-紅簾石の合成と中性子結晶構造解析2009

    • Author(s)
      赤坂正秀,永嶌真理子,濱田麻希,佐野亜沙美
    • Organizer
      日本鉱物科学会2009年度年会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2009-09-08
  • [Presentation] 新規採択された中性子散乱を用いた鉱物中の水の固定機構に関する研究計画について2009

    • Author(s)
      永井隆哉
    • Organizer
      2009年日本地球惑星科学連合
    • Place of Presentation
      幕張メッセ(千葉県)
    • Year and Date
      2009-05-16
  • [Book] 地球惑星科学入門2010

    • Author(s)
      在田一則,竹下徹,見延庄士郎,渡部重十 編者(永井隆哉:第3章執筆)
    • Total Pages
      427(第3章p25-34)
    • Publisher
      北海道大学出版会
  • [Remarks]

    • URL

      http://yagi.issp.u-tokyo.ac.jp/shingakujutsu/mineral.html

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Published: 2014-08-29  

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