Precise Design of Soft Interfaces through Surface Micro-, Nano-Fabrication and Polymer Nano-Grafting

2012 Fiscal Year Final Research Report

• Project Area: Molecular Soft-Interface Science
• Project/Area Number: 20106002
• Research Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Kyushu University
• Principal Investigator: TAKAHARA Atsushi 九州大学, 先導物質化学研究所, 教授 (20163305)
• Co-Investigator(Kenkyū-buntansha): KOBAYASHI Motoyasu 九州大学, 先導物質化学研究所, 助教 (50323176)
• Co-Investigator(Renkei-kenkyūsha): HIGAKI Yuji 九州大学, 先導物質化学研究所, 助教 (40619649)
• Project Period (FY): 2008 – 2012
• Keywords: ナノファイバー / ナノインプリント / 表面開始制御ラジカル重合 / 濡れ性 / ナノファイバー不織布 / オムニフォビシティ

Research Abstract

Surface properties of softmaterials were governed by the hierarchical structure through nanometer (molecular level) to μm (artificial fabrication size) scales as well as surface chemistry and surface molecular motion. In this study, micro-, nano-structure controlled soft interfaces were fabricated by various precise processing techniques and surface chemistry was controlled by the surface initiated controlled radical polymerization. The molecular aggregation structure and surface properties of softinterfaces were characterized through various microscopic, spectroscopic and scattering methods. Also, the relationships among surface functionalities, surface structure and surface chemistry were discussed.

Research Products

• [Journal Article] Precise and Non-destructive Characterization of 'Buried' Nano-structure in Polymer Thin Film by Synchrotron Radiation Ultra-Small Angle X-ray Scattering (2013)
  • Author(s): T. Shinohara, T. Shirahase, D. Murakami, T. Hoshino, M. Kikuchi, J. Koike, M. Horigome, H. Masunaga, H. Ogawa, A. Takahara
  • Journal Title: Polym. J Volume: 45 Pages: 307-312
  • DOI: DOI:10.1038/pj.2012.133
  • Peer Reviewed
• [Journal Article] Structural Effects of Catechol-Containing Polystyrene Gels Based on Dual Cross-linking Approach (2013)
  • Author(s): H. Xu, J. Nishida, H. Wu, Y. Higaki, H. Otsuka, N. Ohta, A. Takahara
  • Journal Title: Soft Matter Volume: 9 Pages: 1967-1974
  • DOI: DOI:10.1039/C2SM26994E
  • Peer Reviewed
• [Journal Article] Perfluoropolyether-infused nano-texture: a versatile Approach to omniphobic coatings with low hysteresis and high transparency (2013)
  • Author(s): W. Ma, Y. Higaki, H. Otsuka, A. Takahara
  • Journal Title: Chem. Comm Volume: 49 Pages: 597-599
  • DOI: DOI:10.1039/C2CC37576A
  • Peer Reviewed
• [Journal Article] Orientation of Poly (vinyl alcohol) Nanofiber and Crystallites in Non-woven Electrospun Nanofiber Mats under Uniaxial Stretching (2012)
  • Author(s): T. Yano, Y. Higaki. D. Tao, D. Murakami, M. Kobayashi, N. Ohta, Y. Ikemoto, T. Moriwaki, A. Takahara
  • Journal Title: Polymer Volume: 53 Pages: 4702-4708
  • DOI: DOI:10.1016/j.polymer.2012.07.067
  • Peer Reviewed
• [Journal Article] A " Non-sticky " superhydrophobic surface by self-assembly of fluoroalkyl phosphonic acid on a hierarchically micro/nanostructured alumina gel film (2012)
  • Author(s): W. Ma, H. Wu, Y. Higaki,. H. Otsuka, A. Takahara
  • Journal Title: Chem.Comm Volume: 48 Pages: 6824-6826
  • DOI: DOI:10.1039/C2CC32513F
  • Peer Reviewed
• [Journal Article] Competition between Oxidation and Coordination in Cross-Linking of Polystyrene Copolymer Containing Catechol Groups (2012)
  • Author(s): H. Xu, J. Nishida, W. Ma, H. Wu,,M. Kobayashi,,H. Otsuka, A.Takahara
  • Journal Title: ACS Macro Lett Volume: 1 Pages: 457-460
  • DOI: DOI:10.1021/mz200217d
  • Peer Reviewed
• [Journal Article] Abnormalities of Stromal Structure in the Bullous Keratopathy Cornea Identified by Second Harmonic Generation Imaging Microscopy (2012)
  • Author(s): N. Morishige, N.Yamada, X. Zhang, Y. Morita, N. Yamada, K. Kimura, A. Takahara, K.-H.Sonoda
  • Journal Title: Investigative Ophthalmology and Visual Science Volume: 53 Pages: 4998-5003
  • DOI: DOI:10.1167/iovs.12-10214
  • Peer Reviewed
• [Journal Article] Applications of Polymer Brushes to Structural Nano-Coatings (2011)
  • Author(s): M. Kobayashi, K. Mitamura, M. Terada, M. Kikuchi, D. Murakami, H. Yamaguchi, H. Arita, T. Ishikawa, Y. Terayama, H. Soejima, A. Takahara
  • Journal Title: Proceeding of IEEE NMDC 2011 Pages: 69-74
  • DOI: DOI:10.1109/NMDC.2011.6155315
  • Peer Reviewed
• [Journal Article] Precise Control of Surface Physicochemical Properties for Electrospun Fiber Mats by Surface-Initiated Radical Polymerization (2011)
  • Author(s): T. Yano, W.-O. Yah, H. Yamaguchi, Y. Terayama, M. Nishihara, M. Kobayashi, A. Takahara
  • Journal Title: Polym. J Volume: 43 Pages: 838-848
  • DOI: DOI:10.1038/pj.2011.80
  • Peer Reviewed
• [Journal Article] Characterization of SurfaceMicrostructures on Bio-based Polymer Film Fabricated with Nano-imprint Lithography by Synchrotron Radiation Small Angle X-rayScattering (2011)
  • Author(s): T, Shinohara, T. Shirahase, D. Murakami, T. Hoshino, M. Kikuchi, J.-I. Koike, H. Masunaga, H. Ogawa, A. Takahara
  • Journal Title: Mater. Sci. Eng Volume: 24 Pages: 012004
  • DOI: DOI:10.1088/1757-899X/24 /1/012004
  • Peer Reviewed
• [Journal Article] Three-Dimensional Analysis of Collagen Lamellae in the Anterior Stroma of the Human Cornea Visualized by Second Harmonic Generation Imaging Microscopy (2011)
  • Author(s): N. Morishige, Y.Takagi, T. Chikama, A. Takahara, T. Nishida
  • Journal Title: Investigative Ophthalmology and Visual Science Volume: 52 Pages: 911-915
  • DOI: DOI:10.1167/iovs.10-5657
  • Peer Reviewed
• [Journal Article] Preparation and Surface Characterization of Surface-modified Electrospun Poly(methyl methacrylate) Copolymer Nanofibers (2010)
  • Author(s): T. Yano, W.-O. Yah, H. Yamaguchi, Y. Terayama, M. Nishihara, M. Kobayashi, A. Takahara
  • Journal Title: Chem. Lett Volume: 39 Pages: 1110-111
  • DOI: DOI:10.1246/cl.2010.1110
  • Peer Reviewed
• [Journal Article] Synthesis, Characterization and Drug Release of Biocompatible/Biodegradable Non-toxic Poly(urethane urea)s Based on Poly(ε -caprolactone)s and Lysine-BasedDiisocyanate (2010)
  • Author(s): T. T. Reddy, A. Kano, A. Maruyama, A. Takahara
  • Journal Title: J. Biomater.Sci.,Polym.Ed Volume: 21 Pages: 1483-1502
  • DOI: DOI:10.1163/092050609X125188047947 85
  • Peer Reviewed
• [Journal Article] Novel Silver-Loaded Semi-Interpenetrating Polymer Network Gel Films with Antibacterial Activity (2009)
  • Author(s): T. T. Reddy, A. Kano, A. Maruyama, A. Takahara
  • Journal Title: J. Polym. Sci. Chem. Ed Volume: 47 Pages: 4950-4962
  • DOI: DOI:10.1002/pola.23546
  • Peer Reviewed
• [Journal Article] Simultaneous and sequential micro-porous semi-interpenetrating polymer network hydrogel films for drug delivery and wound dressing applications (2009)
  • Author(s): T. T. Reddy and A. Takahara
  • Journal Title: Polymer Volume: 50 Pages: 3537-3546
  • DOI: DOI:10.1016/j.polymer.2009.0
  • Peer Reviewed
• [Journal Article] Structure and Surface Properties of High-density Polyelectrolyte Brushes at the Interface ofAqueous Solution (2009)
  • Author(s): M. Kobayashi, H. Yamaguchi, Y. Terayama, Z. Wang, K. Ishihara, M. Hino, A. Takahara
  • Journal Title: Macromol. Symp Volume: 279 Pages: 79-87
  • DOI: DOI:10.1002/masy.200950513
  • Peer Reviewed
• [Journal Article] Preparation of Poly(vinylidene fluoride-co-trifluoroethylene) Film with a Hydrophilic Surface by Direct Surface-initiated Atom Transfer Radical Polymerization without Pretreatment (2009)
  • Author(s): T. Kimura, M. Kobayashi, M. Morita, A. Takahara
  • Journal Title: Chem. Lett Volume: 38(5) Pages: 446-447
  • DOI: DOI:10.1246/cl.2009.446
  • Peer Reviewed
• [Presentation] Water-surface interaction on polyelectrolyte brush surfaces (2013)
  • Author(s): A. Takahara
  • Organizer: Annual Meetingof American Adhesion Society
  • Place of Presentation: Dayton Beach, U.S.A.
  • Year and Date: 2013-03-03
• [Presentation] Design of Polyelectrolyte Brushes for High-Performance Nano-coatings (2012)
  • Author(s): A. Takahara
  • Organizer: The 2012 US-Japan Seminar on Polymer Synthesis
  • Place of Presentation: Santa Barbara, U.S.A.
  • Year and Date: 2012-12-02
• [Presentation] 高分子超薄膜の構造と物性 (2012)
  • Author(s): 高原 淳
  • Organizer: レオロジーイブニングセミナー
  • Place of Presentation: 出光会館(千葉県市原市)
  • Year and Date: 2012-11-09
• [Presentation] ソフトマテリアル界面の示す特異的な表面・界面物性と歯科材料分野への展開 (2012)
  • Author(s): 高原 淳
  • Organizer: 第60回日本歯科理工学会学術講演会
  • Place of Presentation: 九州大学医学部百年講堂 (福岡県福岡市)
  • Year and Date: 2012-10-13
• [Presentation] A superhydrophobic surface with low surface stickiness by self-assembly of fluoroalkyl phosphonic acid on a hierarchically micro/nanostructured alumina gel film (2012)
  • Author(s): W. Ma, Y. Higaki, H. Otsuka, A. Takahara
  • Organizer: The World Congress on Oleo Science & 29th ISFCongress (WCOS2012)
  • Place of Presentation: Arkas Sasebo(長崎県佐世保市)
  • Year and Date: 2012-10-03
• [Presentation] Wettability, Antifouling and Adhesion Behaviors of Immobilized Polyelectrolyte Brushes (2012)
  • Author(s): A. Takahara
  • Organizer: 2012 Japan-Taiwan Bilateral Polymer Symposium (JTBPS'12)
  • Place of Presentation: 西日本総合展示場(福岡県北九州市)
  • Year and Date: 2012-09-07
• [Presentation] ソフトインターフェースの精密設計と界面物性 (2012)
  • Author(s): 高原淳,小林元康
  • Organizer: 平成24年未踏科学サマー道場
  • Place of Presentation: 湘南国際村センター(神奈川県三浦郡葉山町)
  • Year and Date: 2012-08-17
• [Presentation] Control of Wettabilty and Friction by Immobilization of Polyelectrolyte Brushes with Bio-inspired Functional Groups (2012)
  • Author(s): A. Takahara
  • Organizer: Nanofair 2012
  • Place of Presentation: MARITIM Hotel (Dresden,Germany)
  • Year and Date: 2012-06-12
• [Presentation] Highly transparent and low hysteresis omniphobic surface by infusing a nano-textured alumina gel film with a perfluoropolyether liquid (2012)
  • Author(s): W. Ma, Y. Higaki, H. Otsuka, A. Takahara
  • Organizer: International Symposium on PolymerPhysics 2012(PP2012)
  • Place of Presentation: California Garden Hotel (Chengdu, China)
  • Year and Date: 2012-06-06
• [Presentation] Wettability, Antifouling and Adhesion Behaviors of Immobilized Polyelectrolyte Brushes (2012)
  • Author(s): A. Takahara
  • Organizer: International Symposium on Polymer Physics 2012(PP2012)
  • Place of Presentation: California Garden Hotel (Chengdu, China)
  • Year and Date: 2012-06-06
• [Presentation] 超親水性ポリマーブラシの精密材料設計に基づく環境に優しい防汚・潤滑・接着技術 (2012)
  • Author(s): 高原淳
  • Organizer: 第33回高分子同友会総合講演会
  • Place of Presentation: 化学会館ホール(東京都千代田区神田)
  • Year and Date: 2012-04-25
• [Presentation] Precise Design of Antifouling, 5.062 Intelligent Adhesion Surfaces through Polyelectrolyte Brush Immobilization (2012)
  • Author(s): A. Takahara
  • Organizer: Annual Meeting of American Adhesion Society
  • Place of Presentation: Dayton Beach, U.S.A.
  • Year and Date: 2012-03-03
• [Presentation] 高分子界面の精密設計による漏れ性,防汚性,潤滑性,接着性制御 (2012)
  • Author(s): 高原淳
  • Organizer: 平成24年度東海シンポジウム 高分子の更なる可能性を目指して
  • Place of Presentation: 名古屋国際会議場(名古屋市熱田区)
  • Year and Date: 2012-01-17
• [Presentation] Design of Environmentally Friendly Super Hydrophilic and Super Hydrophobic Polymer Surfaces (2011)
  • Author(s): A. Takahara, M. Kobayashi, M. Terada, H. Yamaguchi, M. Morita, I. Yamamoto
  • Organizer: The 12th Pacific Polymer Conference
  • Place of Presentation: The Shilla Hotel Jeju( Jeju Island, Korea)
  • Year and Date: 2011-11-14
• [Presentation] Precise and Non-destructive Characterization of 'Buried' Nano-structure by Scattering Technique (2011)
  • Author(s): T. Shinohara, T. Shirahase, D Murakami, T. Hoshino, M. Kikuchi, H. Masunaga, H. Ogawa, J.-I. Koike, M.Horigome, A. Takahara
  • Organizer: The 12th Pacific Polymer Conference
  • Place of Presentation: The Shilla Hotel Jeju( Jeju Island, Korea)
  • Year and Date: 2011-11-14
• [Presentation] Surface Modification of Stainless Steel by Adhesive Anionic Copolymer and Biocompatible Multilayer for Controlled Drug Release (2011)
  • Author(s): M. Inoue, H. Xu J. Nishida, M. Kobayashi, A. Takahara
  • Organizer: The 12th Pacific Polymer Conference
  • Place of Presentation: The Shilla Hotel Jeju( Jeju Island, Korea)
  • Year and Date: 2011-11-14
• [Presentation] Surface and Interface Characterization of Organic ThinFilms by Quantum Beam (2011)
  • Author(s): A. Takahara
  • Organizer: 15th International Conference on Thin Films(ICTF-15)
  • Place of Presentation: Kyoto TERRSA(京都府京都市南区)
  • Year and Date: 2011-11-10
• [Presentation] Non-destructive Characterization of 'Buried' Nano-structure in Polymer Thin Film by Small Angle X-ray Scattering (2011)
  • Author(s): T. Shinohara, T. Shirahase, D. Murakami, T. Hoshino, M. Kikuchi, H. Masunaga, H. Ogawa, J.-I. Koike, M. Horigome, A. Takahara
  • Organizer: The 3rd Asian Symposium on Advanced Materials(ASAM-3)
  • Place of Presentation: 九州大学筑紫キャンパス(福岡県春日市)
  • Year and Date: 2011-09-21
• [Presentation] Characterization of Molecular Aggregation Structure of Poly (vinyl alcohol) Nanofiber Fabricated by Electrospinning (2011)
  • Author(s): T. Yano, M. Kikuchi, T. Hoshino, N. Ohta, M. Kobayashi, A. Takahara
  • Organizer: The 3rd Asian Symposium on Advanced Materials (ASAM-3)
  • Place of Presentation: 九州大学筑紫キャンパス(福岡県春日市)
  • Year and Date: 2011-09-21
• [Presentation] Gelation of Polystyrene Copolymer Containing Catechol Groups in the Presence of Iron (III) Ions (2011)
  • Author(s): H. Xu,M. Kobayashi, J.Nishida, H.Otsuka, A. Takahara
  • Organizer: The 3rd Asian Symposium on Advanced Materials (ASAM-3)
  • Place of Presentation: 九州大学筑紫キャンパス(福岡県春日市)
  • Year and Date: 2011-09-21
• [Presentation] Applications of Surface Initiated ATRP to the Preparation of Polyelectrolyte Brushes for Wettability, Adhesion and Friction Control (2011)
  • Author(s): A. Takahara, Y. Terayama, T. Ishikawa, M. Terada, D. Murakami, M. Kikuchi, M. Kobayashi
  • Organizer: 242nd ACS National Meeting: 6th symposium on "Controlled/Living Radical Polymerization" (CRP), Denver
  • Place of Presentation: Denver, Colorado,U.S.A.
  • Year and Date: 2011-08-31
• [Presentation] Fabrication of Micro- and Nano-structures on Flexible Bio-based Polymer Films (2010)
  • Author(s): T. Shinohara, T. Shirahase, A. Takahara
  • Organizer: 2010 International Chemical Congress of Pacific Basin Societies
  • Place of Presentation: Kamehameha Halls II and III Convention Center(Hawaii, U.S.A.)
  • Year and Date: 2010-12-19
• [Presentation] Precise Control of Surface Physicochemical Properties for Electrospun Poly(methyl methacrylate) Derivative Fibers by Surface Initiated Radical Polymerization (2010)
  • Author(s): T. Yano, A. Takahara
  • Organizer: 2010 International ChemicalCongress of Pacific Basin Societies
  • Place of Presentation: Kamehameha Halls IIand III Convention Center(Hawaii, U.S.A.)
  • Year and Date: 2010-12-18
• [Presentation] ナノインプリント法により表面微細構造を賦与したポリ乳酸薄膜の顕微・散乱手法による精密構造解析 (2010)
  • Author(s): 篠原貴道,高原 淳
  • Organizer: 第19回ポリマー材料フォーラム
  • Place of Presentation: 名古屋国際会議場 (愛知県名古屋市)
  • Year and Date: 2010-12-03
• [Presentation] 交互吸着法によるポリアニオンとカチオン性ナノ粒子のステンレス基板上への積層とその表面・界面特性解析 (2010)
  • Author(s): 井上満美子,高原 淳
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学(北海道札幌市)
  • Year and Date: 2010-09-16
• [Presentation] 表面開始ATRPを利用した電界紡糸ファイバーの構造・物性制御 (2010)
  • Author(s): 矢野貴大,高原 淳
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学(北海道札幌市)
  • Year and Date: 2010-09-16
• [Presentation] ソフト界面の精密構造制御とその特性解析 (2010)
  • Author(s): 高原 淳,小林元康
  • Organizer: 第 59回高分子討論会
  • Place of Presentation: 北海道大学(北海道札幌市)
  • Year and Date: 2010-09-15
• [Presentation] ナノインプリント法によるポリ乳酸フィルムへの表面微細周期構造の形成と散乱法・顕微手法を用いた精密構造評価 (2010)
  • Author(s): 篠原貴道,高原 淳
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学(北海道札幌市)
  • Year and Date: 2010-09-15
• [Presentation] Chain Conformation of Zwitter Ionic Polymer in Solution and Concentrated Brush State (2010)
  • Author(s): A.Takahara
  • Organizer: AOFSRR2010
  • Place of Presentation: Pohang工科大学 (Korea)
  • Year and Date: 2010-07-07
• [Presentation] Interfacial Properties and Dynamics of Polymer Brushes (2010)
  • Author(s): A. Takahara
  • Organizer: ISPAC2010
  • Place of Presentation: Pohang工科大学(Korea)
  • Year and Date: 2010-05-31
• [Presentation] 電界紡糸ファイバーの表面化学修飾とその特性評価 (2010)
  • Author(s): 矢野貴大,小林元康,高原 淳
  • Organizer: 第59回高分子年次大会
  • Place of Presentation: パシフィコ横浜 (神奈川県横浜市)
  • Year and Date: 2010-05-28
• [Presentation] ナノインプリント法によるバイオベースポリマーブレンドフィルムへの表面微細構造形成と細胞培養挙動 (2010)
  • Author(s): 篠原貴道,白波瀬朋子,高原 淳
  • Organizer: 第59回高分子年次大会
  • Place of Presentation: パシフィコ横浜 (神奈川県横浜市)
  • Year and Date: 2010-05-28
• [Presentation] 電界紡糸ポリメタクリル酸エステル誘導体ナノファイバーの表面改質と表面機能特性評価 (2010)
  • Author(s): 西原正通,小林元康,高原 淳
  • Organizer: 第45回九大生体材料・力学研究会
  • Place of Presentation: 九州大学西新プラザ(福岡県福岡市)
  • Year and Date: 2010-02-03
• [Presentation] 電界紡糸法を用いた PMMA誘導体ナノファイバーからの表面開始重合と濡れ性評価 (2009)
  • Author(s): 西原正通,小林元康,高原 淳
  • Organizer: 第5回物質合成シンポジウム
  • Place of Presentation: 京都大学宇治キャンパス・おうばくプラザ内「きはだホール」(京都府宇治市)
  • Year and Date: 2009-11-19
• [Presentation] Preparation and surface modification of electro-spun PMMA derivative nano fiber (2009)
  • Author(s): Masamichi Nishihara, Motoyasu Kobayashi, Atsushi Takahara
  • Organizer: International Symposium on Nanobio-Interfaces Related to Molecular Mobility(ISNI2009)
  • Place of Presentation: 東京大学(東京都文京区)
  • Year and Date: 2009-11-09
• [Presentation] 電界紡糸法を用いたポリメタクリル酸メチル誘導体ナノファイバーの調製とその表面化学修飾 (2009)
  • Author(s): 矢野貴大,小林元康,高原淳
  • Organizer: 第58回高分子討論会
  • Place of Presentation: 熊本大学工学部黒髪キャンパス(熊本県熊本市)
  • Year and Date: 2009-09-17
• [Presentation] バイオインターフェースのためのソフトマテリアルの構造制御技術 (2009)
  • Author(s): 高原 淳、小林元康
  • Organizer: 生体医工学会九州支部講演会
  • Place of Presentation: 九州大学馬出キャンパス(福岡県福岡市)
  • Year and Date: 2009-03-07
• [Presentation] Design of Soft Interfaces through Biomimetic Approach (2009)
  • Author(s): A. Takahara, M. Kobayashi
  • Organizer: 9th International Symposium on Biomimetic Materials Processing(BMMP-9)
  • Place of Presentation: 名古屋大学(愛知県名古屋市)
  • Year and Date: 2009-01-20
• [Presentation] 表面ナノ形態と表面化学組成制御による材料表面の親・疎水性制御,創造機能化学 (2009)
  • Author(s): 高原淳、小林元康
  • Organizer: 第116委員会(平成20年度1月期研究調査報告)
  • Place of Presentation: 学士会館(東京都千代田区)
  • Year and Date: 2009-01-19
• [Book] Adhesion and Tribological Characteristics of Ion-Containing Polymer Brushes Prepared by Controlled Radical Polymerization," Chapter 2 in H. Zeng Eds. "Polymer Adhesion, Friction, and Lubrication, Wiley (2013)
  • Author(s): M. Kobayashi, T. Ishikawa, A. Takahara
  • Total Pages: 59-82
• [Book] ソフトマター～分子設計・キャラクタリゼーションから機能性材料まで～ (2009)
  • Author(s): 高原 淳、栗原 和枝、前田瑞夫 編
  • Total Pages: 3-18, 191-202, 273
  • Publisher: 丸善
• [Remarks]
  • URL: http://takahara/ifoc.kyushu-u.ac.jp