2015 Fiscal Year Final Research Report
Development of Catalytic reactions Involving Activation of Unreactive Bonds
Project Area | Molecule Activation Directed toward Straightforward Synthesis |
Project/Area Number |
22105002
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Research Category |
Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
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Allocation Type | Single-year Grants |
Review Section |
Science and Engineering
|
Research Institution | Osaka University |
Principal Investigator |
CHATANI Naoto 大阪大学, 工学(系)研究科(研究院), 教授 (30171953)
|
Co-Investigator(Renkei-kenkyūsha) |
FUKUMOTO Yoshiya 大阪大学, 大学院工学研究科, 准教授 (50273595)
TOBISU Mamoru 大阪大学, 大学院工学研究科, 准教授 (60403143)
|
Project Period (FY) |
2010-04-01 – 2016-03-31
|
Keywords | 炭素-水素結合活性化 / 炭素-酸素結合活性化 / 炭素-窒素結合活性化 / 炭素-リン結合活性化 / 炭素-硫黄結合活性化 |
Outline of Final Research Achievements |
A new type of C-H functionalization reactions utilizing an N,N-bidentate chelation system has been developed. It was found that Ni/8-aminoquinoline directing group is reliable system for developing the Ni-catalyzed C-H functionalizations. In addition, some catalytic reactions using ruthenium and rhodium chlorides have been successfully developed. After the examination of the effect of NHC ligands on the efficiency of C-O bond activation, it was found that ICy shows a high catalytic activity. The use of ICy led to the development of new reactions, which cannot achieve by using conventional common ligands.
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Free Research Field |
有機合成化学
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