1989 Fiscal Year Annual Research Report

重合反応の精密制御とその応用に関する総合的研究

Research Project

Project/Area Number	01303008
Research Institution	The University of Tokyo
Principal Investigator	井上祥平東京大学, 工学部, 教授 (20010762)
Co-Investigator(Kenkyū-buntansha)	松田実東北大学, 非水溶液化学研究所, 教授 (90006297) 福田清成埼玉大学, 理学部, 教授 (80008789) 横田健二名古屋工業大学, 工学部, 教授 (30024201) 岡本佳男大阪大学, 基礎工学部, 助教授 (60029501) 東村敏延京都大学, 工学部, 教授 (20025860)
Keywords	重合反応 / リビング重合 / ブロック共重合体 / 光学活性高分子 / 共重合 / 二分子膜 / LB膜 / 薄膜
Research Abstract	重合反応の制御は,高性能・高機能の高分子材料の分子設計にとって最も基本的で重要な課題である。これについて,種々の重合反応の共通的,統一的理解に立った進展をはかることが強く望まれる。本研究は,この見地から高分子材料の分子設計の一般的原理となり得るような重合反応の精密制御の方法を確立しその応用への基礎をきずくことを目的とし,具体的には1)分子量の制御,2)立体化学の制御,3)共重合配列の制御,4)集合状態の制御の各分野について,相互に関連させた有機的,総合的な研究を行った。本年度の研究の結果,以下に概略を記すように種々の重合反応の制御が可能となり,大きい成果が得られた。1.分子量の制御とその応用:リビングカチオン重合によるビニルポリマ-の精密制御。アニオンリビング重合による反応性高分子の分子量制御。リビング配位重合によるポリオレフィンの分子量制御。ポルフィリン錯体による開環,付加重合の制御:これらによるブロツクコポリマ-,末端完能性ポリマ-の合成。2.立体化学の制御とその応用:コンホメ-ションに由来する光学活性ポリマ-の合成と応用。立体制御された多糖の合成とその生理活性化。包接重合による立体化学の制御。3.共重合配列の制御とその応用:金属塩を用いるラジカル共重合の制御。高分子反応による交互および周期コポリマ-の合成と物性の解明。4.集合状態の制御とその応用:層状組織体における単量体分子の配列と重合反応の制御。2分子膜の分子集合状態による重合制御。導電性高分子の超ミクロ構造制御。高分子LB膜の調整と光誘起電子移動反応の実現。固相重付加反応による高結晶性共役高分子薄膜の合成。これらは来年度にさらに総合的に研究を展開するための基礎となるものである。

Research Products

(61 results)

All Other

All Publications (61 results)

[Publications] 渡辺喜彦、相田貞三、井上祥平: "Novel Visible Light-Mediated Living and Immortal Polymerizations of Epoxides with Zine Complexes of N-Substituted Porphyrins." Macromolecules. 23. (1990)
[Publications] 杉本裕、相田貞三、井上祥平: "Ring-Opening Polymezizations of Lactone and Epoxide Initiated with Aluminum Complexes of Substituted Tetraphenylporphyrins.Molecular Design of Highly Active Initiators." Macromolecules. 23. (1990)
[Publications] 相田貞三、川口健一、井上祥平: "Zinc N-Substituted Porphyrins as Novel Initiators for the Living and Immortal Polymerizations of Episulfide." Macromolecules. 23. (1990)
[Publications] 東村敏延: "リビングカチオン重合" 高分子論文集. 46. 189-201 (1989)
[Publications] 東村敏延: "Living Cationic Polymerization of Vinyl Monomers:Control of Propagating Species with Added Bases" Frontiers of Macromolecular Science. 67-72 (1989)
[Publications] 東村敏延: "Carbocationic Polymerization:Vinyl Ethers" Comprehensive Polymer Science(Vol.3,PartI). 3. 673-696 (1989)
[Publications] 東村敏延: "Design and Initiators of Living Cationic Polymerization of Vinyl Monomers" Makromoleculaire Chemie,Macromolecular Symposium. (1990)
[Publications] 東村敏延: "Living Cationic Polymerization of Sryrene by the Methanesulfonic Acid/Tin Tetrach,oride Initiating System in the Presence of Tetra-n-butylammonium Chloride" Polymer Bulletin. (1990)
[Publications] Katsuhikko Takenaka: "Polymerization of Monomers Containing Functional Silyl Groups 6.Anionic Polymerization of 2-(Trialkoxysilyl)-1,3-butadiene" Macromolecules. 22. 1563-1567 (1989)
[Publications] Ken Suzuki: "Protection and polymerization of Functional Monomers 12.Synthesis of Well-Defined Poly(4-aminostryrene)by Means of Anionic Living Polymerization of 4-(N,N-Bis(trimethylsilyl)amino)styrene" Macromolecules. 22. 2607-2611 (1989)
[Publications] Jae-Suk Lee: "Polymerization of Monomers Containing Functional Silyl Groups.7.Porous Membranes with Controlled Microstructures" Macromolecules. 22. 2602-2606 (1989)
[Publications] Ken Suzuki: "Protection and polymerization of Functional monomers,14 Anionic living polymerization of 4-〔N.N-bis(trimethylsilyl)aminomethyl〕styrene and 4-[2-〔N.N-bis(trimethylsilyl)amino〕ethyl}styrene" Makromol.Chem. 190. 2893-2901 (1989)
[Publications] Yoshiharu Doi: "Synthesis and structure of a "living"copolymer of propylene and 1,5-hexadien" Makromol.Chem. 190. 643-651 (1989)
[Publications] 土肥義治: "可溶性バナジウム触媒によるジオレフィンの重合" 高分子論文集. 46. 215-222 (1989)
[Publications] Yoshio Okamoto: "Chromatographic Optical Resolution by Optically Active poly(diphenyl-2-pyridylmethyl methacrylate)with a Highly One-Handed Helical Structure" Polymer Journal. 21. 439-445 (1989)
[Publications] Yoshio Okamoto: "Asymmetric polymerization of N,N-Disubstituted Acrylamides" Polymer Journal. 21. 543-549 (1989)
[Publications] Yoshio Okamoto: "Stereomutation of Optically Active Poly(diphenyl-2-pyridylmethyl methacrylate)" Journal of the American Chemical Society. 111. 5952-5954 (1989)
[Publications] Haruhiko Mohri: "Helix-Sense-Selective Polymerization of 2-(6-Methyl-phyridyl)diphenylmethyl Methacrylate" Polymer Journal. 21. 719-724 (1989)
[Publications] Tamaki Nakano: "Crystal Structure of Methyl Methacrylate Dimer.Revisad meso/racemo Assignment for the Dimer" Polymer Journal. 21. 935-939 (1989)
[Publications] Yoshio Okamoto: "Asymmetric Polymerization of Optically Active Phenyl-2-phyridyl-m-tolylmethyl Methacrylate and Stereomutation of the Polymer" Journal of Polymer science.
[Publications] K.Hatanaka,T.Hirobe,T.Yoshida.M.Yamanaka.T.Uryu: "Synthesis and Sulfation of Branched Dextrans" Polymer J.
[Publications] M.Ogawa,K.Hatanaka,t.Uryu: "Synthesis of a Novel Cellulose-Type Hexopyranan 6-Deoxy-(1→4)-α-L-Talopyranan by Selective Ring-Opening Polymerizable of 1,4-Anhydro Sugar Derivatives" J.Am.Chem.Soc.
[Publications] K.Hatanaka,Y.Yoshida,T.Yoshida,T.Uryu: "Synthesis of Polymerizabe Anhydro Deoxyribose Derivatives" Chem.Lett.
[Publications] Hiromori TSUTSUMI,Mikiji MIYATA<Kiichi TAKEMOTO: "Inclusion polymerization of cyclic diene monomers in deoxycholic acid canals" Angewandte Makromolekulare Chemie. 165. 109-123 (1989)
[Publications] Hiromori TSUTSUMI,Ken OKANISHI,Mikiji MIYATA,Kiichi TAKEMOTO: "Dehydrochlorination of head-to-tail,1,4-trans poly(1-chlorobutadiene)prepared by inclusion polymerization in deoxycholic acid canals" J.Macromolecular Science-chemistry A. 26. 1335-1345 (1989)
[Publications] K.Miki,A.Masui,N.Kasai,M.Miyata,W.Goonewardena,M.shibakami,K.Takemoto: "Structure of a 2:1 addition compound of methyl deoxycholte with methanol" Acta Crystallographica. C45. 79-83 (1989)
[Publications] Y.Gotoh: "Stereoregulation in the Alternation Copolymerization of Methyl Methacrylate with Styrene in the presence of Metal Halide" Pacific Polymer Preprints. 1. 395-396 (1989)
[Publications] K.Sato: "Polymerization of Coordinated Monomer.XX.MNDO Calculation and H-NMR Spectroscopy on the Binary Molecular Complex Composed of Methacrylate and Boron Trichloride" Journal of Polymer Science,Polymer Chemistry Ed.,投稿準備中.
[Publications] 後藤八重子: "金属塩を用いるメタクリル酸メチル-スチレン交互共重合系のα-パラメ-タとテトラドシ-ケンス" 高分子学会予稿集. 38. 1320-1322 (1989)
[Publications] 平林忠道・山内幸二、横田健二: "Synthesis of Sequence-Ordered Copolymer.Symthesic of Ethylene-Methyl Methacrylate Alternating Copolymer by a Polymer Reaction" Macromolecules. 23. (1990)
[Publications] 平林忠道・山内幸二、横田健二: "Alternating Gepolymers from Allyl Chloride and Their Pllimer Reactions" 投稿準備中.
[Publications] 平林忠道・山内幸二、横田健二: "Alternating Gepolymers from Allyl Trimethylsilyl Ether and Their Polymer Reactions"
[Publications] 平林忠道・森泰彦、横田健二: "Synthesis of Echylene-Vinyl Alcohol and Ethylene-Vinyl Acetate Alternating copolymevs"
[Publications] 平林忠道・山内幸二、横田健二: "Polymer Reactions of Some Alternating and Periodic Copolymers"
[Publications] K.Seki,H.Nakahara.K.Fukuda.et al.: "Photopolymerization of Long-Chain Diacetylene Monocarboxylic Acid in Langmuir-Blodgett Films Studies by UV Photoelectron Spectroscopy and X-ray Absorption Near-edge Structure." Thin Solid Filsm. 179. 15-20 (1989)
[Publications] H.Niino,Y.Kawabata,W.Tagaki.H.Nakahara.K.Fukuda.et al.: "Photopolymerization in a Langmuir-Blodgett Film of an Amphiphilic Cyclodextrin Derivative Containing a Diacetylene Group." Thin Solid Filsm. 179. 53-57 (1989)
[Publications] K.Fukuda,Y.Shibasaki,H.Nakahara.and H.Endo: "Control of Polymerizations and Polymer Structures through the Molecular Orientation of Amphiphilic Monomers in Langmuir-Blodgett Films" Thin Solid Filsm. 179. 103-107 (1989)
[Publications] 福田清成、中原弘雄: "分子の配列と制御:LB膜(機能性有機超薄膜)" 化学総説. 5. 75-90 (1989)
[Publications] 福田清成、柴崎芳夫、中原弘雄: "LB膜における分子配列と化学反応の制御" 油化学. 39(3). (1990)
[Publications] J-M.Kim: "Stabilization of a Phosphote Bilayer in Organic Media by Complixation with Ca^<2+> Ion" chemistry Lettes. 959-962 (1989)
[Publications] T.Kumitake: "Polymerization and Membran Cloacteristics of Aqueous Bitayers of Glutamate-Based Dabble-Clain Ammonium Amphiptile" Macromolecules. 22. 3544-3550 (1989)
[Publications] Takeo Shimidzu: "Derivatization of Conducting polymers with Functional Molecules Directed via Moeleclar structural control toward a Molecular Device" Reactive Polymers. 11. 177-189 (1989)
[Publications] Takeo Shimidzu.et al: "Multi-mode Signal Transducer and 3-D Fabrication of Conducting Polymers" MRS International Meeting on Advanced Materials. 12. 261-266 (1989)
[Publications] Takeo Shimidzu.et al: "Ultra-anisotropic Conducting Polymer LB Multilayer" MRS International Meeting on Advanced Materials. 12. 237-240 (1989)
[Publications] Masanori Ando,et al: "Syntheses of _Conducting Polymer Langmuir-Blodgett" Thin Solid Films. 179. 225-231 (1989)
[Publications] Akira Ohtari,et al: "Effective Doping of Polymer Anion during Chemical Polymerization of Pycrole using Fe(OH)_3 Oxidant" Bull.Chem.Soc.Japan. 62. 234-238 (1989)
[Publications] Hiroshi Segawa,et al: "A novel Photo-sensitized Polymerization of Pyrrole" J.Chem.Soc..Chem.Commun.,. 1989. 132-133 (1989)
[Publications] T.Murakata: "Psreading Behaviors of Polymer haviorss of Polymer Having Aromatic cheomophores in a Barium Stearate Monolayer andPreparation of the Polymer Langmuir-Blodgett Films" Macromolecules. 22. 2706-2709 (1989)
[Publications] A.Watanabe: "Comparative Study of Redox Reactions of Polyaniline Films inAqueous and Nonaqueous Solutions" Macromolecules. 22. 3323-3327 (1989)
[Publications] T.Miyashita: "Characterization of an N-Octadecylacrylamide LangmuirBlodgett Film for Application as an Electron Beam Resist" thinSolid Films. 168. L47-L49 (1989)
[Publications] T.Miyashita: "Studies on Photochemical Behavior of Amphiphilic Polymers Consisting of Stryrenesulfonate,Butyl Methacrylate,and Vinylcarbazole Probe in Aqueous and Nonaqueous Solutions" Polymer Journal. 21. 789-794 (1989)
[Publications] 小林英一: "固相重付加による結晶性高分子の合成:可逆的相転移を用いる光記録材料" 高分子. 38. 836-840 (1989)
[Publications] 八木高: "ベンゼンジチオ-ルとジビニルベンゼンの共重合体の特性(1):共重合体の合成" 材料技術. 7. 16-24 (1989)
[Publications] 小林英一: "チオフェジチオ-ルとジエチニルチオフェンの重付加体の合成とミクロ構造" 高分子論文集. 46. 203-208 (1989)
[Publications] T.Ohashi: "Effect of photolysis wavelength on the addition polymerization of 1,4-benzenedithiod to 1,4-diethynylbonzene in solid state" J.Polymer Sci.Part C.27. 247-252 (1989)
[Publications] E.Kobayashi: "Novel conjugated polymer containing anthracene backbone:Competitive addition polymerization of dithiol monomers to diethynyl monomers and relative reactivity" polymer J.22. 146-152 (1990.2)
[Publications] J.Jiany: "Novel conjugated polymer containing anthracene backbone:The microstructure of polymer of 1,4-benzenedithiol voith 9,10-diethynylanthracene and isomerization of the polymer and model compounds" Polymer J.22. 274-282 (1990.2)
[Publications] Seiidhi Nakahama and Akira Hirao: "Progress Polymer Science,Vol.15 Protection and Polymerization of Functional Monomers:Anionic Living Polymerization of Protected Monomerss" Pergamon Press plc, 299-335 (1990)
[Publications] Toshiyuji Uryu(共著): "Models of Bipolymers by Ring-Opening Polymerization" CRC Press,Boco Raton,U.S.A., 100pages (1990)
[Publications] T.Uryu,K.Hatanaka,T.Yoshida,K.Matsuzaki,Y.Kaneko,T.mimura,H.Nakashima,O.Yoshida,N.Yamamoto(分担): "Cellulose Utilization" Elsevier,London., 8pages (1989)
[Publications] 井上祥平、国武豊喜、清水剛夫(共著): "(高分子学会編)高分子新素材便覧" 丸善, 634 (1989)

1989 Fiscal Year Annual Research Report

重合反応の精密制御とその応用に関する総合的研究

Principal Investigator

井上 祥平 東京大学, 工学部, 教授 (20010762)

Research Products

[Publications] 渡辺喜彦、相田貞三、井上祥平: "Novel Visible Light-Mediated Living and Immortal Polymerizations of Epoxides with Zine Complexes of N-Substituted Porphyrins." Macromolecules. 23. (1990)

[Publications] 杉本裕、相田貞三、井上祥平: "Ring-Opening Polymezizations of Lactone and Epoxide Initiated with Aluminum Complexes of Substituted Tetraphenylporphyrins.Molecular Design of Highly Active Initiators." Macromolecules. 23. (1990)

[Publications] 相田貞三、川口健一、井上祥平: "Zinc N-Substituted Porphyrins as Novel Initiators for the Living and Immortal Polymerizations of Episulfide." Macromolecules. 23. (1990)

[Publications] 東村敏延: "リビングカチオン重合" 高分子論文集. 46. 189-201 (1989)

[Publications] 東村敏延: "Living Cationic Polymerization of Vinyl Monomers:Control of Propagating Species with Added Bases" Frontiers of Macromolecular Science. 67-72 (1989)

[Publications] 東村敏延: "Carbocationic Polymerization:Vinyl Ethers" Comprehensive Polymer Science(Vol.3,PartI). 3. 673-696 (1989)

[Publications] 東村敏延: "Design and Initiators of Living Cationic Polymerization of Vinyl Monomers" Makromoleculaire Chemie,Macromolecular Symposium. (1990)

[Publications] 東村敏延: "Living Cationic Polymerization of Sryrene by the Methanesulfonic Acid/Tin Tetrach,oride Initiating System in the Presence of Tetra-n-butylammonium Chloride" Polymer Bulletin. (1990)

[Publications] Katsuhikko Takenaka: "Polymerization of Monomers Containing Functional Silyl Groups 6.Anionic Polymerization of 2-(Trialkoxysilyl)-1,3-butadiene" Macromolecules. 22. 1563-1567 (1989)

[Publications] Ken Suzuki: "Protection and polymerization of Functional Monomers 12.Synthesis of Well-Defined Poly(4-aminostryrene)by Means of Anionic Living Polymerization of 4-(N,N-Bis(trimethylsilyl)amino)styrene" Macromolecules. 22. 2607-2611 (1989)

[Publications] Jae-Suk Lee: "Polymerization of Monomers Containing Functional Silyl Groups.7.Porous Membranes with Controlled Microstructures" Macromolecules. 22. 2602-2606 (1989)

[Publications] Ken Suzuki: "Protection and polymerization of Functional monomers,14 Anionic living polymerization of 4-〔N.N-bis(trimethylsilyl)aminomethyl〕styrene and 4-[2-〔N.N-bis(trimethylsilyl)amino〕ethyl}styrene" Makromol.Chem. 190. 2893-2901 (1989)

[Publications] Yoshiharu Doi: "Synthesis and structure of a "living"copolymer of propylene and 1,5-hexadien" Makromol.Chem. 190. 643-651 (1989)

[Publications] 土肥義治: "可溶性バナジウム触媒によるジオレフィンの重合" 高分子論文集. 46. 215-222 (1989)

[Publications] Yoshio Okamoto: "Chromatographic Optical Resolution by Optically Active poly(diphenyl-2-pyridylmethyl methacrylate)with a Highly One-Handed Helical Structure" Polymer Journal. 21. 439-445 (1989)

[Publications] Yoshio Okamoto: "Asymmetric polymerization of N,N-Disubstituted Acrylamides" Polymer Journal. 21. 543-549 (1989)

[Publications] Yoshio Okamoto: "Stereomutation of Optically Active Poly(diphenyl-2-pyridylmethyl methacrylate)" Journal of the American Chemical Society. 111. 5952-5954 (1989)

[Publications] Haruhiko Mohri: "Helix-Sense-Selective Polymerization of 2-(6-Methyl-phyridyl)diphenylmethyl Methacrylate" Polymer Journal. 21. 719-724 (1989)

[Publications] Tamaki Nakano: "Crystal Structure of Methyl Methacrylate Dimer.Revisad meso/racemo Assignment for the Dimer" Polymer Journal. 21. 935-939 (1989)

[Publications] Yoshio Okamoto: "Asymmetric Polymerization of Optically Active Phenyl-2-phyridyl-m-tolylmethyl Methacrylate and Stereomutation of the Polymer" Journal of Polymer science.

[Publications] K.Hatanaka,T.Hirobe,T.Yoshida.M.Yamanaka.T.Uryu: "Synthesis and Sulfation of Branched Dextrans" Polymer J.

[Publications] M.Ogawa,K.Hatanaka,t.Uryu: "Synthesis of a Novel Cellulose-Type Hexopyranan 6-Deoxy-(1→4)-α-L-Talopyranan by Selective Ring-Opening Polymerizable of 1,4-Anhydro Sugar Derivatives" J.Am.Chem.Soc.

[Publications] K.Hatanaka,Y.Yoshida,T.Yoshida,T.Uryu: "Synthesis of Polymerizabe Anhydro Deoxyribose Derivatives" Chem.Lett.

[Publications] Hiromori TSUTSUMI,Mikiji MIYATA<Kiichi TAKEMOTO: "Inclusion polymerization of cyclic diene monomers in deoxycholic acid canals" Angewandte Makromolekulare Chemie. 165. 109-123 (1989)

[Publications] Hiromori TSUTSUMI,Ken OKANISHI,Mikiji MIYATA,Kiichi TAKEMOTO: "Dehydrochlorination of head-to-tail,1,4-trans poly(1-chlorobutadiene)prepared by inclusion polymerization in deoxycholic acid canals" J.Macromolecular Science-chemistry A. 26. 1335-1345 (1989)

[Publications] K.Miki,A.Masui,N.Kasai,M.Miyata,W.Goonewardena,M.shibakami,K.Takemoto: "Structure of a 2:1 addition compound of methyl deoxycholte with methanol" Acta Crystallographica. C45. 79-83 (1989)

[Publications] Y.Gotoh: "Stereoregulation in the Alternation Copolymerization of Methyl Methacrylate with Styrene in the presence of Metal Halide" Pacific Polymer Preprints. 1. 395-396 (1989)

[Publications] K.Sato: "Polymerization of Coordinated Monomer.XX.MNDO Calculation and H-NMR Spectroscopy on the Binary Molecular Complex Composed of Methacrylate and Boron Trichloride" Journal of Polymer Science,Polymer Chemistry Ed.,投稿準備中.

[Publications] 後藤八重子: "金属塩を用いるメタクリル酸メチル-スチレン交互共重合系のα-パラメ-タとテトラドシ-ケンス" 高分子学会予稿集. 38. 1320-1322 (1989)

[Publications] 平林忠道・山内幸二、横田健二: "Synthesis of Sequence-Ordered Copolymer.Symthesic of Ethylene-Methyl Methacrylate Alternating Copolymer by a Polymer Reaction" Macromolecules. 23. (1990)

[Publications] 平林忠道・山内幸二、横田健二: "Alternating Gepolymers from Allyl Chloride and Their Pllimer Reactions" 投稿準備中.

[Publications] 平林忠道・山内幸二、横田健二: "Alternating Gepolymers from Allyl Trimethylsilyl Ether and Their Polymer Reactions"

[Publications] 平林忠道・森泰彦、横田健二: "Synthesis of Echylene-Vinyl Alcohol and Ethylene-Vinyl Acetate Alternating copolymevs"

[Publications] 平林忠道・山内幸二、横田健二: "Polymer Reactions of Some Alternating and Periodic Copolymers"

[Publications] K.Seki,H.Nakahara.K.Fukuda.et al.: "Photopolymerization of Long-Chain Diacetylene Monocarboxylic Acid in Langmuir-Blodgett Films Studies by UV Photoelectron Spectroscopy and X-ray Absorption Near-edge Structure." Thin Solid Filsm. 179. 15-20 (1989)

[Publications] H.Niino,Y.Kawabata,W.Tagaki.H.Nakahara.K.Fukuda.et al.: "Photopolymerization in a Langmuir-Blodgett Film of an Amphiphilic Cyclodextrin Derivative Containing a Diacetylene Group." Thin Solid Filsm. 179. 53-57 (1989)

[Publications] K.Fukuda,Y.Shibasaki,H.Nakahara.and H.Endo: "Control of Polymerizations and Polymer Structures through the Molecular Orientation of Amphiphilic Monomers in Langmuir-Blodgett Films" Thin Solid Filsm. 179. 103-107 (1989)

[Publications] 福田清成、中原弘雄: "分子の配列と制御:LB膜(機能性有機超薄膜)" 化学総説. 5. 75-90 (1989)

[Publications] 福田清成、柴崎芳夫、中原弘雄: "LB膜における分子配列と化学反応の制御" 油化学. 39(3). (1990)

[Publications] J-M.Kim: "Stabilization of a Phosphote Bilayer in Organic Media by Complixation with Ca^<2+> Ion" chemistry Lettes. 959-962 (1989)

[Publications] T.Kumitake: "Polymerization and Membran Cloacteristics of Aqueous Bitayers of Glutamate-Based Dabble-Clain Ammonium Amphiptile" Macromolecules. 22. 3544-3550 (1989)

[Publications] Takeo Shimidzu: "Derivatization of Conducting polymers with Functional Molecules Directed via Moeleclar structural control toward a Molecular Device" Reactive Polymers. 11. 177-189 (1989)

[Publications] Takeo Shimidzu.et al: "Multi-mode Signal Transducer and 3-D Fabrication of Conducting Polymers" MRS International Meeting on Advanced Materials. 12. 261-266 (1989)

[Publications] Takeo Shimidzu.et al: "Ultra-anisotropic Conducting Polymer LB Multilayer" MRS International Meeting on Advanced Materials. 12. 237-240 (1989)

[Publications] Masanori Ando,et al: "Syntheses of _Conducting Polymer Langmuir-Blodgett" Thin Solid Films. 179. 225-231 (1989)

[Publications] Akira Ohtari,et al: "Effective Doping of Polymer Anion during Chemical Polymerization of Pycrole using Fe(OH)_3 Oxidant" Bull.Chem.Soc.Japan. 62. 234-238 (1989)

[Publications] Hiroshi Segawa,et al: "A novel Photo-sensitized Polymerization of Pyrrole" J.Chem.Soc..Chem.Commun.,. 1989. 132-133 (1989)

[Publications] T.Murakata: "Psreading Behaviors of Polymer haviorss of Polymer Having Aromatic cheomophores in a Barium Stearate Monolayer andPreparation of the Polymer Langmuir-Blodgett Films" Macromolecules. 22. 2706-2709 (1989)

[Publications] A.Watanabe: "Comparative Study of Redox Reactions of Polyaniline Films inAqueous and Nonaqueous Solutions" Macromolecules. 22. 3323-3327 (1989)

[Publications] T.Miyashita: "Characterization of an N-Octadecylacrylamide LangmuirBlodgett Film for Application as an Electron Beam Resist" thinSolid Films. 168. L47-L49 (1989)

[Publications] T.Miyashita: "Studies on Photochemical Behavior of Amphiphilic Polymers Consisting of Stryrenesulfonate,Butyl Methacrylate,and Vinylcarbazole Probe in Aqueous and Nonaqueous Solutions" Polymer Journal. 21. 789-794 (1989)

[Publications] 小林英一: "固相重付加による結晶性高分子の合成:可逆的相転移を用いる光記録材料" 高分子. 38. 836-840 (1989)

[Publications] 八木高: "ベンゼンジチオ-ルとジビニルベンゼンの共重合体の特性(1):共重合体の合成" 材料技術. 7. 16-24 (1989)

[Publications] 小林英一: "チオフェジチオ-ルとジエチニルチオフェンの重付加体の合成とミクロ構造" 高分子論文集. 46. 203-208 (1989)

[Publications] T.Ohashi: "Effect of photolysis wavelength on the addition polymerization of 1,4-benzenedithiod to 1,4-diethynylbonzene in solid state" J.Polymer Sci.Part C.27. 247-252 (1989)

[Publications] E.Kobayashi: "Novel conjugated polymer containing anthracene backbone:Competitive addition polymerization of dithiol monomers to diethynyl monomers and relative reactivity" polymer J.22. 146-152 (1990.2)

[Publications] J.Jiany: "Novel conjugated polymer containing anthracene backbone:The microstructure of polymer of 1,4-benzenedithiol voith 9,10-diethynylanthracene and isomerization of the polymer and model compounds" Polymer J.22. 274-282 (1990.2)

[Publications] Seiidhi Nakahama and Akira Hirao: "Progress Polymer Science,Vol.15 Protection and Polymerization of Functional Monomers:Anionic Living Polymerization of Protected Monomerss" Pergamon Press plc, 299-335 (1990)

[Publications] Toshiyuji Uryu(共著): "Models of Bipolymers by Ring-Opening Polymerization" CRC Press,Boco Raton,U.S.A., 100pages (1990)

[Publications] T.Uryu,K.Hatanaka,T.Yoshida,K.Matsuzaki,Y.Kaneko,T.mimura,H.Nakashima,O.Yoshida,N.Yamamoto(分担): "Cellulose Utilization" Elsevier,London., 8pages (1989)

[Publications] 井上祥平、国武豊喜、清水剛夫(共著): "(高分子学会編)高分子新素材便覧" 丸善, 634 (1989)

井上祥平東京大学, 工学部, 教授 (20010762)