1989 Fiscal Year Annual Research Report

新規機能材料の合成と応用開発

Research Project

Project/Area Number	01430016
Research Institution	Hiroshima University
Principal Investigator	小倉文夫広島大学, 工学部, 教授 (90028150)
Co-Investigator(Kenkyū-buntansha)	大下浄治広島大学, 工学部, 助手 (90201376) 塩谷優広島大学, 工学部, 助教授 (80002137) 木谷皓広島大学, 工学部, 助教授 (70034395) 須沢利郎広島大学, 工学部, 教授 (20034291) 服部信広島大学, 工学部, 教授 (30034416)
Keywords	導電性化合物 / 有機電子供与体と受容体 / 有機ヘテロ原子化合物 / ポリアニリン / 無機層状化合物の層間修飾 / 高分子ラテツクス表面の吸着性 / ポリジシラニル化合物の光反応 / 包接化合物の放射線化学
Research Abstract	1.ヘテロ原子を含む新規ドナ-としてペリレンと等電子構造で周辺の4ベンゼン環をチオフェン環で置換した3,3′:4,4′-Bis(thieno[2,3-b]thiophene)、ペリ位ジカルコゲン架橋テトラセン、TPDT誘導体等を合成し高電導性の錯体を得た。一方新規電子受容体としてTCNQのヘテロキノイド類似体を多数合成した。これらは弱い受容体であるがon-site Coulomb反発が小さい。電子吸引基導入により受容能を改善し多数の高電導性錯体を得た。優れた機能の故に実用材料として期待の高いボリアニリンの電解合成の条件を詳細に検討し90Scm^<-1>と伝導度を一桁高める事に成功し、支配因子としてモルホロジ-及び重合度が重要である事を明らかにした。2.無機層状化合物リン酸ジルコニウムの層間表面にあるリン酸水素基をエステル化し有機官能基をグラフトした。このようにしてエ-テル基を導入した無機ー有機複合体は種々のLi塩と固溶体を形成し高いイオン伝導度を示した。3.表面特性の異なる種々の高分子ラテツクスを乳化剤不在系で合成し単分散かつ安定性の良い資料を得た。ラテツクスへの血液タンパク質の吸着性は表面特性と共にイオン強度や共存イオンに大きく影響を受ける。タンパク質で覆われたラテツクスの凝集性は被覆物質による架橋や立体反発により裸の場合とは異なる。4.主鎖にSi-Si結合とpi電子系とを交互に有するpoly(disylanylethenylene)及びpoly(disilanylbutenyn-1,4-diyl)系を合成した。これらは光感応性を有しUV光照射によりSi-Si結合の解裂を伴い顕著な分子量低下が起こる。ポリマ-の薄膜はSbF_5処理により0.65ー7.7Scm^<-1>の導電性を示した。5.チオ尿素(TU)に包接された2,3-dimethyl-1,3-butadiene(DBE)の放射線重合は30℃,[TU]/[DBE]<3の場合約0.5Mrad以上のγ線量では照射中に完了する。又炭化水素の放射線化学の初期過程解明のためcycloalkaneをguestとしhalocarbon系、低温固相での照射を伴う電荷移動をESR法で研究中である。

Research Products
(26 results)

All Other

All Publications (26 results)

[Publications] 湯井幸治: "Novel Electron Acceptors Bearing a Heteroquinonoid System.I.Synthesis and Conductive Complexes of 5,5′-Bis(dicyanomethylene)-5,5′-dihydro-DELTA^<2,2′>-bithiophene and Pelated Compounds" Bulletin of the Chemical Society of Japan. 62. 1539-1546 (1989)
[Publications] 湯井幸治: "Novel Electron Acceptors Bearing a Feteroquinonoid System.II.Synthesis and Conductive Complexes of 2,5-Bis(dicyanomethylene)-2,5-dihydrothieno[3,2-b]thiophene,2,6-Bis(dicyanomethylene)-2,6-dihydro-dithieno[3,2-b:2′,3′-b]thiophene and Their Derivatives" Bulletin of the Chemical Society of Japan. 62. 1547-1555 (1989)
[Publications] 河野泰宏: "3,3′:4,4′-Bis(thieno[2,3-b]thiophene):A Novel Fused Heteroarene" Angewndte Chemie,International Edition in English. 28. 1222-1224 (1989)
[Publications] 滝宮和男: "2,3-Dimethyl and 2,3,6,7-Tetramethyl Derivatives of Anthra[1,9-cd:4,10-c′d′]bis[1,2]dichalcogenols as New Electron Donors" Chemistry Letters. inpress (1990)
[Publications] 白浜博幸: "Participation of Electrolyte Cations in Albumin Adsorption onto Negatively Charged Polymer Latices" Colloid and Polymers Sciences. 267. 587-594 (1989)
[Publications] 玉井久司: "Colloidal Stability of Hydrophilic Functional Copolymer Latex Coated with Albumin" Colloid Surfaces. 40. 63-70 (1989)
[Publications] 玉井久司: "Surface Charactererization of Hydrophilic Functional Polymer Particles" Journal of Applied Polymer Science. 38. 403-412 (1989)
[Publications] 白浜博幸: "Bovine Hemoglobin Adsorption onto Polymer Latices" Journal of Colloid and Interface Science. 129. 483-490 (1989)
[Publications] 吉川研一: "Preparation of Highly Conducting Polyanilines" Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. 270. 421-427 (1989)
[Publications] 木谷皓: "Electrochemical Preparation of Highly Conducting Polyaniline" Abstracts of 40th ISE(International Society of Electrochemistry)Meeting,Sept.17-22,1989. 1. 229 (1989)
[Publications] 木谷皓: "アニリン誘導体ポリマ-のエレクトロクロミズム" 染料と薬品. 34. 35-45 (1989)
[Publications] 木谷皓: "有機分子で電池を創る" 表面科学. 10. 209-211 (1989)
[Publications] 長谷川明紀: "Electron Spin Resonance Spectra and Structure of the Radical Cations of 1,3-Dichloropropane and Other Dichloroalkanes" Journal of the Chemical Society,Perkin Transactions Part II,. 147-151 (1989)
[Publications] 長谷川明紀: "Electron Spin Resonance Spectra and Structure of the Radical Cations of Dibromoalkanes and Monobromoalkanes" Journal of the Chemical Society,Perkin Transactions part II,. 657-665 (1989)
[Publications] 市川隆久: "ESR and Optical Studies of Solute n-Alkane Cations formed in gamma-Irradiated n-Pentane and n-Hexane Matrices" Journal of Physical Chemistry. 93. 3826-3831 (1989)
[Publications] Mikael Lindgren: "ESR Evidence of a Distorted ^2A_g Electronic Structure of the Methylcyclohexane Padical Cation" Chemical Physics Letters. 161. 127-130 (1989)
[Publications] 相馬純吉: "Solid State High Resolution NMR Studies on the Degradation of Polyethylene by gamma-Irradiation" Proceedings of the International Symposium of Polymer. 53-56 (1989)
[Publications] 塩谷優: "The Jahn-Teller Splitted HOMO of the Cyclohexane Cation in Selectively Alkylsubstituted Cyclohexanes:An ESR and MNDO/INDO MO Study" Journal of the American Chemical Society. 111. (1990)
[Publications] L.Sjoqvist: "Structure of trans and cis-3-Hexene Radical Cations Stabilized in Low Temperature Halocarbon Matrices:An ESR and MNDO/AMI Study" Chemical Physics. (1990)
[Publications] 塩谷優: "Radical Cations of Cyclohexanes Alkylsubstituted on One Carbon:An ESR Study of the Jahn-Teller Distorted HOMO of Cyclohexane" Journal of Physical Chemistry. (1990)
[Publications] 塩谷優: "On the Alkyl Radical Formation from Alkane Cations in Ealocarbons:Results for Various Alkyl-substituted Cyclohexanes" Chemical Physics Letters. (1990)
[Publications] 大下浄治: "Polymeric Organosilicon Systems.VI.Synthesis and Properties of trans-Poly[(disilanylene)ethenylene]" Journal of Organometallic Chemistry. 369. C18-C20 (1989)
[Publications] 大下浄治: "Polymeric Organosilicon Systems.5.Synthesis of Poly[(disylanylene)butenyne-1,4-diyls]with highly Conducting Properties" Organometallics. 8. 2084-2085 (1989)
[Publications] 山中昭司: ""Two-Dimensional Layered Phosphates"in Inorganic Phosphate Materials(分担執筆)" Edited by Takahumi KANAZAWA Kodansha/Elsevier, 33 (1989)
[Publications] 小倉文夫: "The Physics and Chemistry of Organic Superconductors(The Proceedings of the 1st International Symposium on the Physics and Chemistry of Organic Superconductors)(分担執筆)" Springer-Verlag, (1990)
[Publications] 大坪徹夫: "The Physics and Chemistry of Organic Superconductors(The Proceedings of the 1st International Symposium on the Physics and Chemistry of Organic Superconductors)(分担執筆)" Springer-Verlag, (1990)

1989 Fiscal Year Annual Research Report

新規機能材料の合成と応用開発

Principal Investigator

小倉 文夫 広島大学, 工学部, 教授 (90028150)

Research Products

[Publications] 湯井幸治: "Novel Electron Acceptors Bearing a Heteroquinonoid System.I.Synthesis and Conductive Complexes of 5,5′-Bis(dicyanomethylene)-5,5′-dihydro-DELTA^<2,2′>-bithiophene and Pelated Compounds" Bulletin of the Chemical Society of Japan. 62. 1539-1546 (1989)

[Publications] 河野泰宏: "3,3′:4,4′-Bis(thieno[2,3-b]thiophene):A Novel Fused Heteroarene" Angewndte Chemie,International Edition in English. 28. 1222-1224 (1989)

[Publications] 滝宮和男: "2,3-Dimethyl and 2,3,6,7-Tetramethyl Derivatives of Anthra[1,9-cd:4,10-c′d′]bis[1,2]dichalcogenols as New Electron Donors" Chemistry Letters. inpress (1990)

[Publications] 白浜博幸: "Participation of Electrolyte Cations in Albumin Adsorption onto Negatively Charged Polymer Latices" Colloid and Polymers Sciences. 267. 587-594 (1989)

[Publications] 玉井久司: "Colloidal Stability of Hydrophilic Functional Copolymer Latex Coated with Albumin" Colloid Surfaces. 40. 63-70 (1989)

[Publications] 玉井久司: "Surface Charactererization of Hydrophilic Functional Polymer Particles" Journal of Applied Polymer Science. 38. 403-412 (1989)

[Publications] 白浜博幸: "Bovine Hemoglobin Adsorption onto Polymer Latices" Journal of Colloid and Interface Science. 129. 483-490 (1989)

[Publications] 吉川研一: "Preparation of Highly Conducting Polyanilines" Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. 270. 421-427 (1989)

[Publications] 木谷皓: "Electrochemical Preparation of Highly Conducting Polyaniline" Abstracts of 40th ISE(International Society of Electrochemistry)Meeting,Sept.17-22,1989. 1. 229 (1989)

[Publications] 木谷皓: "アニリン誘導体ポリマ-のエレクトロクロミズム" 染料と薬品. 34. 35-45 (1989)

[Publications] 木谷皓: "有機分子で電池を創る" 表面科学. 10. 209-211 (1989)

[Publications] 長谷川明紀: "Electron Spin Resonance Spectra and Structure of the Radical Cations of 1,3-Dichloropropane and Other Dichloroalkanes" Journal of the Chemical Society,Perkin Transactions Part II,. 147-151 (1989)

[Publications] 長谷川明紀: "Electron Spin Resonance Spectra and Structure of the Radical Cations of Dibromoalkanes and Monobromoalkanes" Journal of the Chemical Society,Perkin Transactions part II,. 657-665 (1989)

[Publications] 市川隆久: "ESR and Optical Studies of Solute n-Alkane Cations formed in gamma-Irradiated n-Pentane and n-Hexane Matrices" Journal of Physical Chemistry. 93. 3826-3831 (1989)

[Publications] Mikael Lindgren: "ESR Evidence of a Distorted ^2A_g Electronic Structure of the Methylcyclohexane Padical Cation" Chemical Physics Letters. 161. 127-130 (1989)

[Publications] 相馬純吉: "Solid State High Resolution NMR Studies on the Degradation of Polyethylene by gamma-Irradiation" Proceedings of the International Symposium of Polymer. 53-56 (1989)

[Publications] 塩谷優: "The Jahn-Teller Splitted HOMO of the Cyclohexane Cation in Selectively Alkylsubstituted Cyclohexanes:An ESR and MNDO/INDO MO Study" Journal of the American Chemical Society. 111. (1990)

[Publications] L.Sjoqvist: "Structure of trans and cis-3-Hexene Radical Cations Stabilized in Low Temperature Halocarbon Matrices:An ESR and MNDO/AMI Study" Chemical Physics. (1990)

[Publications] 塩谷優: "Radical Cations of Cyclohexanes Alkylsubstituted on One Carbon:An ESR Study of the Jahn-Teller Distorted HOMO of Cyclohexane" Journal of Physical Chemistry. (1990)

[Publications] 塩谷優: "On the Alkyl Radical Formation from Alkane Cations in Ealocarbons:Results for Various Alkyl-substituted Cyclohexanes" Chemical Physics Letters. (1990)

[Publications] 大下浄治: "Polymeric Organosilicon Systems.VI.Synthesis and Properties of trans-Poly[(disilanylene)ethenylene]" Journal of Organometallic Chemistry. 369. C18-C20 (1989)

[Publications] 大下浄治: "Polymeric Organosilicon Systems.5.Synthesis of Poly[(disylanylene)butenyne-1,4-diyls]with highly Conducting Properties" Organometallics. 8. 2084-2085 (1989)

[Publications] 山中昭司: ""Two-Dimensional Layered Phosphates"in Inorganic Phosphate Materials(分担執筆)" Edited by Takahumi KANAZAWA Kodansha/Elsevier, 33 (1989)

[Publications] 小倉文夫: "The Physics and Chemistry of Organic Superconductors(The Proceedings of the 1st International Symposium on the Physics and Chemistry of Organic Superconductors)(分担執筆)" Springer-Verlag, (1990)

[Publications] 大坪徹夫: "The Physics and Chemistry of Organic Superconductors(The Proceedings of the 1st International Symposium on the Physics and Chemistry of Organic Superconductors)(分担執筆)" Springer-Verlag, (1990)

小倉文夫広島大学, 工学部, 教授 (90028150)