1991 Fiscal Year Annual Research Report

新規機能材料の合成と応用開発

Research Project

Project/Area Number	01430016
Research Institution	Hiroshima University
Principal Investigator	小倉文夫広島大学, 工学部, 教授 (90028150)
Co-Investigator(Kenkyū-buntansha)	塩谷優広島大学, 工学部, 助教授 (80002137) 木谷皓広島大学, 工学部, 助教授 (70034395) 山中昭司広島大学, 工学部, 教授 (90081314) 藤原祐三広島大学, 工学部, 教授 (10029481) 安田源広島大学, 工学部, 教授 (00028200)
Keywords	導電性化合物 / 有機電子供与体と受容体 / 有機ヘテロ原子化合物 / ポリアニリン / 無機層状化合物の層間修飾 / シラシクロアルカン / π電子系有機ケイ素ポリマ- / 生分解性高分子材料
Research Abstract	有機電導体に関し小倉、大坪、安蘇らはドナ-として置換縮合芳香環のカルコゲン架橋体及びTPDT誘導体を合成した。また電子受容体として鎖状共役混合ヘテロTCNQ、及び縮合チオフェン環を含むTCNQ類似体を合成した。これらの新規電子供与体、受容体のCT錯体を調製し構造と物性の相関を詳細に研究した。その結果、室温伝導度450Scm^<-1>で150Kまで金属的伝導を示す架橋アントラセンのラジカル塩等多くの高電導性錯体を得て、ヘテロ原子の役割を解明した。ポリアニリンについて木谷らは従来ほとんど研究例のない電極触媒への応用につき検討した。ポリマ-自身がレドックス活性な電位領域では、基質が有機、無機いずれでも触媒作用を示すが、不活性領域では、有機基質と選択的に電子移動を行う事を発見した。この結果は、高選択的センサ-への応用を示唆する。近年生分解性ポリヒドロキシブチレ-トが注目されているが、安田らは類似構造を有するポリエステルをラクトン類の開環重合によリ合成し、酵素分解等種々の試験の結果、生物起源体より生分解性が高く、且つ優れた特性のある高分子を得た。藤原らは前年度のYb金属によるαーアミノ酸の合成反応を応用し、DIOP等のキラル配位子の共存下光学活性体の合成に成功した。また、SmI_2によるイソシアナ-トの二量化にも成功した。山中らはリン酸ジルコニウム結晶の層間表面にエ-テル基を含む有機鎖をグラフトし、新しい無機・有機誘導体を合成した。この層間には種々のLi塩が固溶し、Li^+導電体となる事を示した。塩谷らは、シラシクロアルカンをモデルとして、実験、理論の両面から研究し、有機ケイ素化合物の構造と反応性の理解を飛躍的に深めた。大下らはジエチニルシラン類をRh(I)錯体触媒を用いジシラニレンまたはシリレン単位とエンイン単位を主鎖中に交互に規則正しく含むポリマ-に高収率で変換した。またモデル反応を通じてπ電子系ケイ素ポリマ-の光反応挙動を解明した。

Research Products
(41 results)

All Other

All Publications (41 results)

[Publications] Hideki Ishida;石田英樹: "2,5ーBis(dicyanomethylene)ー2,5ーdihydrofuran and Its Conjugated Homologues as Novel OxygenーContaining Electron Acceptors" Synthetic Metals. 41ー43. 811-814 (1991)
[Publications] Hisakazu Miyamoto;宮本久一: "Dimethyl and Tetramethyl Derivatives of Anthra[1,9ーcd:4,10ーc',d']ーand Naphthaceno[5,6ーcd:11,12ーc'd']ーbis[1,2]dichalcogenoles" Synthetic Metals. 41ー43. 2389-2392 (1991)
[Publications] Kazuo Takimiya;瀧宮和男: "Syntheses and Properties of Dimethyl and Tetramethyl Anthra[1,9ーcd:4,10ーc'd']bis[1,2]dichalcogenoles and Their chargeーTransfer Complexes" Bulletin of the Chemical Society of Japan. 64. 2091-2102 (1991)
[Publications] Kazuo Takimiya;瀧宮和男: "Phenanthro [1,9ーcd:8,9ーc'd']bis[1,2]ーdithiole and ーdiselenole as Novel Electron Donors" Journal of The Chemical Society.Chemical Communications. No.3. 278-280 (1992)
[Publications] Fumio Ogura;小倉文夫: "Design of Novel ChalcogenーContaining Organic Metals:Extensively Conjugated Electron Donors and Acceptors with Reduced OnーSite Coulomb Repulsion" Sulfur Reports.
[Publications] 安田源: "希土類金属錯体に特有な触媒作用" 化学. 47. 74-75 (1992)
[Publications] Ken Takaki;高木謙: "Yitterbium MetalーPromoted Reaction of ketimines with Carbon Dioxide" Chemistry Letters. No.3. 493-496 (1991)
[Publications] Koーichi Sato;佐藤浩一: "PdーCayalyzed Regioー and Stereoーselective Carboxylation of Cycloーalkane with CO" Chemistry Letters. No.8. 1433-1436 (1991)
[Publications] Kazuyuki Nakata;中田一之: "Palladium Catalyzed Carboxylation of Cyclohexane with Carbon Monoーoxide" Chemistry Letters. No.8. 1437-1440 (1991)
[Publications] Ken Takaki;高木謙: "Trichlorolanthanoid(LnCl_3)/Zn Catalyzed Cyclodimerization of Chalcone" Chemistry Letters. No.9. 1665-1668 (1991)
[Publications] Ken Takaki;高木謙: "Reductive Coupling of 2ーPropynー1ーones Promoted by Yb Metal or YbCl_3ーZn" Chemistry Letters. No.9. 1669-1672 (1991)
[Publications] ken Takaki;高木謙: "Reaction of Chalcone Derivatives with Aromatic Aldehydes Promoted by Yitterbium Metal" Chemistry Letters.
[Publications] Shoji Yamanaka;山中昭司: "Intercalation of LiClO_4 into the Organic Derivative of Layered Zirconium Phosphate" Chemistry Letters. No.7. 1225-1258 (1991)
[Publications] Masao Ohashi;大橋正夫: "CoーIntercalation of Tetrahydrofuran and Propylene Carbonate with Alkali Metals in βーZrNCl Layer Structured Crystal" Bull.Chem.Soc.Jpn.,. 64. 2814-2818 (1991)
[Publications] Shoji Yamanaka;山中昭司: "Design and Synthesis of Functional Layered Nanaocomposites" Ceramic Bulletin. 70. 1056-1058 (1991)
[Publications] 山中昭司: "ミクロポ-ラスクリスタルの新しい合成" 表面. 29. 387-398 (1991)
[Publications] Shoji Yamanaka;山中昭司: "γ→α Transformation inthe Layered Structured Zirconium Phosphate" Phosphorus Resarch Bulletin. 1. 51-56 (1991)
[Publications] Shoji Yamanaka;山中昭司: "Anion Exchange Reaction in Layered Basic Copper Salts" Sold State Ionics.
[Publications] Shoji Yamanaka;山中昭司: "Preparation and Ionic Conductivities of the Solid Solution of LiCl0_4ーOrganic Derivatives of Zirconium Phospate" Solid State Ionics.
[Publications] Jun Yano;矢野淳: "Unique Electrochemical Response of a PolyanilineーFilm Coated Electrodes to Several Dissolved Organic Species" Canadian Journal of Chemistry. 70. (1992)
[Publications] Jun Yano;矢野淳: "The Mechnistic Difference between Hydroquinone and Fe^<2+> in the Electrochemical Response of a PolyanilineーFilm Coated Electrode" Bulletin of The Chemical Society of Japan.
[Publications] 木谷皓: "ポリアニリンの導電性及び機械的性質の向上" 電池技術. 4. (1992)
[Publications] Masaru Shiotani;塩谷優: "Radical Cations of Cyclohexanes Alkylーsubstituted on one Carbon:An ESR Srudy of the JahnーTeller Disistorted HOMO of Cyclohexane" Jounal of Chemical Society,Perkin Transactions II. 711-719 (1991)
[Publications] L.Sjoqvist: "The Structure of the Azetidine Radical Caticon and the Neutral 1ーAzetidinyl Redical:an Theoretical abーinitio and ESR Study" Journal of the Chemical Society,Faraday Transactions. 87. 1083-1088 (1991)
[Publications] Nobuaki Ohta;太田信昭: "Electron Paramagnetic Resonance and INDOーMO Studies of 2ーmethylーbutane,3ーMethylpantane,and 3ーMethylhexane Cations Produced in Several halocarbon Matrices γーirradiated at 77k" Journal of Chemical Society,Farady Transactions. 87. 3869-3874 (1991)
[Publications] Junkichi Sohma;相馬純吉: "SolidーState HighーResolution ^<13>CーNMR Study of Crosslinks in Heavily GammaーIrradiated Polyethylene" Radiat.Phys.Chem.(Int.J.Radiat.Appl.Instrum.,Part C). 37. 47-51 (1991)
[Publications] Masaru Shiotani;塩谷優: "An Asymmetrically Distorted Structure of the 1ーMethylsilacyclohexane Radical Cations:ESR Evidence" Chemical Physics Letters. 188. 93-99 (1992)
[Publications] Hiroto Tachikawa: "Structure and Formation Mecahnisms of Methylー and DimethylーAcetylene Dimer Cations:ESR and ab Initio MO Studies" The Journal of Physical Chemistry. 96. 164-171 (1992)
[Publications] Y.Kubozono: "Matrix Dependence og the Conformations of 1,4ーDiethylbenzene Redical Cation at Low Temperature" Spectrochimica Acta. 48A. 213-218 (1992)
[Publications] Joji Ohshita;大下浄治: "Polymeric Organosilicon Systems.10.Synthesis and Conducting Properties of Poly[2,5ー(disilanylene)thienylenes" Macromolecules. 24. 2106-2107 (1991)
[Publications] Joji Ohshita;大下浄治: "SiliconーCarbon Unsaturated Compounds.26.Photochemical Behavior of 1,4ーand 1,5ーBis(pentamethyldisilanyl)naphthalene" Organometallics. 10. 880-887 (1991)
[Publications] Joji Ohshita;大下浄治: "SiliconeーCarbon Unsaturated Compounds.29.The Photochemical Behavior of 2,6ーand 2,7ーBis(pentamethyldisilanyl)naphthalene" Organometallics. 10. 2685-2695 (1991)
[Publications] Joji Ohshita;大下浄治: "SiliconーCarbon Unsaturated Compounds.31.The Photochemical Behavior of 1,1ーand 1,2ーDinaphthyldisilanes" Organometallics. 10. 2695-2700 (1991)
[Publications] Joji Ohshita;大下浄治: "Polymeric Organosilicon Systems.11.Synthesis and Some Properties of Poly[(disilanylene)butenyneー1,4ーdiyls]and Poly [(methylphenylーsilylene)ーbuteneyneー1,4ーdiyl]" Macromolecules.
[Publications] 藤原祐三: "3族有機金属錯体の合成(実験化学講座18,有機金属錯体)" 丸善株式会社, 9 (1991)
[Publications] 服部信: "多孔性セラミックスの開発と応用II" シ-エム-シ, 322 (1991)
[Publications] Masaru Shiotani;塩谷優: "Handbook of Radiation chemistry(Ed.Y.Tabata):Chapter IX.B:ESR Spectra of Free Radicals Generated by Ionized Radiation" CRC Press, 24 (1990)
[Publications] A.Lund: "Radical Ionic SystemsーProperties in Condensed Phases (Editors.A.Lund;M.Shiotani)" Kluwer Academic Publisher, 496 (1991)
[Publications] M.Lindgren: "Radical Ionic Systems(Editors,A.Lund;M.Shiotani):Chapter 15,ESR Studies Cations of Radical of Cycloalkanes and Saturated Heterocycles" kluwer Acadimec Publisher, 26 (1991)
[Publications] Masaru Shiotani;塩谷優: "Radical Ionic Systems(Ed.A.Lund;M.Shiotani):Chapter I.6,Deuterium Labelling Studies of Cation Radicals" Kluwer Academic Publisher, 26 (1991)
[Publications] Masaru Shiotani;塩谷優: "Handbook of Radiation Chemistry(Ed.Y.Tabata):Chapter III.B.7:ESR Detection of Radicals Trapped in Soild" CRC Press, 6 (1991)

1991 Fiscal Year Annual Research Report

新規機能材料の合成と応用開発

Principal Investigator

小倉 文夫 広島大学, 工学部, 教授 (90028150)

Research Products

[Publications] Hideki Ishida;石田 英樹: "2,5ーBis(dicyanomethylene)ー2,5ーdihydrofuran and Its Conjugated Homologues as Novel OxygenーContaining Electron Acceptors" Synthetic Metals. 41ー43. 811-814 (1991)

[Publications] Hisakazu Miyamoto;宮本 久一: "Dimethyl and Tetramethyl Derivatives of Anthra[1,9ーcd:4,10ーc',d']ーand Naphthaceno[5,6ーcd:11,12ーc'd']ーbis[1,2]dichalcogenoles" Synthetic Metals. 41ー43. 2389-2392 (1991)

[Publications] Kazuo Takimiya;瀧宮 和男: "Syntheses and Properties of Dimethyl and Tetramethyl Anthra[1,9ーcd:4,10ーc'd']bis[1,2]dichalcogenoles and Their chargeーTransfer Complexes" Bulletin of the Chemical Society of Japan. 64. 2091-2102 (1991)

[Publications] Kazuo Takimiya;瀧宮 和男: "Phenanthro [1,9ーcd:8,9ーc'd']bis[1,2]ーdithiole and ーdiselenole as Novel Electron Donors" Journal of The Chemical Society.Chemical Communications. No.3. 278-280 (1992)

[Publications] Fumio Ogura;小倉 文夫: "Design of Novel ChalcogenーContaining Organic Metals:Extensively Conjugated Electron Donors and Acceptors with Reduced OnーSite Coulomb Repulsion" Sulfur Reports.

[Publications] 安田 源: "希土類金属錯体に特有な触媒作用" 化学. 47. 74-75 (1992)

[Publications] Ken Takaki;高木 謙: "Yitterbium MetalーPromoted Reaction of ketimines with Carbon Dioxide" Chemistry Letters. No.3. 493-496 (1991)

[Publications] Koーichi Sato;佐藤 浩一: "PdーCayalyzed Regioー and Stereoーselective Carboxylation of Cycloーalkane with CO" Chemistry Letters. No.8. 1433-1436 (1991)

[Publications] Kazuyuki Nakata;中田 一之: "Palladium Catalyzed Carboxylation of Cyclohexane with Carbon Monoーoxide" Chemistry Letters. No.8. 1437-1440 (1991)

[Publications] Ken Takaki;高木 謙: "Trichlorolanthanoid(LnCl_3)/Zn Catalyzed Cyclodimerization of Chalcone" Chemistry Letters. No.9. 1665-1668 (1991)

[Publications] Ken Takaki;高木 謙: "Reductive Coupling of 2ーPropynー1ーones Promoted by Yb Metal or YbCl_3ーZn" Chemistry Letters. No.9. 1669-1672 (1991)

[Publications] ken Takaki;高木 謙: "Reaction of Chalcone Derivatives with Aromatic Aldehydes Promoted by Yitterbium Metal" Chemistry Letters.

[Publications] Shoji Yamanaka;山中 昭司: "Intercalation of LiClO_4 into the Organic Derivative of Layered Zirconium Phosphate" Chemistry Letters. No.7. 1225-1258 (1991)

[Publications] Masao Ohashi;大橋 正夫: "CoーIntercalation of Tetrahydrofuran and Propylene Carbonate with Alkali Metals in βーZrNCl Layer Structured Crystal" Bull.Chem.Soc.Jpn.,. 64. 2814-2818 (1991)

[Publications] Shoji Yamanaka;山中 昭司: "Design and Synthesis of Functional Layered Nanaocomposites" Ceramic Bulletin. 70. 1056-1058 (1991)

[Publications] 山中 昭司: "ミクロポ-ラスクリスタルの新しい合成" 表面. 29. 387-398 (1991)

[Publications] Shoji Yamanaka;山中 昭司: "γ→α Transformation inthe Layered Structured Zirconium Phosphate" Phosphorus Resarch Bulletin. 1. 51-56 (1991)

[Publications] Shoji Yamanaka;山中 昭司: "Anion Exchange Reaction in Layered Basic Copper Salts" Sold State Ionics.

[Publications] Shoji Yamanaka;山中 昭司: "Preparation and Ionic Conductivities of the Solid Solution of LiCl0_4ーOrganic Derivatives of Zirconium Phospate" Solid State Ionics.

[Publications] Jun Yano;矢野 淳: "Unique Electrochemical Response of a PolyanilineーFilm Coated Electrodes to Several Dissolved Organic Species" Canadian Journal of Chemistry. 70. (1992)

[Publications] Jun Yano;矢野 淳: "The Mechnistic Difference between Hydroquinone and Fe^<2+> in the Electrochemical Response of a PolyanilineーFilm Coated Electrode" Bulletin of The Chemical Society of Japan.

[Publications] 木谷 皓: "ポリアニリンの導電性及び機械的性質の向上" 電池技術. 4. (1992)

[Publications] Masaru Shiotani;塩谷 優: "Radical Cations of Cyclohexanes Alkylーsubstituted on one Carbon:An ESR Srudy of the JahnーTeller Disistorted HOMO of Cyclohexane" Jounal of Chemical Society,Perkin Transactions II. 711-719 (1991)

[Publications] L.Sjoqvist: "The Structure of the Azetidine Radical Caticon and the Neutral 1ーAzetidinyl Redical:an Theoretical abーinitio and ESR Study" Journal of the Chemical Society,Faraday Transactions. 87. 1083-1088 (1991)

[Publications] Junkichi Sohma;相馬 純吉: "SolidーState HighーResolution ^<13>CーNMR Study of Crosslinks in Heavily GammaーIrradiated Polyethylene" Radiat.Phys.Chem.(Int.J.Radiat.Appl.Instrum.,Part C). 37. 47-51 (1991)

[Publications] Masaru Shiotani;塩谷 優: "An Asymmetrically Distorted Structure of the 1ーMethylsilacyclohexane Radical Cations:ESR Evidence" Chemical Physics Letters. 188. 93-99 (1992)

[Publications] Hiroto Tachikawa: "Structure and Formation Mecahnisms of Methylー and DimethylーAcetylene Dimer Cations:ESR and ab Initio MO Studies" The Journal of Physical Chemistry. 96. 164-171 (1992)

[Publications] Y.Kubozono: "Matrix Dependence og the Conformations of 1,4ーDiethylbenzene Redical Cation at Low Temperature" Spectrochimica Acta. 48A. 213-218 (1992)

[Publications] Joji Ohshita;大下 浄治: "Polymeric Organosilicon Systems.10.Synthesis and Conducting Properties of Poly[2,5ー(disilanylene)thienylenes" Macromolecules. 24. 2106-2107 (1991)

[Publications] Joji Ohshita;大下 浄治: "SiliconーCarbon Unsaturated Compounds.26.Photochemical Behavior of 1,4ーand 1,5ーBis(pentamethyldisilanyl)naphthalene" Organometallics. 10. 880-887 (1991)

[Publications] Joji Ohshita;大下 浄治: "SiliconeーCarbon Unsaturated Compounds.29.The Photochemical Behavior of 2,6ーand 2,7ーBis(pentamethyldisilanyl)naphthalene" Organometallics. 10. 2685-2695 (1991)

[Publications] Joji Ohshita;大下 浄治: "SiliconーCarbon Unsaturated Compounds.31.The Photochemical Behavior of 1,1ーand 1,2ーDinaphthyldisilanes" Organometallics. 10. 2695-2700 (1991)

[Publications] Joji Ohshita;大下 浄治: "Polymeric Organosilicon Systems.11.Synthesis and Some Properties of Poly[(disilanylene)butenyneー1,4ーdiyls]and Poly [(methylphenylーsilylene)ーbuteneyneー1,4ーdiyl]" Macromolecules.

[Publications] 藤原 祐三: "3族有機金属錯体の合成(実験化学講座18,有機金属錯体)" 丸善株式会社, 9 (1991)

[Publications] 服部 信: "多孔性セラミックスの開発と応用II" シ-エム-シ, 322 (1991)

[Publications] Masaru Shiotani;塩谷 優: "Handbook of Radiation chemistry(Ed.Y.Tabata):Chapter IX.B:ESR Spectra of Free Radicals Generated by Ionized Radiation" CRC Press, 24 (1990)

[Publications] A.Lund: "Radical Ionic SystemsーProperties in Condensed Phases (Editors.A.Lund;M.Shiotani)" Kluwer Academic Publisher, 496 (1991)

[Publications] M.Lindgren: "Radical Ionic Systems(Editors,A.Lund;M.Shiotani):Chapter 15,ESR Studies Cations of Radical of Cycloalkanes and Saturated Heterocycles" kluwer Acadimec Publisher, 26 (1991)

[Publications] Masaru Shiotani;塩谷 優: "Radical Ionic Systems(Ed.A.Lund;M.Shiotani):Chapter I.6,Deuterium Labelling Studies of Cation Radicals" Kluwer Academic Publisher, 26 (1991)

[Publications] Masaru Shiotani;塩谷 優: "Handbook of Radiation Chemistry(Ed.Y.Tabata):Chapter III.B.7:ESR Detection of Radicals Trapped in Soild" CRC Press, 6 (1991)

小倉文夫広島大学, 工学部, 教授 (90028150)

[Publications] Hideki Ishida;石田英樹: "2,5ーBis(dicyanomethylene)ー2,5ーdihydrofuran and Its Conjugated Homologues as Novel OxygenーContaining Electron Acceptors" Synthetic Metals. 41ー43. 811-814 (1991)

[Publications] Hisakazu Miyamoto;宮本久一: "Dimethyl and Tetramethyl Derivatives of Anthra[1,9ーcd:4,10ーc',d']ーand Naphthaceno[5,6ーcd:11,12ーc'd']ーbis[1,2]dichalcogenoles" Synthetic Metals. 41ー43. 2389-2392 (1991)

[Publications] Kazuo Takimiya;瀧宮和男: "Syntheses and Properties of Dimethyl and Tetramethyl Anthra[1,9ーcd:4,10ーc'd']bis[1,2]dichalcogenoles and Their chargeーTransfer Complexes" Bulletin of the Chemical Society of Japan. 64. 2091-2102 (1991)

[Publications] Kazuo Takimiya;瀧宮和男: "Phenanthro [1,9ーcd:8,9ーc'd']bis[1,2]ーdithiole and ーdiselenole as Novel Electron Donors" Journal of The Chemical Society.Chemical Communications. No.3. 278-280 (1992)

[Publications] Fumio Ogura;小倉文夫: "Design of Novel ChalcogenーContaining Organic Metals:Extensively Conjugated Electron Donors and Acceptors with Reduced OnーSite Coulomb Repulsion" Sulfur Reports.

[Publications] 安田源: "希土類金属錯体に特有な触媒作用" 化学. 47. 74-75 (1992)

[Publications] Ken Takaki;高木謙: "Yitterbium MetalーPromoted Reaction of ketimines with Carbon Dioxide" Chemistry Letters. No.3. 493-496 (1991)

[Publications] Koーichi Sato;佐藤浩一: "PdーCayalyzed Regioー and Stereoーselective Carboxylation of Cycloーalkane with CO" Chemistry Letters. No.8. 1433-1436 (1991)

[Publications] Kazuyuki Nakata;中田一之: "Palladium Catalyzed Carboxylation of Cyclohexane with Carbon Monoーoxide" Chemistry Letters. No.8. 1437-1440 (1991)

[Publications] Ken Takaki;高木謙: "Trichlorolanthanoid(LnCl_3)/Zn Catalyzed Cyclodimerization of Chalcone" Chemistry Letters. No.9. 1665-1668 (1991)

[Publications] Ken Takaki;高木謙: "Reductive Coupling of 2ーPropynー1ーones Promoted by Yb Metal or YbCl_3ーZn" Chemistry Letters. No.9. 1669-1672 (1991)

[Publications] ken Takaki;高木謙: "Reaction of Chalcone Derivatives with Aromatic Aldehydes Promoted by Yitterbium Metal" Chemistry Letters.

[Publications] Shoji Yamanaka;山中昭司: "Intercalation of LiClO_4 into the Organic Derivative of Layered Zirconium Phosphate" Chemistry Letters. No.7. 1225-1258 (1991)

[Publications] Masao Ohashi;大橋正夫: "CoーIntercalation of Tetrahydrofuran and Propylene Carbonate with Alkali Metals in βーZrNCl Layer Structured Crystal" Bull.Chem.Soc.Jpn.,. 64. 2814-2818 (1991)

[Publications] Shoji Yamanaka;山中昭司: "Design and Synthesis of Functional Layered Nanaocomposites" Ceramic Bulletin. 70. 1056-1058 (1991)

[Publications] 山中昭司: "ミクロポ-ラスクリスタルの新しい合成" 表面. 29. 387-398 (1991)

[Publications] Shoji Yamanaka;山中昭司: "γ→α Transformation inthe Layered Structured Zirconium Phosphate" Phosphorus Resarch Bulletin. 1. 51-56 (1991)

[Publications] Shoji Yamanaka;山中昭司: "Anion Exchange Reaction in Layered Basic Copper Salts" Sold State Ionics.

[Publications] Shoji Yamanaka;山中昭司: "Preparation and Ionic Conductivities of the Solid Solution of LiCl0_4ーOrganic Derivatives of Zirconium Phospate" Solid State Ionics.

[Publications] Jun Yano;矢野淳: "Unique Electrochemical Response of a PolyanilineーFilm Coated Electrodes to Several Dissolved Organic Species" Canadian Journal of Chemistry. 70. (1992)

[Publications] Jun Yano;矢野淳: "The Mechnistic Difference between Hydroquinone and Fe^<2+> in the Electrochemical Response of a PolyanilineーFilm Coated Electrode" Bulletin of The Chemical Society of Japan.

[Publications] 木谷皓: "ポリアニリンの導電性及び機械的性質の向上" 電池技術. 4. (1992)

[Publications] Masaru Shiotani;塩谷優: "Radical Cations of Cyclohexanes Alkylーsubstituted on one Carbon:An ESR Srudy of the JahnーTeller Disistorted HOMO of Cyclohexane" Jounal of Chemical Society,Perkin Transactions II. 711-719 (1991)

[Publications] Junkichi Sohma;相馬純吉: "SolidーState HighーResolution ^<13>CーNMR Study of Crosslinks in Heavily GammaーIrradiated Polyethylene" Radiat.Phys.Chem.(Int.J.Radiat.Appl.Instrum.,Part C). 37. 47-51 (1991)

[Publications] Masaru Shiotani;塩谷優: "An Asymmetrically Distorted Structure of the 1ーMethylsilacyclohexane Radical Cations:ESR Evidence" Chemical Physics Letters. 188. 93-99 (1992)

[Publications] Joji Ohshita;大下浄治: "Polymeric Organosilicon Systems.10.Synthesis and Conducting Properties of Poly[2,5ー(disilanylene)thienylenes" Macromolecules. 24. 2106-2107 (1991)

[Publications] Joji Ohshita;大下浄治: "SiliconーCarbon Unsaturated Compounds.26.Photochemical Behavior of 1,4ーand 1,5ーBis(pentamethyldisilanyl)naphthalene" Organometallics. 10. 880-887 (1991)

[Publications] Joji Ohshita;大下浄治: "SiliconeーCarbon Unsaturated Compounds.29.The Photochemical Behavior of 2,6ーand 2,7ーBis(pentamethyldisilanyl)naphthalene" Organometallics. 10. 2685-2695 (1991)

[Publications] Joji Ohshita;大下浄治: "SiliconーCarbon Unsaturated Compounds.31.The Photochemical Behavior of 1,1ーand 1,2ーDinaphthyldisilanes" Organometallics. 10. 2695-2700 (1991)

[Publications] Joji Ohshita;大下浄治: "Polymeric Organosilicon Systems.11.Synthesis and Some Properties of Poly[(disilanylene)butenyneー1,4ーdiyls]and Poly [(methylphenylーsilylene)ーbuteneyneー1,4ーdiyl]" Macromolecules.

[Publications] 藤原祐三: "3族有機金属錯体の合成(実験化学講座18,有機金属錯体)" 丸善株式会社, 9 (1991)

[Publications] 服部信: "多孔性セラミックスの開発と応用II" シ-エム-シ, 322 (1991)

[Publications] Masaru Shiotani;塩谷優: "Handbook of Radiation chemistry(Ed.Y.Tabata):Chapter IX.B:ESR Spectra of Free Radicals Generated by Ionized Radiation" CRC Press, 24 (1990)

[Publications] Masaru Shiotani;塩谷優: "Radical Ionic Systems(Ed.A.Lund;M.Shiotani):Chapter I.6,Deuterium Labelling Studies of Cation Radicals" Kluwer Academic Publisher, 26 (1991)

[Publications] Masaru Shiotani;塩谷優: "Handbook of Radiation Chemistry(Ed.Y.Tabata):Chapter III.B.7:ESR Detection of Radicals Trapped in Soild" CRC Press, 6 (1991)