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1990 Fiscal Year Final Research Report Summary

Photo-Physical Measurements of Fuctional Organic Materials under High Pressure

Research Project

Project/Area Number 01460083
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 物理計測・光学
Research InstitutionKyushu University

Principal Investigator

MATSUSHIGE Kazumi  Kyushu Univ., Fac. of Eng. Professor, 工学部, 教授 (80091362)

Co-Investigator(Kenkyū-buntansha) HORIUCHI Toshihisa  Kyushu Univ., Fac. of Eng. Res. Assist., 工学部, 教務員
OKABE Hirotaka  Kyushu Univ., Fac. of Eng. Res. Assoc., 工学部, 助手 (90221142)
HARA Kazuhiro  Kyushu Univ., Fac. of Eng. Assoc. Prof., 工学部, 助教授 (00180993)
Project Period (FY) 1989 – 1990
KeywordsPhoto-Physical properties / High pressure / Organic materials / Photo-absorbance spectra / Charge-transfer complex / Crystal structure / X-ray diffraction / Phase transition
Research Abstract

The objectives of this study were to develop the measuring system for photo-physical measurement under high pressure and to analyze the correlation between the functionalities and structures in organic materials with notable photo-and electric functions. And major results are followings.
1) The high pressure measuring system which is capable of conducting the photo-absorbance spectra, photo-conductivity, Raman scattering measurements up to 500 MPa was constructed. And its performance was fully ascertained.
2) The photo-absorbance measurements under high pressure were conducted for typical photo-conductive polymers, PVK-TNF comples, and several district changes in photo-absorbance spectra were observed, suggesting that the application of pressure induces the closer packing in the molecular chains and promotes the CT complex formation.
3) The application of high pressure was revealed by high-pressure X-ray and Roman measurements to induce the conformational transition from gauche to trans and the crystal formation with more perfect crystalinity.
4) Several new data on the solid-solid phase transition under high pressure were obtained for urea-paraffin adducts.
5) The multi-photospectrometer with photo-diode array was utilized to monitor the gelletion process in some protains.

  • Research Products

    (10 results)

All Other

All Publications (10 results)

  • [Publications] K.Matsushige: "Pressure Effect on Phase Transition in Ferroelectric Polymers" Phase Transition. Vol.18. 247-262 (1989)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Fukao,T.Horiuchi,S.Taki,K.Matsushige: "Phase Transitions of Urea Adducts with NーParaffins under High Pressure" Mol.Cryst.Liq.Cryst.Vol.180B. 405-416 (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Tsubakihara,K.Matsushige,M.Yasumiwa: "Phase Transitions of nーPerfluoroalkanes under High Pressure" Rept.Progr.Polym.Phys.Jpn.Vol.33. 195-196 (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Okada,K.Matsushige: "Longitudinal Acoustic Mode of nーParaffin in UreaーAdduct" Rept.Progr.Polym.Phys.Jpn.Vol.33. 469-472 (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Okada,K.Matsushige: "Pressure Effect on Photoーabsorption Spectra of PVKーTNF Charge Transfer Complex" Rept.Progr.Polym.Phys.Jpn.Vol.33. 473-476 (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K. Matsushige: "Pressure Effect on Phase Transition in Ferroelectric Polymers" Phase Transition. vol. 18. 247-262 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Fukao, T. Horiuchi, S. Taki, K. Matsushige: "Phase Transitions of Urea Adducts with n-Paraffins under High Pressure" Mol. Cryst. Liq. Cryst.,. vol. 180B. 405-416 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Tsubakihara, K. Matsushige, M. Yasumiwa: "Phase Transitions of n-Perfluoroalkanes under High Pressure" Rept. Progr. Polym. Phys. Jpn.Vol. 33. 469-472 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N. Okada, K. Matsushige: "Longitudinal Acoustic Mode of n-Paraffin in Urea-Adduct" Rept. Progr. Polym. Phys. Jpn.,. Vol. 33. 469-472 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N. Okada, K. Matsushige: "Pressure Effect on photo-absorption Spectra of PVK-TNF Charge Transfer Complex" Rept. Progr. Polym. Phys. Jpn.Vol. 33. 473-475 (1990)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1993-08-12  

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