• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

1992 Fiscal Year Final Research Report Summary

"Formational mechanisms and materials properties of iron sulfides"

Research Project

Project/Area Number 02045003
Research Category

Grant-in-Aid for international Scientific Research

Allocation TypeSingle-year Grants
SectionUniversity-to-University Cooperative Research
Research InstitutionTohoku University

Principal Investigator

OHMOTO Hiroshi TSUKAMOTO Katsuo  Faculty of Science, Tohoku University. Prof. Faculty of Science, Tohoku University., 理学部, 助手 (60125614)

Co-Investigator(Kenkyū-buntansha) U. Graham  ペンシルヴァニア州立大学, 地球及び鉱物科学, 助手
S. Poulson  ペンシルヴァニア州立大学, 地球及び鉱物科学, 助手
L.M. Kump  ペンシルヴァニア州立大学, 地球及び鉱物科学, 助教授
K.OSSEO-ASARE  College of Earth and Mineral Sciences, Pennsylvania State University., 地球及び鉱物科学, 教授
NARAOKA Hiroshi  Faculty of Science, Tohoku University., 理学部, 助手 (20198386)
KITAKAZE Arashi  Faculty of Science, Tohoku University., 理学部, 助手 (90035064)
HAYASHI Ken-ichiro  Faculty of Science, Tohoku University., 理学部, 助教授 (40124614)
SHIMADA Masahiko  Faculty of Engineering, Tohoku University., 工学部, 教授 (80029701)
HIRAI Toshio  Institute of Material Sciences, Tohoku University., 金属材料研究所, 教授 (50005865)
SIMON R.Poulson  College of Earth and Mineral Sciences, Pennsylvania State University.
URSULA M.Graham  College of Earth and Mineral Sciences, Pennsylvania State University.
LEE M.Kump  College of Earth and Mineral Sciences, Pennsylvania State University.
Project Period (FY) 1990 – 1992
KeywordsIron Sulfides / Pyrrhotite / Hydrothermal Solution / Semiconductivity / Lattice Constant / Anisotropy / Trace Elements / 微量元素
Research Abstract

Iron sulfides, especially pyrite and pyrrhotite, are the most abundant sulfide minerals in the Earth. They are formed from magmas in igneous rocks, from hydrothermal solutions in a variety of mineral deposits, and by bacterial activity in oceans, sedimentary rocks, coals and petroleum. The iron sulfide minerals are known to exhibit considerable variations in physical properties (morphology and habits, density), crystal structure (lattice constants), optical properties,(reflectivity,anisotropy), electrochemical properties (semiconductivity, photoelectrical and thermoelectrical potentials),surface reactivity in the air and in aqueous solutions, sorption potentials for gold and other trace elements, and in chemical properties (Fe/S ratios, trace element contents). The principal objective of this cooperative research project was,therefore, to identify the relationships among the various properties of pyrite, and the relationships between the properties and the formational mechanisms of pyr … More ite. This objective was approached through systematic investigations on the properties of both synthetic and natural iron sulfide crystals formed under a variety of conditions. We were able to accomplish the objective.
The results of our research are expected to provide an important basis for the better use of pyrite in various industries, For example, in the electronic industry, some pyrite crystals may be developed as semiconductors, high energy batteries, and solar energy cells. In the mineral processing, petroleum, and coal industries, understanding the relationships between the properties and the formational environments of pyrite crystals will help developments of better methods for preferential removal of pyrite from other metal-bearing minerals, oils and coals. In environmental agancies, information on the behaviors of pyrite in aqueous solutions will be useful in controlling the weathering of pyrite at abandoned mine sites, which has been the main cause for acid drainages. In the mining industry, some properties of pyrite may be used for exploration of new mineral deposits, especially gold deposits. Less

  • Research Products

    (15 results)

All Other

All Publications (15 results)

  • [Publications] S.R.Poulson and H.OHMOTO: "″An evaluation of the solubility of sulfide sulfur in silicatc mclts from cxpcrimental data and natural samples″" Chem.Geol. 85. 57-75 (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.S Kim,Y.T.Kho,H.W.Pickering,and K.Osseo-Asare: "″Mass transfer effects on the anodic behavior of porous Fe and Co sintered electrodes in aqueous ammonical solution″" J.Electrochem.Soc.138. 1599-1607 (1991)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.MISHRA and K.Osseo-Asare: "″Electroreduction of Fe^<3+>,O_2,and Fe(CN)_6^<3->at the n-pyrite(FeS_2)surface″" J.Electrochem.Soc.139. 3116-3120 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Osseo-Asare: "″Semiconductor electrochemistry and hydrometallurgecal dissolution processes″" Hydrometallurgy. 29. 61-90 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.OHMOTO,K.HAYASHI,and Y.KAJISA: "″Experimental study of the solubilities of pyrite in NaCl-bearing aqueous solutions at250゚-350℃″" Geochim.Cosmochim.Acta.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] ONUMA,K.,TSUKAMOTO,K.,and NAKADATE,S.: "Application of real time phase shift interferometer to the measurement of concentration field" J.Crystal Growth.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.OHMOTO,C.J.Kaiser,and K.A.Geer: "Systematics of sulphur isotopes in recent marine sediments and ancient sediment-hosted basemental deposits in StableIsotopes and Flued Processes in Mineralization,Herbert,H.M.and Ho,S.E.eds." The Univ.of Wetern Australia Publication, (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] TSUKAMOTO,K.: "In-situ observations of erystal growth processes,in VII European symqosium on materials and Nuid sciences in microgravity,Kaldeich,B.H.ed." (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.R Poulson and H. Ohmoto: "An evaluation of the solubility of sulfide sulfur in silicate malts from experimental data and natural samples" Chem. Geol.85. 57-75 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.S.Kim, Y.T.Kho,H.W.Pickering, and K.Osseo-Asare: "Mass transfer effects on the anodic behavior of porous Fe and Cosintered electrodes in aqueous ammonical solution" J.Electrochem.Soc.138. 1599-1607 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Mishra and K. Osseo-Asare: "Electroreduction of Fe^<3+>, O_2, and Fe(CN)_6^<3-> at the n-pyrite (FeS_2) surface" J. Electrochem. Soc.139. 3116-3120 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Osseo-Asare: "Semiconductor electrochemistry and hydrometallurgical dissolution processes" Hydrometallurgy. 29. 61-90 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Ohmoto, Hayashi, and Y. Kajisa: "Experimental study of the solubilities of pyrite in CaCl-bearing aqueous solutions at 250゚-350゚C" Geochim. Cosmochim. Acta.

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Ohmoto, C.J.Kaiser, and K.A.Geer: The Univ.of Western Australia Publication. Systematics of sulphur isotopes in recent marine sediments and ancient sediment-hosted basemental deposits in Stable Isotopes and Fluid Processes in Mineralization, Herbert, H.M.and Ho, S.E.eds., 23,70-120 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Tsukamoto: In-situ observations of crystal growth processes, in VII European symposium on materials and fluid sciences in microgravity, Kaldeich, B.H. ed., 561-563 (1990)

    • Description
      「研究成果報告書概要(欧文)」より

URL: 

Published: 1994-03-24  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi